Degradable polymer composition and methods of manufacturing and using in downhole tools

Patent metadata

Field	Value
Publication number	US-2022363802-A1
Application number	US-202117239680-A
Country	US
Kind code	A1
Filing date	Apr 25, 2021
Priority date	Apr 25, 2021
Publication date	Nov 17, 2022
Grant date	—

Abstract

A chemical composition for a degradable polymeric material includes an isocyanate terminated prepolymer, including prepolymer units as a main chain with a plurality of isocynanates at ends of the main chain, a catalyst additive, and a cross-linking agent. The isocyanate terminated prepolymer can be an isocyanate terminated polyester, polycarbonate or polyether prepolymer. The isocyanate terminated prepolymer has a structural formula as follows:
ONC—R″—NH—[—CO—R—CO—O—R′—O—]n—NH—R″—CNO

wherein R, R′ and R″ are an aryl group or alkyl group and wherein n is a number of prepolymer units corresponding to length of the main chain. The composition degrades at a rate and at a delay for failure between 8-72 hours. The composition is a dissolvable rubber material with a modulus and elongation suitable for a component of a downhole tool.

First claim

We claim:

1 . A chemical composition for a degradable polymeric material, the chemical composition comprising:
an isocyanate terminated prepolymer, being comprised of prepolymer units as a main chain with a plurality of isocynanates at ends of said main chain, said isocyanate terminated prepolymer having a structural formula below:

wherein R is an aryl group or alkyl group,
wherein R′ is an aryl group or alkyl group,
wherein R″ is an aryl group or alkyl group,
wherein said isocyanate terminated prepolymer is selected from a group consisting of: an isocyanate terminated polyester prepolymer, an isocyanate terminated polycarbonate prepolymer, and isocyanate terminated polyether prepolymer, and
wherein n is a number of prepolymer units corresponding to length of said main chain;
a catalyst additive being comprised of at least one of a group consisting of a metal oxide and a base additive; and
a cross-linking agent so as to reach fracturing failure between 8-72 hours, display more than 60% weight change within 10 days, and maintain over an 8000 psi pressure differential over 24 hours depending on temperature in water.

2 . The chemical composition of claim 1 , wherein said isocyanates are selected from a group consisting of: 2,4-toluene di-isocyanate, 2,6 toluene di-isocyanate, methylene diphenyl diisocyanate (MDI), para-phenyl diisocyanate (pPDI), and hexamethylene isocyanate (HDI).

3 . The chemical composition of claim 1 , wherein said catalyst is comprised of said metal oxide, said metal oxide being selected from a group consisting of: sodium oxide, potassium oxide, calcium oxide, and magnesium oxide.

4 . The chemical composition of claim 3 , wherein said catalyst is further comprised of said metal oxide and said base additive, said base additive being comprised of a metal hydroxide or a Lewis base.

5 . The chemical composition of claim 4 , wherein said metal hydroxide is selected from a group consisting of: sodium hydroxide, potassium hydroxide, calcium hydroxide, and magnesium hydroxide.

6 . The chemical composition of claim 1 , wherein said catalyst is comprised of said base additive, said base additive being comprised of a metal hydroxide.

7 . The chemical composition of claim 6 , wherein said metal hydroxide is selected from a group consisting of: sodium hydroxide, potassium hydroxide, calcium hydroxide, and magnesium hydroxide.

8 . The chemical composition of claim 1 , wherein said catalyst is comprised of said metal oxide so as to reach fracturing failure between 8-72 hours in aqueous solution between 50-130 degrees Celsius, display more than 60% weight change within 10 days in in aqueous solution between 50-130 degrees Celsius, and maintain over an 8000 psi pressure differential over 24 hours depending in in aqueous solution between 50-130 degrees Celsius.

9 . The chemical composition of claim 8 , wherein said metal oxide being selected from a group consisting of: sodium oxide, potassium oxide, calcium oxide, and magnesium oxide.

10 . The chemical composition of claim 8 , wherein said catalyst is comprised of said metal oxide so as to reach fracturing failure between 24-72 hours in aqueous solution between 50-130 degrees Celsius.

11 . The chemical composition of claim 8 , wherein said catalyst is comprised of said metal oxide so as to have a 100% modulus higher than 400 psi and an elongation higher than 300% between 50-130 degrees Celsius.

12 . The chemical composition of claim 1 , wherein said catalyst is further comprised of said metal oxide and said base additive so as to reach fracturing failure between 8-24 hours in aqueous solution between 40-50 degrees Celsius and maintain over an 8000 psi pressure differential over 24 hours in aqueous solution between 40-50 degrees Celsius.

13 . The chemical composition of claim 12 , wherein said base additive is comprised of a metal hydroxide.

14 . The chemical composition of claim 13 , wherein said metal oxide is selected from a group consisting of: sodium oxide, potassium oxide, calcium oxide, and magnesium oxide.

15 . The chemical composition of claim 13 , wherein said metal hydroxide is selected from a group consisting of: sodium hydroxide, potassium hydroxide, calcium hydroxide, and magnesium hydroxide.

16 . The chemical composition of claim 1 , wherein said catalyst is comprised of said base additive so as to reach fracturing failure between 24-72 hours in hours in aqueous solution between 90-130 degrees Celsius and display more than 60% weight change within 10 days in hours in aqueous solution between 90-130 degrees Celsius.

17 . The chemical composition of claim 16 , wherein said base additive is comprised of a metal hydroxide.

18 . The chemical composition of claim 17 , wherein said metal hydroxide is selected from a group consisting of: sodium hydroxide, potassium hydroxide, calcium hydroxide, and magnesium hydroxide.

19 . A method for formation of a degradable polymeric material, the method comprising the steps of:
vacuuming said isocyanate terminated prepolymer of claim 1 ; vacuuming said cross-linking agent; mixing said isocyanate terminated prepolymer, said catalyst additive, and said cross-linking agent so as to form a mixture; and molding said mixture so as to form a cured polymer as a component.

20 . A method for removal, the method comprising the steps of:
forming a chemical composition according to claim 1 into a component; installing said component in an assembly; dissolving said component in an aqueous solution into a degraded component; and collapsing said assembly so as to remove said assembly and said degraded component.

Assignees

• Cnpc Usa Corp
• Beijing Huamei Inc

Inventors

• Ren Jiaxiang
• Cheng Peng

Classifications

• C08G18/7621

  being toluene diisocyanate including isomer mixtures · CPC title

• C08G18/44

  Polycarbonates · CPC title

• C08G18/7614

  containing only one aromatic ring · CPC title

• C08G2230/00

  Compositions for preparing biodegradable polymers · CPC title

• C08G18/225 Primary

  of alkali or alkaline earth metals · CPC title