Resistive heating reactors for high temperature co2 upgrading

Patent metadata

Field	Value
Publication number	US-2022287155-A1
Application number	US-202117193937-A
Country	US
Kind code	A1
Filing date	Mar 5, 2021
Priority date	Mar 5, 2021
Publication date	Sep 8, 2022
Grant date	—

Abstract

A product includes a three-dimensional resistive heating element formed by additive manufacturing and a catalytic component on at least an external surface of the resistive heating element. The resistive heating element has a pre-defined geometric arrangement of features, and the resistive heating element includes a conductive ceramic material.

First claim

What is claimed is:

1 . A product, comprising:
a resistive heating reactor comprising:
a three-dimensional resistive heating element formed by additive manufacturing, wherein the resistive heating element has a pre-defined geometric arrangement of features, wherein the resistive heating element comprises a conductive ceramic material; and
a catalytic component on at least an external surface of the resistive heating element.

2 . The product as recited in claim 1 , wherein the catalytic component is integrated into the resistive heating element.

3 . The product as recited in claim 1 , wherein an amount of catalytic component is in a range of greater than 0.1 weight percent to less than 50 weight percent of total weight of the resistive heating element and the catalytic component.

4 . The product as recited in claim 1 , wherein the catalytic component is in a coating on only a portion of a surface of the resistive heating element.

5 . The product as recited in claim 4 , wherein a thickness of the coating is in a range of greater than 0 nanometers and less than 50 microns.

6 . The product as recited in claim 4 , wherein the coating on only the portion of the surface of the resistive heating element is at a pre-defined location.

7 . The product as recited in claim 1 , wherein the catalytic component is selected from the group consisting of: a metal, a metal oxide, a reducible metal oxide, a metal carbide, a perovskite, a zeolite, a metal organic framework (MOF), and a combination thereof.

8 . The product as recited in claim 7 , wherein the catalytic component is in nanoparticle form.

9 . The product as recited in claim 1 , wherein the melting point of the conductive ceramic material is greater than 1800 degrees Celsius.

10 . The product as recited in claim 1 , wherein the conductive ceramic material includes at least one material selected from the group consisting of: a metal carbide, a metalloid carbide, a metal boride, a metalloid boride, a metal oxide, a metalloid oxide, a metal nitride, a metalloid nitride, a metal silicide, and a combination thereof.

11 . The product as recited in claim 1 , wherein the pre-defined geometric arrangement of features comprises an open cell structure having continuous channels through the resistive heating element from one side of the resistive heating element to the other side of the resistive heating element.

12 . The product as recited in claim 11 , wherein the open cell structure is selected from the group consisting of: a Triply Periodic Minimal Structure (TPMS), a log-pile structure, a hollow cylinder, and a gyroid type structure.

13 . A method of forming a product for high temperature conversion of one or more reactants, the method comprising:
fabricating a resistive heating reactor using, at least in part, additive manufacturing, wherein the resistive heating reactor comprises a conductive ceramic material and a catalytic component.

14 . The method as recited in claim 13 , wherein fabricating the resistive heating reactor comprises,
forming a resistive heating element; and coating the resistive heating element with the catalytic component.

15 . The method as recited in claim 14 , wherein the coating forms a layer of catalytic component directly on a surface of the resistive heating element, wherein a thickness of the layer is in a range of greater than 0 nanometers to less than 50 microns.

16 . The method as recited in claim 13 , wherein fabricating the resistive heating reactor comprises,
printing a resistive heating element using one or more inks.

17 . The method as recited in claim 13 , wherein fabricating the resistive heating reactor comprises,
obtaining an already manufactured resistive heating element; and printing the catalytic component onto a surface of the already manufactured resistive heating element.

18 . The method as recited in claim 13 , wherein the catalytic component is selected from the group consisting of: a metal, a metal oxide, a reducible metal oxide, a metal carbide, a perovskite, a zeolite, a metal organic framework (MOF), and a combination thereof.

19 . The method as recited in claim 13 , wherein the melting point of the conductive ceramic material is greater than 1800 degrees Celsius.

20 . The method as recited in claim 13 , wherein the conductive ceramic material includes at least one material selected from the group consisting of: a metal carbide, a metalloid carbide, a metal boride, a metalloid boride, a metal oxide, a metalloid oxide, a metal nitride, a metalloid nitride, a metal silicide, and a combination thereof.

21 . The method as recited in claim 13 , wherein the additive manufacturing technique includes a technique selected from the group consisting of: an extrusion-based technique, a powder bed-based technique, a material jetting technique, a sheet lamination technique, an electrostatic deposition technique, a laser fusion technique, use of a mold, and use of a template.

22 . A method of using a ceramic resistive heating reactor for converting one or more reactants, the method comprising:
applying a current to the ceramic resistive heating reactor for heating the ceramic resistive heating reactor to a pre-defined temperature, wherein the ceramic resistive heating reactor comprises a catalytic component; contacting the one or more reactants with the catalytic component for causing a reaction to form at least one product by flowing the one or more reactants across the heated ceramic resistive heating reactor; and collecting the at least one product.

23 . The method as recited in claim 22 , wherein the pre-defined temperature is in a range of greater than about 100 degrees Celsius to about 1500 degrees Celsius.

24 . The method as recited in claim 22 , wherein at least one of the one or more reactants is selected from the group consisting of: a gas, a liquid, a solid dissolved in a liquid, a first liquid dissolved in a second liquid, a gas dissolved in a liquid, a gas entrained in a liquid, a solid entrained in a liquid, a solid fluidized in a gas, and a combination thereof.

25 . The method as recited in claim 22 , wherein the ceramic resistive heating reactor is configured to form at least one product selected from the group consisting of: CO, CH 4 , H 2 O, H 2 , and O 2 .

Assignees

• L Livermore Nat Security Llc

Inventors

• Pang Simon Hoching
• Haslam Jeffery J
• Kelly James Patrick
• Stolaroff Joshuah K

Classifications

• C04B2235/6021

  Extrusion moulding · CPC title

• H05B2203/017

  Manufacturing methods or apparatus for heaters · CPC title

• H05B3/22

  non-flexible · CPC title

• H05B3/141 Primary

  Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds · CPC title

• B01J35/45

  Nanoparticles · CPC title