Capacitor with electrodes made of an interconnected corrugated carbon-based network

Patent metadata

Field	Value
Publication number	US-2022238284-A1
Application number	US-202217568214-A
Country	US
Kind code	A1
Filing date	Jan 4, 2022
Priority date	Mar 5, 2012
Publication date	Jul 28, 2022
Grant date	—

Abstract

Capacitors having electrodes made of interconnected corrugated carbon-based networks (ICCNs) are disclosed. The ICCN electrodes have properties that include high surface area and high electrical conductivity. Moreover, the electrodes are fabricated into an interdigital planar geometry with dimensions that range down to a sub-micron scale. As such, micro-supercapacitors employing ICCN electrodes are fabricated on flexible substrates for realizing flexible electronics and on-chip applications that can be integrated with micro-electromechanical systems (MEMS) technology and complementary metal oxide semiconductor technology in a single chip. In addition, capacitors fabricated of ICCN electrodes that sandwich an ion porous separator realize relatively thin and flexible supercapacitors that provide compact and lightweight yet high density energy storage for scalable applications.

First claim

1 . A micro-supercapacitor comprising:
a. a first electrode; b. a second electrode; c. a first conductor interfaced with the first electrode; d. a second conductor interfaced with the second electrode; e. a non-conductive liner contacting at least a portion of the first conductor and the second conductor; and f. an electrolyte in contact with the first electrode and the second electrode, wherein at least one of the first electrode or the second electrode comprises an interconnected corrugated carbon-based network (ICCN) having a plurality of expanded and interconnected carbon layers.

2 . The micro-supercapacitor of claim 1 , wherein the non-conductive liner contacting at least the portion of the first conductor and the second conductor provides an electrical terminal configured to be coupled to external circuitry.

3 . The micro-supercapacitor of claim 1 , wherein the non-conductive liner seals the electrolyte within the micro-supercapacitor device.

4 . The micro-supercapacitor of claim 1 , wherein the non-conductive liner contacts at least a portion of the first electrode or the second electrode.

5 . The micro-supercapacitor of claim 1 , wherein the non-conductive liner comprises a central window.

6 . The micro-supercapacitor of claim 1 , wherein the electrolyte comprises a gel electrolyte.

7 . The micro-supercapacitor of claim 1 , wherein the electrolyte comprises fumed silica (FS) nano-powder mixed with an ionic liquid.

8 . The micro-supercapacitor of claim 1 , wherein the electrolyte comprises 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide.

9 . The micro-supercapacitor of claim 1 , wherein the electrolyte comprises a hydrogel electrolyte.

10 . The micro-supercapacitor of claim 1 , wherein the electrolyte comprises poly(vinyl alcohol) (PVA)-H 2 SO 4 .

11 . The micro-supercapacitor of claim 10 , wherein the micro-supercapacitor is a solid state micro-supercapacitor.

12 . The micro-supercapacitor of claim 1 , wherein the first conductive strip or the second conductive strip comprises copper (Cu), aluminum (Al), or an ICCN structure.

13 . The micro-supercapacitor of claim 1 , wherein the first electrode comprises a first plurality of electrode digits, wherein the second electrode comprises a second plurality of electrode digits, and wherein the first plurality of electrode digits of the first electrode and the second plurality of electrode digits of the second electrode are woven in an interdigitating pattern.

14 . The micro-supercapacitor of claim 13 , further comprising an interspace distance between the interdigitating pattern of the first electrode and the second electrode of about 150 micrometers.

15 . The micro-supercapacitor of claim 1 , wherein the first electrode or the second electrode comprises 4, 8, or 16 electrode digits.

16 . The micro-supercapacitor of claim 1 wherein the first electrode or the second electrode comprises widths from about 330 micrometer to about 1770 micrometers.

17 . The micro-supercapacitor of claim 1 , further comprising a total area of less than about 50 square millimeters, 40 square millimeters, or 30 square millimeters.

18 . The micro-supercapacitor of claim 1 , wherein the first electrode or the second electrode comprises an edge dimension of from about 220 micrometers to about 1770 micrometers.

19 . The micro-supercapacitor of claim 1 , wherein the micro-supercapacitor is comprised within an integrated circuit package or a nanoelectromechanical device.

20 . The micro-supercapacitor of claim 1 , wherein the micro-supercapacitor exhibits a nearly triangular CC curve when operated at a first current density of about 1.684×10 4 mA/cm 3 , wherein the micro-supercapacitor exhibits a stack capacitance of around about 3.05 F/cm 3 at 16.8 mA/cm 3 , and wherein the micro-supercapacitor maintains about 60% of the stack capacitance when operated at a second current density of about 1.84×10 4 mA/cm 3 .

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Strong Veronica A
• Kaner Richard B

Classifications

• Y02E60/13

  Energy storage using capacitors · CPC title

• Y02T10/70

  Energy storage systems for electromobility, e.g. batteries · CPC title

• H01G11/56

  Solid electrolytes, e.g. gels; Additives therein · CPC title

• H01G11/32 Primary

  Carbon-based · CPC title

• H01G11/24

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title