Method for manufacturing a polyacrylonitrile-sulfur composite material
US-10096834-B2 · Oct 9, 2018 · US
US2022340693A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2022340693-A1 |
| Application number | US-202017763839-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 14, 2020 |
| Priority date | Sep 27, 2019 |
| Publication date | Oct 27, 2022 |
| Grant date | — |
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The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).
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1 . A method of producing sulfur-modified polyacrylonitrile, comprising: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container comprising a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1). 2 . The method of producing sulfur-modified polyacrylonitrile according to claim 1 , wherein a ratio between the polyacrylonitrile and the elemental sulfur is as follows: 100 parts by mass to 1,500 parts by mass of the elemental sulfur with respect to 100 parts by mass of the polyacrylonitrile. 3 . The method of producing sulfur-modified polyacrylonitrile according to claim 1 , wherein the polyacrylonitrile and the elemental sulfur each have a particle diameter of from 1 μm to 1,000 μm in terms of an average particle diameter. 4 . The method of producing sulfur-modified polyacrylonitrile according to claim 1 , wherein the polyacrylonitrile and the elemental sulfur each have a particle diameter of from 1 μm to 1,000 μm in terms of an average particle diameter.
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