Negative electrode for rechargeable lithium battery and rechargeable lithium battery including same

Patent metadata

Field	Value
Publication number	US-2023109733-A1
Application number	US-202217937260-A
Country	US
Kind code	A1
Filing date	Sep 30, 2022
Priority date	Oct 7, 2021
Publication date	Apr 13, 2023
Grant date	—

Abstract

Disclosed is a negative electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same, and the negative electrode includes a current collector and a negative active material layer on the current collector and including a negative active material and a conductive material, the negative active material including a silicon-based active material and the conductive material includes carbon nanotube, wherein the negative active material and the conductive material are included in the negative active material layer in order to satisfy a relationship of Equation 1 and Equation 2.26<A*B−{(C*D)/10}<55   Equation 1600≤D≤1000   Equation 2

First claim

What is claimed is:

1 . A negative electrode for a rechargeable lithium battery, comprising:
a current collector; and a negative active material layer on the current collector and comprising a negative active material and a conductive material, wherein the negative active material comprises a silicon-based active material, wherein the conductive material comprises carbon nanotubes, and wherein the negative active material and the conductive material are comprised in the negative active material layer in order to satisfy a relationship of Equation 1 and Equation 2:
26< A*B−{ ( C*D )/10}<55   Equation 1

600 ≤D≤ 1000   Equation 2

wherein, in Equations 1 and 2, A is wt % of the silicon-based active material comprised in the negative active material layer, B is a specific surface area (m 2 /g) according to gas adsorption of the silicon-based active material comprised in the negative active material layer, C is wt % of carbon nanotubes comprised in the negative active material layer, and D is a specific surface area (m 2 /g) according to gas adsorption of the carbon nanotubes comprised in the negative active material layer.

2 . The negative electrode for a rechargeable lithium battery of claim 1 , wherein the silicon-based active material comprises a composite of Si and carbon.

3 . The negative electrode for a rechargeable lithium battery of claim 1 , wherein the specific surface area according to gas adsorption of the silicon-based active material is about 1 m 2 /g to about 20 m 2 /g.

4 . The negative electrode for a rechargeable lithium battery of claim 1 , wherein an amount of the negative active material is about 95 wt % to about 99.99 wt % based on the total, 100 wt % of the negative active material layer.

5 . The negative electrode for a rechargeable lithium battery of claim 1 , wherein an amount of the carbon nanotubes is about 0.01 wt % to about 5 wt % based on the total, 100 wt % of the negative active material layer.

6 . A method of preparing a negative electrode for a rechargeable lithium battery, comprising:
distributing a conductive material having a specific surface area of about 600 m 2 /g to about 1000 m 2 /g according to gas adsorption in a solvent to prepare a distributed liquid having a specific surface area of about 60 m 2 /g to about 100 m 2 /g as measured by laser diffraction; adding a negative active material to the distributed liquid to prepare a composition for a negative active material layer; and coating the composition for the negative active material layer on a current collector, wherein the conductive material comprises carbon nanotubes, and wherein the negative active material comprises a silicon-based active material.

7 . The method of preparing a negative electrode for a rechargeable lithium battery of claim 6 , wherein the distributed liquid comprising the conductive material has a concentration of about 0.1 wt % to about 5 wt % based on the total weight of the distributed liquid.

8 . The method of preparing a negative electrode for a rechargeable lithium battery of claim 6 , wherein the silicon-based active material comprises a composite of Si and carbon.

9 . A negative electrode for a rechargeable lithium battery prepared by the method of claim 6 .

10 . A rechargeable lithium battery, comprising:
the negative electrode of claim 1 ; a positive electrode; and an electrolyte.

11 . A rechargeable lithium battery, comprising:
the negative electrode of claim 9 ; a positive electrode; and an electrolyte.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Seol Jongheon
• Kim Minjae
• Kim Soochan
• Jung Hyeseung
• Cho Chaewoong
• Hong Minyoung
• Nam Junghyun
• Han Sungsoo

Classifications

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title