Herbicidal compositions

Patent metadata

Field	Value
Publication number	US-2022386605-A1
Application number	US-202017624108-A
Country	US
Kind code	A1
Filing date	Jun 26, 2020
Priority date	Jul 4, 2019
Publication date	Dec 8, 2022
Grant date	—

Abstract

The present invention provides compositions comprising herbicidally active compounds (A) and (B), wherein (A) represents one or more compounds of the general formula (I) or agrochemically acceptable salts thereof [component (A)],and (B) represents one or more herbicides [component (B)]. The application further relates to a method and to the use of the herbicidal composition of the invention for controlling harmful plants or for regulating growth.

First claim

1 . A composition comprising one or more herbicidally active compounds (A) and (B), wherein
(A) represents one or more compounds of formula (I) or one or more agrochemically acceptable salts thereof [herbicides (A)],

in which

G denotes a group of the formula OR 4 or NR 11 R 12 ;
R 1 and R 2 are each independently hydrogen, halogen or cyano,
or
are (C 1 -C 4 )-alkyl or (C 1 -C 4 )-alkoxy, each substituted by m radicals from the group consisting of halogen and cyano;

R 3 is cyano or fluorine,
or
is (C 1 -C 5 )-alkyl, (C 3 -C 6 )-cycloalkyl, (C 2 -C 5 )-alkenyl, (C 2 -C 5 )-alkynyl or (C 1 -C 5 )-alkoxy, each substituted by m radicals from the group consisting of halogen, cyano, (C 1 -C 5 )-alkoxy and hydroxy;

R 4 is hydrogen,
or
is (C 1 -C 12 )-alkyl, (C 3 -C 7 )-cycloalkyl, (C 3 -C 7 )-cycloalkyl-(C 1 -C 8 )-alkyl, (C 2 -C 8 )-alkenyl, (C 5 -C 6 )-cycloalkenyl or (C 2 -C 8 )-alkynyl, each substituted by m radicals from the group consisting of halogen, cyano, (C 1 -C 6 )-alkoxy, hydroxy and aryl;

Y is oxygen or sulfur;
W is oxygen or sulfur;
Z represents a monounsaturated cyclopentane ring substituted by k radicals from the group of R 10 ,

where the arrow in each case represents a bond to the group C═W of the formula (I);

R 10 is halogen, cyano or CO 2 R 7 ,
or
is (C 1 -C 2 )-alkyl or (C 1 -C 2 )-alkoxy, each substituted by m radicals from the group consisting of fluorine and chlorine;

R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n RS, SO 2 NR 6 R 7 , CO 2 R, CONR 6 R 8 , COR 6 , NR 6 R 8 , NR 6 COR 8 , NR 6 CONR 8 R 8 , NR 6 CO 2 R 8 , NR 6 SO 2 R 8 , NR 6 SO 2 NR 6 R 8 , C(R 6 )═NOR 8 , optionally substituted aryl, optionally substituted heteroaryl or optionally substituted heterocyclyl,
or
are (C 1 -C 12 )-alkyl, (C 3 -C 8 )-cycloalkyl, (C 3 -C 7 )-cycloalkyl-(C 1 -C 7 )-alkyl, (C 2 -C 12 )-alkenyl, (C 5 -C 7 )-cycloalkenyl or (C 2 -C 12 )-alkynyl, each substituted by m radicals from the group consisting of halogen, cyano, nitro, OR 7 , S(O) n R 5 , SO 2 NR 6 R 7 , CO 2 R, CONR 6 R 8 , COR 6 , NR 6 R 8 , NR 6 COR 8 , NR 6 CONR 8 R 8 , NR 6 CO 2 R 8 , NR 6 SO 2 R 8 , NR 6 SO 2 NR 6 R 8 , C(R 6 )═NOR 8 , optionally substituted aryl, optionally substituted heteroaryl and optionally substituted heterocyclyl,
or

R 11 and R 12 together with the nitrogen atom to which they are bonded form a saturated or partly or fully unsaturated five-, six- or seven-membered ring which is optionally mono- to hexasubstituted by radicals from the group consisting of halogen, cyano, nitro, (C 1 -C 6 )-alkyl, halo-(C 1 -C 6 )-alkyl, oxo, OR 7 , S(O) n R 5 , SO 2 NR 6 R 7 , CO 2 R, CONR 6 R 8 , COR 6 , NR 6 R 8 , NR 6 COR 8 , NR 6 CONR 8 R 8 , NR 6 CO 2 R 8 , NR 6 SO 2 R 8 , NR 6 SO 2 NR 6 R 8 and C(R 6 )═NOR 8 and which, in addition to that nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR 7 and NCOR 7 as ring atoms;
X 2 , X 4 and X 6 are each independently hydrogen, halogen or cyano,
or
are (C 1 -C 2 )-alkyl, in each case substituted by m radicals from the group consisting of fluorine, chlorine, bromine and (C 1 -C 2 )-alkoxy;

X 3 and X 5 are each independently hydrogen, fluorine, chlorine, bromine, iodine, hydroxy, cyano, nitro, S(O) n R 6 or CO 2 R 7 ,
or
are (C 1 -C 3 )-alkyl, (C 1 -C 3 )-alkoxy, (C 3 -C 4 )-cycloalkyl, (C 2 -C 3 )-alkenyl or (C 2 -C 3 )-alkynyl, each substituted by m radicals from the group consisting of fluorine, chlorine and bromine;

R 5 is (C 1 -C 8 )-alkyl, (C 3 -C 6 )-cycloalkyl or aryl, each substituted by m radicals from the group consisting of halogen, cyano and hydroxy;
R 6 is hydrogen or R 5 ;
R 7 is hydrogen,
or
is (C 1 -C 6 )-alkyl, (C 3 -C 6 )-cycloalkyl, (C 3 -C 4 )-alkenyl or (C 3 -C 4 )-alkynyl, each substituted by m radicals from the group consisting of halogen, cyano and (C1-C 2 )-alkoxy;

R 8 is hydrogen,
or
is (C 1 -C 8 )-alkyl, (C 3 -C 6 )-cycloalkyl, (C 3 -C 8 )-alkenyl or (C 3 -C 8 )-alkynyl, each substituted by m radicals from the group consisting of halogen, cyano and (C1-C 2 )-alkoxy;

the index k is 0, 1 or 2; where, when k>1, R 10 may independently be the same or different;
the index m is 0, 1, 2, 3, 4 or 5;
the index n is 0, 1 or 2;
the index o is 0, 1 or 2;
the index p is 0 or 1;
the index q is 0 or 1; and
the index r is 3, 4, 5 or 6;
and
(B) represents one or more herbicides [component (B)] from the group of the active herbicidal ingredients (B1) to (B111), in which
(B1) represents active herbicidal ingredients from the group of the 1,3-diketo compounds selected from
(B1.1) alloxydim,
(B11.2) bicyclopyrone,
(B11.3) butroxydim,
(B11.4) clethodim,
(B11.5) cycloxydim,
(B11.6) fenquinotrione,
(B11.7) mesotrione,
(B11.8) pinoxaden,
(B11.9) profoxydim,
(B1.10) sethoxydim,
(B11.11) sulcotrione,
(B1.12) SYP-9121
(B1.13) tefuryltrione,
(B11.14) tembotrione,
(B1.15) tepraloxydim,
(B1.16) tralkoxydim,
(B1.17) Y13161,
(B1.18) Y13287;

(B2) represents active herbicidal ingredients from the group of the (sulfon)amides selected from
(B2.1) acetochlor,
(B2.2) alachlor,
(B2.3) amidosulfuron,
(B2.4) asulam,
(B2.5) azimsulfuron,
(B2.6) beflubutamid,
(B2.7) bensulfuron,
(B2.8) butachlor,
(B2.9) carbetamide,
(B2.10) chlorimuron,
(B2.11) chlorpropham,
(B2.12) chlorsulfuron,
(B2.13) cinosulfuron,
(B2.14) cloransulam,
(B2.15) cyclosulfamuron,
(B2.16) desmedipham,
(B2.17) diclosulam,
(B2.18) diflufenican,
(B2.19) dimethachlor,
(B2.20) dimethenamid,
(B2.21) esprocarb,
(B2.22) ethametsulfuron,
(B2.23) ethoxysulfuron,
(B2.24) flazasulfuron,
(B2.25) florasulam,
(B2.26) flucarbazone,
(B2.27) flucetosulfuron,
(B2.28) flufenacet,
(B2.29) flumetsulam,
(B2.30) flupyrsulfuron,
(B2.31) foramsulfuron,
(B2.32) halosulfuron,
(B2.33) imazosulfuron,
(B2.34) iodosulfuron,
(B2.35) ipfencarbazone,
(B2.36) mefenacet,
(B2.37) mesosulfuron,
(B2.38) metazachlor,
(B2.39) metazosulfuron,
(B2.40) metolachlor,
(B2.41) metosulam,
(B2.42) metsulfuron,
(B2.43) nicosulfuron,
(B2.44) orthosulfamuron,
(B2.45) oxasulfuron,
(B2.46) penoxsulam,
(B2.47) pethoxamide,
(B2.48) phenmedipham,
(B2.49) picolinafen,
(B2.50) pretilachlor,
(B2.51) primisulfuron,
(B2.52) propachlor,
(B2.53) propanil,
(B2.54) propham;
(B2.55) propisochlor,
(B2.56) propoxycarbazone,
(B2.57) propyrisulfuron,
(B2.58) propyzamide,
(B2.59) prosulfocarb,
(B2.60) prosulfuron,
(B2.61) pyrazosulfuron,
(B2.62) pyroxsulam,
(B2.63) rimsulfuron,
(B2.64) S-metolachlor,
(B2.65) sulfometuron,
(B2.66) sulfosulfuron,
(B2.67) thenylchlor,
(B2.68) thiencarbazone,
(B2.69) thifensulfuron,
(B2.70) tri-allate,
(B2.71) triasulfuron,
(B2.72) tribenuron,
(B2.73) trifloxysulfuron,
(B2.74) triflusulfuron,
(B2.75) tritosulfuron,
(B2.76) esprocarb,
(B2.77) profluazol,
(B2.78) tri-allate;

(B3) represents active herbicidal ingredients from the group of the aryl nitriles selected from
(B3.1) bromoxynil,
(B3.2) chlorthiamid,
(B3.3) dichlobenil,
(B3.4) ioxynil,
(B3.5) pyraclonil;

(B4) represents active herbicidal ingredients from the group of the azoles selected from
(B4.1) amicarbazone,
(B4.2) amitrole,
(B4.3) azafenidin,
(B4.4) benzofenap,
(B4.5) benzuofucaotong,
(B4.6) biscarfentrazone,
(B4.7) cafenstrole,
(B4.8) carfentrazone,

Assignees

• Bayer Ag

Inventors

• Lorentz Lothar
• Haaf Klaus Bernhard
• Trabold Klaus
• Menne Hubert
• Gatzweiler Elmar
• Rosinger Christopher Hugh

Classifications

• A01P13/00

  Herbicides; Algicides · CPC title

• A01N43/26 Primary

  five-membered rings · CPC title

• A01P13/02

  selective · CPC title

• A01N43/80 Primary

  five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2 · CPC title