Methods of fabrication of ceramic mirror blanks

Patent metadata

Field	Value
Publication number	US-2022314488-A1
Application number	US-202217704087-A
Country	US
Kind code	A1
Filing date	Mar 25, 2022
Priority date	Mar 30, 2021
Publication date	Oct 6, 2022
Grant date	—

Abstract

The disclosure relates to methods of fabricating of ceramic structures, and more particularly to methods of fabricating ceramic structures having profiled surfaces and more particularly to methods of fabrication of ceramic mirror blanks. In one embodiment, a method of forming a shaped ceramic article, includes: forming, via one of a cold-pressing process or pressure casting process, a green ceramic article comprising a first surface, an opposing second surface and at least one high aspect ratio feature shaped into at least one surface; heating the green featured ceramic part to form a debound featured ceramic part; and densifying the debound featured ceramic part via one of a pressureless sintering process or a hot-pressing process.

First claim

What is claimed is:

1 . A method of forming a featured ceramic article, the method comprising:
forming a green pressed ceramic body comprising a first surface, an opposing second surface and at least one feature shaped into at least one surface, wherein forming the green pressed ceramic body comprises:
placing a first wax mold having at least one feature within a cavity of a pressing die,
pouring ceramic powder within the cavity wherein the ceramic powder at least completely covers the first wax mold,
applying about 30 MPa to about 130 MPa of pressure to the ceramic powder within the cavity to form the green pressed body, and
removing the wax mold and green pressed body from the cavity, and
separating the first wax mold and the green pressed body;
heating the green pressed body to form a debound featured ceramic part; and densifying the debound featured ceramic part via a hot-pressing process, wherein the hot-pressing process comprises:
inserting the debound featured ceramic part into a hot-pressing die,
pouring a first layer of fill material into the hot-pressing die, the first layer of fill material having compression characteristics during hot pressing that are within about 10% of the compression characteristics of the adjacent debound featured ceramic part, wherein the fill material completely fills the at least one features,
applying a first pressure to the debound featured ceramic part in a direction perpendicular to the first surface,
applying a second pressure to the debound featured ceramic part in a direction perpendicular to the second surface while applying the first pressure,
heating the debound featured ceramic part while applying the first pressure and second pressure to compress the debound featured ceramic part in a direction of the thickness of the featured ceramic part,
removing the sintered featured ceramic part from the hot-pressing die, and
removing the fill material powder to expose the at least one features.

2 . The method of claim 1 , further comprising: placing a second wax mold having at least one feature atop the ceramic powder within the cavity of the pressing die to form a green pressed body having the at least one feature on the first surface and at least one feature on the second surface.

3 . The method of claim 2 , wherein the hot-pressing process further comprises:
pouring a second layer of fill material into the hot-pressing die, prior to inserting the debound featured ceramic part into a hot-pressing die the second layer of fill material having compression characteristics during hot pressing that are within about 10% of the compression characteristics of the adjacent debound featured ceramic part.

4 . The method of claim 1 , wherein the hot-pressing process further comprises:
depositing a release layer onto the first surface of the debound featured ceramic part, wherein the release layer comprises a liquid binder and a fill material, after inserting the debound featured ceramic part into a hot-pressing die.

5 . The method of claim 4 , wherein the release layer has a thickness of about 1 mm to 2 mm

6 . The method of claim 4 , wherein the fill material is the ceramic powder.

7 . The method of claim 1 , wherein separating the first wax mold and the green pressed body comprises:
heating the green pressed body to a temperature of about 60 degrees Celsius to about 130 degrees Celsius to melt the wax mold; and applying an external pressure to at least one external surface of the green pressed body during heating to prevent crack formation.

8 . A method of forming a shaped ceramic article, the method comprising:
forming, via a pressure casting process, a green ceramic body comprising a first surface, an opposing second surface and at least one feature shaped into at least one surface, wherein the pressure casting process comprises:
pumping a ceramic solution comprising a liquid component and a solid component into a mold cavity comprising at least one featured surface, wherein the mold cavity is defined by a porous top surface wall, a porous bottom surface wall and porous sidewalls, and wherein the liquid component of the ceramic solution flows through the porous walls of the mold cavity and the solid component remains within the mold cavity to pressure cast the green featured ceramic body,
removing the green ceramic body from the mold cavity, and
heating the green ceramic body to form a debound featured ceramic part; densifying the debound featured ceramic part via a hot-pressing process, wherein the hot-pressing process comprises:
inserting the debound featured ceramic part into a hot-pressing die,
pouring a first layer of fill material into the hot-pressing die, the fill material having compression characteristics during hot pressing within about 10% of the compression characteristics of the adjacent debound featured ceramic part, wherein the fill material fills the at least one features,
applying a first pressure to the debound featured ceramic part in a direction perpendicular to the first surface,
applying a second pressure to the debound featured ceramic part in a direction perpendicular to the second surface while applying the first pressure,
heating the debound featured ceramic part while applying the first pressure and second pressure to compress the debound featured ceramic part in a direction of the thickness of the featured ceramic part,
removing the sintered featured ceramic part from the hot-pressing die, and
removing the fill material powder to expose the features of the ceramic part.

9 . The method of claim 8 , wherein the mold cavity comprises a first featured surface and an opposing second featured surface.

10 . The method of claim 8 , wherein the hot-pressing process further comprises:
depositing a release layer onto the first surface of the debound featured ceramic part, wherein the release layer comprises a liquid binder and a fill material, prior to pouring a first layer of fill material into the hot-pressing die.

11 . The method of claim 10 , wherein the release layer has a thickness of about 1 mm to 2 mm.

12 . The method of claim 8 , wherein separating the first wax mold and the green ceramic body comprises: heating the green body to a temperature of about 60 degrees Celsius to about 130 degrees Celsius to melt the wax mold; and applying an external pressure to at least one external surface of the green pressed body during heating to prevent crack formation.

13 . A method of forming a shaped ceramic article, the method comprising:
forming a green pressed ceramic body comprising a first surface, an opposing second surface and at least one feature shaped into at least one surface, wherein forming the green pressed ceramic body comprises:
placing a first wax mold having at least feature within a cavity of a pressing die,
pouring ceramic powder within the cavity wherein the ceramic powder at least completely covers the first wax mold,
applying about 30 MPa to about 130 MPa of pressure to the ceramic powder within the cavity to form a green pressed body, and
separating the first wax mold and the green pressed body:
heating the green pressed body to form a debound featured ceramic part; and densifying the debound featured ceramic part via a pressureless sintering process, wherein the pressureless sintering process comprises heating the debound featured ceramic part at a temperature of about 2000 degrees Celsius to about 2400 degrees Celsius in an inert gas atmosphere.

14 . The method of claim 12 , further comprising: placing a second wax mold having at least one feature atop the ceramic powder within the cavi

Assignees

• Corning Inc

Inventors

• Conway Bethany Rose
• Force Robin May
• Sutherland James Scott
• Zimmermann James William

Classifications

• B28B3/003 Primary

  Pressing by means acting upon the material via flexible mould wall parts, e.g. by means of inflatable cores, isostatic presses (isostatic presses in general B30B5/02) · CPC title

• C04B35/62802

  Powder coating materials · CPC title

• C04B35/645

  Pressure sintering · CPC title

• B28B11/243

  Setting, e.g. drying, dehydrating or firing ceramic articles (B28B11/242 takes precedence) · CPC title

• B28B1/004

  Devices for shaping artificial aggregates from ceramic mixtures or from mixtures containing hydraulic binder (from slag C04B5/00; composition of artificial aggregates C04B18/02) · CPC title