Electrolytic reduction system and method of vanadium electrolyte

Patent metadata

Field	Value
Publication number	US-2022216495-A1
Application number	US-202217567966-A
Country	US
Kind code	A1
Filing date	Jan 4, 2022
Priority date	Jan 4, 2021
Publication date	Jul 7, 2022
Grant date	—

Abstract

Disclosed are an electrolytic reduction system of a vanadium electrolyte and a method for producing the electrolyte. The electrolytic reduction system includes a separating device and an electrolytic tank. The separating device is configured to separate a mixture consisting of a vanadium pentoxide (V2O5) solid and a sulfate acid solution, thereby obtaining a vanadium solution from a liquid discharging port of the separating device and a vanadium solid from a solid discharging port. The vanadium solution includes pentavalent vanadium ions. The electrolytic tank connects to the liquid discharging port of the separating device to contain the vanadium solution. In the method for producing the vanadium electrolyte, other chemical reagents are unnecessarily to be added into the mixture, and the vanadium solution is subjected to an electrolytic reduction process, such that the pentavalent vanadium ions are reduced to tetravalent vanadium ions and trivalent vanadium ions in the electrolytic tank.

First claim

What is claimed is:

1 . A method for producing a vanadium electrolyte, comprising the following steps:
mixing a vanadium pentoxide solid with a first sulfuric acid liquid to form a mixture consisting of part of the vanadium pentoxide solid and a sulfuric acid solution, the sulfuric acid solution containing pentavalent vanadium ions; performing a separating process on the mixture to separate the part of the vanadium pentoxide solid from the sulfuric acid solution; and performing an electrolytic reduction process on the sulfuric acid solution to reduce the pentavalent vanadium ions to tetravalent vanadium ions and trivalent vanadium ions, a molar ratio of the tetravalent vanadium ions to the trivalent vanadium ions being in a range of 1:0 to 0:1, most preferably (1+/−0.1):(1+/−0.1).

2 . The method for producing a vanadium electrolyte according to claim 1 , wherein the separating process is performed by a cyclone separator.

3 . The method for producing a vanadium electrolyte according to claim 1 , wherein before the electrolytic reduction process is performed, the producing method further comprises: performing a filtering process to filter the sulfuric acid solution.

4 . The method for producing a vanadium electrolyte according to claim 1 , wherein the electrolytic reduction process comprises:
performing a feeding step to introduce the sulfuric acid solution into a vanadium solution sub-tank of an electrolytic tank, and introduce a second sulfuric acid liquid into a sulfuric acid sub-tank of the electrolytic tank; after performing the feeding step, performing an electrolytic reduction step on the sulfuric acid solution, so as to form a reduced solution from the sulfuric acid solution; and performing a detecting step on the reduced solution to determine a vanadium ion composition of the reduced solution, wherein if a molar number of the tetravalent vanadium ions is greater than a molar number of the trivalent vanadium ions, performing the electrolytic reduction step; if the molar number of the tetravalent vanadium ions is less than the molar number of the trivalent vanadium ions, performing an electrolytic oxidation step; and if the molar number of the tetravalent vanadium ions is equal to the molar number of the trivalent vanadium ions, the vanadium electrolyte is produced.

5 . The method for producing a vanadium electrolyte according to claim 4 , wherein the detecting step is to determine the vanadium ion composition of the reduced solution by measuring a voltage of the reduced solution.

6 . An electrolytic reduction system of a vanadium electrolyte, comprising:
a separating device, configured to separate a mixture consisting of a vanadium pentoxide solid and a sulfuric acid solution, thereby obtaining a vanadium solution from a liquid discharging port of the separating device and a vanadium solid from a solid discharging port of the separating device, the vanadium solution containing pentavalent vanadium ions; and an electrolytic tank, comprising a separating membrane, the separating membrane separating the electrolytic tank into a vanadium solution sub-tank and a sulfuric acid sub-tank, the vanadium solution sub-tank connecting to the liquid discharging port to contain the vanadium solution, the electrolytic tank being configured to reduce the pentavalent vanadium ions in the vanadium solution to tetravalent vanadium ions and trivalent vanadium ions, and a molar ratio of the tetravalent vanadium ions to the trivalent vanadium ions being in a range of 1:0 to 0:1, most preferably (1+/−0.1):(1+/−0.1).

7 . The electrolytic reduction system of a vanadium electrolyte according to claim 6 , wherein the separating device is a cyclone separator.

8 . The electrolytic reduction system of a vanadium electrolyte according to claim 6 , further comprising: a filtering device comprising a liquid inlet and a filtrate outlet, the liquid inlet connecting to the liquid discharging port, the filtrate outlet connecting to the vanadium solution sub-tank, and the filtering device being configured to filter the vanadium solution.

9 . The electrolytic reduction system of a vanadium electrolyte according to claim 8 , wherein the filtering device further comprises: a counterflow circuit comprising a counterflow feeding pipe and a counterflow discharging pipe, the counterflow feeding pipe connecting to the liquid discharging port of the separating device and the filtrate outlet, and the counterflow discharging pipe connecting to a feeding port of the separating device and the liquid inlet.

10 . The electrolytic reduction system of a vanadium electrolyte according to claim 6 , wherein the vanadium solution sub-tank further comprises a voltage detector, and the voltage detector is configured to measure a voltage of the vanadium solution to detect the molar ratio of the tetravalent vanadium ions to the trivalent vanadium ions.

Assignees

• Iner Aec Executive Yuan

Inventors

• Hsieh Chin-Lung
• Lu Cian-Tong
• Chang Ya-Hsin
• Hsueh Kan-Lin

Classifications

• H01M2300/0011

  Sulfuric acid-based · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• Y02E60/50

  Fuel cells · CPC title

• C25C7/02 Primary

  Electrodes (consumable anodes for the refining the metals C25C1/00 - C25C5/00); Connections thereof · CPC title

• C25C7/04

  Diaphragms; Spacing elements · CPC title