Multilayer film and method of making the same

Patent metadata

Field	Value
Publication number	US-2022347982-A1
Application number	US-202017639708-A
Country	US
Kind code	A1
Filing date	Sep 18, 2020
Priority date	Sep 26, 2019
Publication date	Nov 3, 2022
Grant date	—

Abstract

A multilayer film comprises first, second, and third layers. The first layer comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is thermoplastic and has a loss modulus at 1 hertz and 25° C. of less than or equal to 60 megapascals and comprises a thermoplastic elastomer and a polyamide. The third layer contacts the second layer opposite the first layer and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is sandwiched between the first and third layers. A method of making the multilayer film by coextrusion is also disclosed.

First claim

1 - 14 . (canceled)

15 . A multilayer film comprising:
a first layer, wherein the first layer is thermoplastic, comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals; a second layer contacting the first layer, wherein the second layer is thermoplastic and has a loss modulus at 1 hertz and 25° C. of less than or equal to 60 megapascals, and comprises: a thermoplastic elastomer; and a polyamide resin that is a reaction product of: (i) a dicarboxylic acid, wherein the dicarboxylic acid includes a non-aromatic, dicarboxylic dimer acid and the mole fraction of the non-aromatic, dicarboxylic dimer acid is between from 0.10 to 1.00, based on the total moles of dicarboxylic acid used to form the polyamide resin; and (ii) a diamine, and wherein the polyamide resin is amine-terminated and includes amine end-groups; and a third layer contacting the second layer, wherein the third layer is thermoplastic, comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals; and wherein the second layer is sandwiched between the first and third layers.

16 . The multilayer film of claim 15 , wherein the second layer is substantially elastic in response to a tensile elongation of at least 10 percent.

17 . The multilayer film of claim 15 , wherein the multilayer film has a transparency of at least 90 percent if viewed parallel to the thickness of the multilayer film.

18 . The multilayer film of claim 15 , wherein the multilayer film has a transmission haze of less than 5 haze percent if viewed parallel to the thickness of the multilayer film.

19 . The multilayer film of claim 15 , wherein the film is uniaxially-oriented or biaxially-oriented.

20 . The multilayer film of claim 15 , wherein the at least one first thermoplastic polymer comprises polyethylene terephthalate.

21 . The multilayer film of claim 15 , wherein the at least one first thermoplastic polymer comprises a glycol-modified polyethylene terephthalate.

22 . The multilayer film of claim 15 , wherein the at least one first thermoplastic polymer comprises a blend of polyethylene terephthalate and glycol-modified polyethylene terephthalate in a respective weight ratio of 4:1 to 9:1.

23 . The multilayer film of claim 15 , wherein the thermoplastic elastomer comprises at least one of an ionomeric elastomer, a thermoplastic polyurethane elastomer, a thermoplastic polyester elastomer, a thermoplastic copolyesters elastomer, a thermoplastic polyether block amide elastomer, a styrenic block copolymer elastomer, an elastomeric copolymer of ethylene and propylene, or an ethylene-vinyl acetate elastomer.

24 . The multilayer film of claim 15 , further comprising a fourth layer and a fifth layer, wherein the fourth layer is sandwiched between the third layer and the fifth layer, wherein second and fourth layers have the same composition, and wherein the first, third and fifth layers have the same composition.

25 . The multilayer film of claim 24 , further comprising a sixth layer and a seventh layer, wherein the fourth layer is sandwiched between the fifth layer and the seventh layer, wherein second, fourth, and six layers have the same composition, and wherein the first, third, fifth, and seventh layers have the same composition.

26 . The multilayer film of claim 15 , wherein the number average molecular weight of the non-aromatic, dicarboxylic dimer acid is between from 300 g/mol to 1400 g/mol.

27 . The multilayer film of claim 26 , wherein the number of carbon atoms in the non-aromatic, dicarboxylic dimer acid is between from 12 to 100.

28 . A method of making a multilayer film, the method comprising coextruding first, second, and third layers, wherein:
the first layer is thermoplastic, comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals; the second layer contacts the first layer, and wherein the second layer is thermoplastic and has a loss modulus at 1 hertz and 25° C. of less than or equal to 60 megapascals, and comprises:
a thermoplastic elastomer; and
a polyamide resin that is a reaction product of:
(i) a dicarboxylic acid, wherein the dicarboxylic acid includes a non-aromatic, dicarboxylic dimer acid and the mole fraction of the non-aromatic, dicarboxylic dimer acid is between from 0.10 to 1.00, based on the total moles of dicarboxylic acid used to form the polyamide resin; and
(ii) a diamine, and wherein the polyamide resin is amine-terminated and includes amine end-groups; and
the third layer that is thermoplastic, has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals, and comprises at least one aromatic polyester; and wherein the second layer is sandwiched between the first and third layers.

Assignees

• 3M Innovative Properties Company

Inventors

• Perez Mario A
• Johansen Mary E
• Goris Sebastian
• Giron Lesbia E
• Kalgutkar Rajdeep S
• Yu Ta-Hua
• Hines Paul T
• Johnson Stephen A

Classifications

• B32B2307/5825

  Tear resistant · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title

• B32B2535/00

  Medical equipment, e.g. bandage, prostheses or catheter · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B2250/24

  All layers being polymeric · CPC title