Counterflow adsorption filter column for water treatment
US-11198624-B2 · Dec 14, 2021 · US
US2023071223A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2023071223-A1 |
| Application number | US-202117793807-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jan 20, 2021 |
| Priority date | Jan 20, 2020 |
| Publication date | Mar 9, 2023 |
| Grant date | — |
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The present invention is to provide a novel adsorbent which is low in cost, has versatility and high adsorption ability. Specifically, the present invention is to provide an adsorbent of a specific metal element containing a metal salt of a cyanometallic acid, a method for producing the same, and a method for removing the ion of the element that is the target of adsorption using such an adsorbent.
Opening claim text (preview).
1 . An adsorbent for a metal element other than cesium or strontium, the adsorbent comprising a metal salt of a cyanometallic acid. 2 . The adsorbent according to claim 1 , wherein the metal element is at least one selected from the group consisting of manganese, iron, cobalt, nickel, zinc, ruthenium, rhodium, barium, lanthanum and cerium. 3 . The adsorbent according to claim 1 , wherein the metal salt of a cyanometallic acid is obtained by a reaction of a salt of a cyanometallic acid and a compound comprising a metal element. 4 . The adsorbent according to claim 3 , wherein the reaction is carried out using a porous substance carrying either one of the compound comprising a metal element or the salt of a cyanometallic acid and an aqueous solution of the other, and wherein the metal salt of a cyanometallic acid is formed and fixed inside and outside the porous substance. 5 . The adsorbent according to claim 4 , wherein the porous substance is a hydrophilic fiber. 6 . The adsorbent according to claim 1 , wherein the metal salt of a cyanometallic acid is a first-row transition metal salt of a hexacyanometallic acid. 7 . The adsorbent according to claim 6 , wherein the first-row transition metal is at least one selected from the group consisting of iron, cobalt, copper and zinc. 8 . A method for removing a metal element other than cesium or strontium from water, comprising a step of bringing the adsorbent according to claim 1 into contact with an aqueous sample comprising the metal element. 9 . The method according to claim 8 , wherein the metal element is at least one selected from the group consisting of manganese, iron, cobalt, nickel, zinc, ruthenium, rhodium, barium, lanthanum and cerium. 10 . The method according to claim 8 , further comprising a step of removing the adsorbent.
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