(6z,9z)-6,9-dodecadien-1-yne and a process for preparing the same

US2022332667A1 · US · A1

Patent metadata
FieldValue
Publication numberUS-2022332667-A1
Application numberUS-202217718376-A
CountryUS
Kind codeA1
Filing dateApr 12, 2022
Priority dateApr 14, 2021
Publication dateOct 20, 2022
Grant date

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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Abstract

Official abstract text for this publication.

The present invention provides (6Z,9Z)-6,9-dodecadien-1-yne of the following formula (1). Further, the present invention provides a process for preparing (6Z,9Z)-6,9-dodecadien-1-yne (1): the process comprising reacting a (3Z,6Z)-10-halo-3,6-decadiene compound of the following general formula (2), wherein X represents a halogen atom with a metal acetylide of the following general formula (3), wherein M represents Na, Li, K, Ag, Cu (I), MgZ, CaZ, or Cu(II)Z, wherein Z represents a halogen atom or an ethinyl group to form (6Z,9Z)-6,9-dodecadien-1-yne (1).

First claim

Opening claim text (preview).

1 . (6Z,9Z)-6,9-dodecadien-1-yne of the following formula (1): 2 . A process for preparing (6Z,9Z)-6,9-dodecadien-1-yne of the following formula (1): the process comprising: reacting a (3Z,6Z)-10-halo-3,6-decadiene compound of the following general formula (2): wherein X represents a halogen atom with a metal acetylide of the following general formula (3): MC≡CH  (3) wherein M represents Na, Li, K, Ag, Cu (I), MgZ, CaZ, or Cu(II)Z, wherein Z represents a halogen atom or an ethinyl group to form (6Z,9Z)-6,9-dodecadien-1-yne (1). 3 . A process for preparing (8Z,11Z)-8,11-tetradecadien-3-yn-1-ol of the following formula (4): the process comprising: reacting (6Z,9Z)-6,9-dodecadien-1-yne (1) with a base; and subjecting a reaction mixture thus obtained to a homologation reaction with ethylene oxide to form (8Z,11Z)-8,11-tetradecadien-3-yn-1-ol (4). 4 . A process for preparing (3E,8Z,11Z)-3,8,11-tetradecatrien-1-ol of the following formula (5): the process comprising: the process according to claim 3 for preparing (8Z,11Z)-8,11-tetradecadien-3-yn-1-ol (4); and subjecting (8Z,11Z)-8,11-tetradecadien-3-yn-1-ol (4) to a reduction reaction to form (3E, 8Z, 11Z)-3,8,11-tetradecatrien-1-ol (5). 5 . A process for preparing (3E,8Z,11Z)-3,8,11-tetradecatrienyl acetate of the following formula (6): wherein Ac represents an acetyl group, the process comprising: the process according to claim 4 for preparing (3E,8Z,11Z)-3,8,11-tetradecatrien-1-ol (5); and acetylating (3E,8Z,11Z)-3,8,11-tetradecatrien-1-ol (5) to form (3E,8Z,11Z)-3,8,11-tetradecatrienyl acetate (6).

Assignees

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Classifications

  • by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

  • the hetero-atom being a metal atom · CPC title

  • by hydrogenation of carbon-to-carbon double or triple bonds · CPC title

  • increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal · CPC title

  • C07C11/28Primary

    containing carbon-to-carbon double bonds and carbon-to-carbon triple bonds · CPC title

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What does patent US2022332667A1 cover?
The present invention provides (6Z,9Z)-6,9-dodecadien-1-yne of the following formula (1). Further, the present invention provides a process for preparing (6Z,9Z)-6,9-dodecadien-1-yne (1): the process comprising reacting a (3Z,6Z)-10-halo-3,6-decadiene compound of the following general formula (2), wherein X represents a halogen atom with a metal acetylide of the following general formula (3), w…
Who is the assignee on this patent?
Shinetsu Chemical Co
What technology area does this patent fall under?
Primary CPC classification C07C11/28. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Thu Oct 20 2022 00:00:00 GMT+0000 (Coordinated Universal Time) (A1). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 6 related publications on this page (citations in our corpus or others sharing the same primary CPC).