Toner for developing electrostatic charge image, electrostatic charge image developer, method for producing toner for developing electrostatic charge image, toner cartridge, process cartridge, image forming apparatus, and image forming method

Patent metadata

Field	Value
Publication number	US-2022373907-A1
Application number	US-202117405402-A
Country	US
Kind code	A1
Filing date	Aug 18, 2021
Priority date	May 21, 2021
Publication date	Nov 24, 2022
Grant date	—

Abstract

A toner for developing an electrostatic charge image contains toner particles containing at least one binder resin, a release agent, and a coloring agent, and a cross-sectional image of the toner particles meets requirements (1) and (2): requirement (1), an average of ten or more domains, per toner particle, of the release agent have an area of 0.5% or more and 5.0% or less of the area of the toner particle; requirement (2), in a Voronoi tessellation generated from the centroids of the domains of the coloring agent, the mean area of the Voronoi cells is 0.020 μm2 or more and 0.060 μm2 or less, and the standard deviation of the areas of the Voronoi cells is 0.010 μm2 or less.

First claim

What is claimed is:

1 . A toner for developing an electrostatic charge image, the toner comprising toner particles containing at least one binder resin, a release agent, and a coloring agent,
a cross-sectional image of the toner particles meeting requirements (1) and (2):
requirement (1), an average of ten or more domains, per toner particle, of the release agent have an area of 0.5% or more and 5.0% or less of an area of the toner particle;
requirement (2), in a Voronoi tessellation generated from centroids of domains of the coloring agent, a mean area of Voronoi cells is 0.020 μm 2 or more and 0.060 μm 2 or less, and a standard deviation of areas of the Voronoi cells is 0.010 μm 2 or less.

2 . The toner according to claim 1 for developing an electrostatic charge image, wherein the cross-sectional image of the toner particles further meets requirement (3):
requirement (3), of all domains of the coloring agent present in the toner particles, 0% by number or more and less than 5% by number are present in a region from a surface to a depth of 100 nm of the toner particle.

3 . The toner according to claim 1 for developing an electrostatic charge image, wherein the binder resin includes an amorphous polyester resin and a crystalline polyester resin.

4 . The toner according to claim 2 for developing an electrostatic charge image, wherein the binder resin includes an amorphous polyester resin and a crystalline polyester resin.

5 . An electrostatic charge image developer comprising the toner according to claim 1 for developing an electrostatic charge image.

6 . A method for producing a toner for developing an electrostatic charge image, the method comprising:
mixing a plurality of liquid dispersions of binder-resin particles, each of which contains particles of a binder resin, a liquid dispersion of release-agent particles, which contains particles of a release agent, and a liquid dispersion of coloring-agent particles, which contains particles of a coloring agent, together to give a liquid dispersion mixture containing the particles of binder resins, the particles of a release agent, and the particles of coloring agent; forming aggregates by causing the particles of binder resins, the particles of a release agent, and the particles of a coloring agent to aggregate in the liquid dispersion mixture; and forming toner particles by heating a liquid dispersion containing the aggregates and thereby making the aggregates fuse and coalesce, wherein: the liquid dispersions of binder-resin particles include at least two liquid dispersions of amorphous polyester resin particles, each of which contains particles of an amorphous polyester resin; and a difference between D1 and D2 is 30 nm or more and 150 nm or less, where D1 is a volume-average diameter of the particles of an amorphous polyester resin in the liquid dispersion in which the particles of an amorphous polyester resin have a greater diameter than the other of, or a greatest diameter among all of, the at least two, and D2 is a volume-average diameter of the particles of an amorphous polyester resin in the liquid dispersion in which the particles of an amorphous polyester resin have a smaller diameter than the other of, or a smallest diameter among all of, the at least two.

7 . The method according to claim 6 for producing a toner for developing an electrostatic charge image, wherein the volume-average diameter of particles D1 is 130 nm or more and 250 nm or less.

8 . The method according to claim 6 for producing a toner for developing an electrostatic charge image, wherein the volume-average diameter of particles D2 is 50 nm or more and 100 nm or less.

9 . The method according to claim 7 for producing a toner for developing an electrostatic charge image, wherein the volume-average diameter of particles D2 is 50 nm or more and 100 nm or less.

10 . The method according to claim 6 for producing a toner for developing an electrostatic charge image, wherein the liquid dispersions of binder-resin particles further include a liquid dispersion of crystalline polyester resin particles, which contains particles of a crystalline polyester resin.

11 . The method according to claim 7 for producing a toner for developing an electrostatic charge image, wherein the liquid dispersions of binder-resin particles further include a liquid dispersion of crystalline polyester resin particles, which contains particles of a crystalline polyester resin.

12 . The method according to claim 8 for producing a toner for developing an electrostatic charge image, wherein the liquid dispersions of binder-resin particles further include a liquid dispersion of crystalline polyester resin particles, which contains particles of a crystalline polyester resin.

13 . The method according to claim 9 for producing a toner for developing an electrostatic charge image, wherein the liquid dispersions of binder-resin particles further include a liquid dispersion of crystalline polyester resin particles, which contains particles of a crystalline polyester resin.

14 . The method according to claim 6 for producing a toner for developing an electrostatic charge image, wherein a surfactant content of the liquid dispersion of release-agent particles is 1% by mass or more and 5% by mass or less of a mass of the particles of a release agent.

15 . A toner for developing an electrostatic charge image produced by the method according to claim 6 for producing a toner for developing an electrostatic charge image.

16 . An electrostatic charge image developer comprising a toner for developing an electrostatic charge image produced by the method according to claim 6 for a toner for developing an electrostatic charge image.

17 . A toner cartridge that is attached to and detached from an image forming apparatus, the toner cartridge comprising the toner according to claim 1 for developing an electrostatic charge image.

18 . A process cartridge that is attached to and detached from an image forming apparatus, the process cartridge comprising:
a developing component that contains the electrostatic charge image developer according to claim 5 and develops, using the electrostatic charge image developer, an electrostatic charge image on a surface of an image carrier to form a toner image.

19 . An image forming apparatus comprising:
an image carrier; a charging component that charges a surface of the image carrier; an electrostatic charge image creating component that creates an electrostatic charge image on the charged surface of the image carrier; a developing component that contains the electrostatic charge image developer according to claim 5 and develops, using the electrostatic charge image developer, the electrostatic charge image on the surface of the image carrier to form a toner image; a transfer component that transfers the toner image on the surface of the image carrier to a surface of a recording medium; and a fixing component that fixes the toner image on the surface of the recording medium.

20 . An image forming method comprising:
charging a surface of an image carrier; creating an electrostatic charge image on the charged surface of the image carrier; developing, using the electrostatic charge image developer according to claim 5 , the electrostatic charge image on the surface of the image carrier to form a toner image; transferring the toner image on the surface of the image carrier to a surface of a recording medium; and fixing the toner image on the

Assignees

• Fujifilm Business Innovation Corp

Inventors

• Noguchi Daisuke
• Sugawara Atsushi
• Nakamura Kazuhiko
• Nakazawa Hiroshi

Classifications

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08782

  Waxes · CPC title

• G03G9/08755 Primary

  Polyesters · CPC title

• G03G9/0825 Primary

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title