Reactor for the hydrothermal treatment of biomass

Patent metadata

Field	Value
Publication number	US-2022267687-A1
Application number	US-202017636382-A
Country	US
Kind code	A1
Filing date	Aug 20, 2020
Priority date	Aug 21, 2019
Publication date	Aug 25, 2022
Grant date	—

Abstract

The present invention concerns a reactor and a process for the hydrothermal treatment of an aqueous mixture, such as watery biomass. The reactor according to the invention comprises ( 31 ) an inlet for receiving the aqueous mixture, ( 32 ) a tube-shaped reactor interior, which is inclined at an angle in the range of 1-45°; ( 33 ) a first zone in the reactor interior ( 32 ) comprising means ( 5 ) for heating the aqueous mixture; ( 34 ) a second zone in the reactor interior ( 32 ) for keeping the aqueous mixture at the predetermined temperature; ( 35 ) a third zone in the reactor interior ( 32 ) for cooling the aqueous mixture; ( 38 ) an outlet for discharging a hydrothermally treated aqueous mixture, and ( 43 ) an outlet for discharging gas, wherein inlet ( 31 ) and outlet ( 43 ) are positioned at the top part of the reactor and outlet ( 38 ) at the bottom part of the reactor. The inclined nature of the reactor ensures that all gases are efficiently removed from the liquid effluent, and the CO 2 formed during the process is used to improved efficacy of the hydrothermal treatment.

First claim

1 - 15 . (canceled)

16 . A hydrothermal reactor, comprising:
an inlet for receiving an aqueous mixture, positioned at the top part of the reactor interior; a tube-shaped reactor interior, which is inclined at an angle in the range of 1-45°; a first zone in the reactor interior comprising means for heating the aqueous mixture to a predetermined temperature; a second zone in the reactor interior for keeping the aqueous mixture at the predetermined temperature; a third zone in the reactor interior for cooling the aqueous mixture; an outlet for discharging a hydrothermally treated aqueous mixture, positioned at the bottom part of the reactor interior; and an outlet for discharging gas, positioned at the top part of the reactor interior.

17 . The reactor according to claim 16 , wherein the inclination angle of the reactor interior is in the range of 2-15°.

18 . The reactor according to claim 16 , further comprising an expansion vessel positioned at the top part of first zone, wherein the outlet is integrated in the expansion vessel.

19 . The reactor according to claim 18 , wherein the expansion vessel comprises a sensor for determining the liquid level within the expansion vessel.

20 . The reactor according to claim 16 , wherein the outlet comprises a valve which can be opened and closed during operation.

21 . The reactor according to claim 16 , wherein the reactor comprises a heat exchanger for heating the aqueous mixture in the first zone and for cooling the aqueous mixture in the third zone.

22 . The reactor according to claim 16 , wherein the reactor is capable at operating at a predetermined temperature in the range of 160-320° C. and a pressure in the range of 10-50 bar.

23 . The reactor according to claim 22 , wherein the reactor is capable at operating at a predetermined temperature in the range of 175-230° C. and a pressure in the range of 15-30 bar.

24 . The reactor according to claim 16 , which is contained in a hydrothermal treatment facility comprising:
( 1 ) a buffer tank for holding an aqueous mixture that is to be treated; ( 2 ) a pump for pumping an aqueous mixture from the buffer tank to a reactor; ( 3 ) the reactor according to claim 16 ; and ( 4 ) an expansion vessel positioned at the top part of the reactor, wherein the outlet is integrated in the expansion vessel.

25 . The reactor according to claim 24 , wherein the hydrothermal treatment facility further comprises a dewatering device for dewatering the liquid effluent discharged via outlet and a digester for digesting the aqueous mixture before it is subjected to the reactor or after it has been dewatered in the dewatering device.

26 . A process for hydrothermally treating an aqueous mixture in the reactor according to claim 16 , comprising:
(a) feeding the aqueous mixture into the reactor interior via inlet, (b) allowing a downward flow of the aqueous mixture through the reactor interior, while heating the aqueous mixture to a predetermined temperature in the first zone, keeping the aqueous mixture at the predetermined temperature in the second zone, and cooling the aqueous mixture in the third zone, as such hydrothermally treating the aqueous mixture; (c) discharging a hydrothermally treated mixture via outlet, (d) discharging gas via outlet.

27 . The process according to claim 26 , wherein the aqueous mixture is watery biomass.

28 . The process according to claim 27 , wherein the aqueous mixture is selected from sludge, manure, dredging waste, food production waste and garden waste.

29 . The process according to claim 28 , wherein the aqueous mixture is sludge obtained from a wastewater treatment process.

30 . The process according to claim 26 , wherein the gas that is discharged via a gas outlet is further treated by a method for capture of H 2 S and other sulfurous compounds.

31 . The process according to claim 26 , wherein the reactor operates in cycles, each cycle comprising while continuously feeding the aqueous mixture during step (a):
(1) a first stage wherein the outlet is closed, no hydrothermally treated mixture is discharged, and the pressure within the reactor increases from an initial pressure to a final pressure, (2) a second stage wherein the outlet is open, hydrothermally treated mixture is discharged, and the pressure within the reactor decreases from the final pressure to the initial pressure.

32 . The process according to claim 31 , wherein the first stage lasts 70-99% of the cycle duration and the second stage lasts the remaining cycle duration.

33 . The process according to claim 31 , wherein the cycle duration is in the range of 5 minutes-2 hours.

34 . The process according to claim 31 , wherein the initial pressure is in the range of 10-30 bar and the final pressure is in the range of 20-50 bar, wherein the initial pressure is higher than the final pressure.

35 . The process according to claim 34 , wherein the initial pressure is at least 5 bar higher than the final pressure.

Assignees

• TNO

Inventors

• Van Der Meijden Christiaan Martinus
• Pels Jan Remmert

Classifications

• C10J2300/0923

  Sludge, e.g. from water treatment plant · CPC title

• B01J19/241 Primary

  of the pulsating type · CPC title

• B01J2204/005

  the outlet side being of particular interest · CPC title

• B01J4/007

  provided with moving parts · CPC title

• B01J2219/00182

  controlling the level of reactants in the reactor vessel · CPC title