Preparing method of electrostatic charge image developing toner, electrostatic charge image developing toner, and electrostatic charge image developer

Patent metadata

Field	Value
Publication number	US-2022308479-A1
Application number	US-202117375103-A
Country	US
Kind code	A1
Filing date	Jul 14, 2021
Priority date	Mar 23, 2021
Publication date	Sep 29, 2022
Grant date	—

Abstract

A preparing method of an electrostatic charge image developing toner includes: mixing an amorphous resin particle dispersion containing amorphous resin particles and a crystalline resin particle dispersion containing crystalline resin particles to prepare a mixed dispersion containing the amorphous resin particles and the crystalline resin particles; aggregating the amorphous resin particles and the crystalline resin particles in the mixed dispersion to form aggregated particles; and coalescing the aggregated particles by heating a dispersion containing the aggregated particles to form toner particles, in which both a zeta potential of the amorphous resin particle dispersion and a zeta potential of the crystalline resin particle dispersion are negative values, and an absolute value of the zeta potential of the crystalline resin particle dispersion is smaller than an absolute value of the zeta potential of the amorphous resin particle dispersion.

First claim

What is claimed is:

1 . A preparing method of an electrostatic charge image developing toner, the method comprising:
mixing an amorphous resin particle dispersion containing amorphous resin particles and a crystalline resin particle dispersion containing crystalline resin particles to prepare a mixed dispersion containing the amorphous resin particles and the crystalline resin particles; aggregating the amorphous resin particles and the crystalline resin particles in the mixed dispersion to form aggregated particles; and coalescing the aggregated particles by heating a dispersion containing the aggregated particles to form toner particles, wherein both a zeta potential of the amorphous resin particle dispersion and a zeta potential of the crystalline resin particle dispersion are negative values, and an absolute value of the zeta potential of the crystalline resin particle dispersion is smaller than an absolute value of the zeta potential of the amorphous resin particle dispersion.

2 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein a difference D 1 between a value of the zeta potential of the amorphous resin particle dispersion and a value of the zeta potential of the crystalline resin particle dispersion is 10 mV or more and 50 mV or less.

3 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein a value of the zeta potential of the amorphous resin particle dispersion is −70 mV or more and −30 mV or less, and a value of the zeta potential of the crystalline resin particle dispersion is −30 mV or more and −10 mV or less.

4 . The preparing method of an electrostatic charge image developing toner according to claim 2 ,
wherein a value of the zeta potential of the amorphous resin particle dispersion is −70 mV or more and −30 mV or less, and a value of the zeta potential of the crystalline resin particle dispersion is −30 mV or more and −10 mV or less.

5 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein the mixing includes adjusting a pH of the mixed dispersion to 4.5 or more and 6.0 or less.

6 . The preparing method of an electrostatic charge image developing toner according to claim 2 ,
wherein the mixing includes adjusting a pH of the mixed dispersion to 4.5 or more and 6.0 or less.

7 . The preparing method of an electrostatic charge image developing toner according to claim 3 ,
wherein the mixing includes adjusting a pH of the mixed dispersion to 4.5 or more and 6.0 or less.

8 . The preparing method of an electrostatic charge image developing toner according to claim 4 ,
wherein the mixing includes adjusting a pH of the mixed dispersion to 4.5 or more and 6.0 or less.

9 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

10 . The preparing method of an electrostatic charge image developing toner according to claim 2 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

11 . The preparing method of an electrostatic charge image developing toner according to claim 3 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

12 . The preparing method of an electrostatic charge image developing toner according to claim 4 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

13 . The preparing method of an electrostatic charge image developing toner according to claim 5 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

14 . The preparing method of an electrostatic charge image developing toner according to claim 6 ,
wherein the aggregating includes
adding an aggregating agent to the mixed dispersion, and
increasing a temperature of the mixed dispersion after adding the aggregating agent to the mixed dispersion at a heating rate of 0.2° C./min or less.

15 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein the amorphous resin particles include amorphous polyester resin particles, and the crystalline resin particles include crystalline polyester resin particles.

16 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein in the mixing, a weight ratio between the amorphous resin particles and the crystalline resin particles contained in the mixed dispersion is amorphous resin particles:crystalline resin particles=97:3 to 70:30.

17 . The preparing method of an electrostatic charge image developing toner according to claim 1 ,
wherein in the mixing, at least one of a release agent particle dispersion containing release agent particles or a coloring agent particle dispersion containing coloring agent particles is further mixed, and the mixed dispersion further containing at least one of the release agent particles or the coloring agent particles is prepared, and in the aggregating, at least one of the release agent particles or the coloring agent particles is further aggregated to form the aggregated particles.

18 . The preparing method of an electrostatic charge image developing toner according to claim 1 , further comprising:
after the aggregating, second aggregating of further mixing a dispersion containing the aggregated particles and a dispersion containing resin particles to be a shell layer and aggregating the resin particles to be the shell layer on surfaces of the aggregated particles to form second aggregated particles, wherein in the coalescing, a dispersion containing the second aggregated particles is heated and the second aggregated particles are coalesced to form toner particles.

19 . An electrostatic charge image developing toner which is prepared by the preparing method of an electrostatic charge image developing toner according to claim 1 .

20 . An electrostatic charge image developer comprising an electrostatic charge image developing toner which is prepared by the preparing method of an electrostatic charge image developing toner according to claim 1 .

Assignees

• Fujifilm Business Innovation Corp

Inventors

• Sugawara Atsushi
• Noguchi Daisuke
• Nakamura Kazuhiko
• Nakazawa Hiroshi

Classifications

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/0804 Primary

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/08755

  Polyesters · CPC title