Treatment solution for chromium-free tension coating, method for forming chromium-free tension coating, and grain oriented electrical steel sheet with chromium-free tension coating
US-2018371621-A1 · Dec 27, 2018 · US
US2022162759A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2022162759-A1 |
| Application number | US-202217667029-A |
| Country | US |
| Kind code | A1 |
| Filing date | Feb 8, 2022 |
| Priority date | Aug 30, 2016 |
| Publication date | May 26, 2022 |
| Grant date | — |
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Provided are coated metal, the metal having improved properties due to a novel coating, a coating-forming treatment solution for forming the novel coating, and a method for producing the coated metal that has the novel coating. The coated metal includes metal and a coating formed on the metal. The coating includes Si, P, and O, and at least one selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn. The coating includes a compound having a NASICON-type crystal structure represented by the general formula M I M IV 2 (M V O 4 ) 3 .
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1 . A coating-forming treatment solution comprising: at least one metal phosphate selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn; colloidal silica; and a compound having a NASICON-type crystal structure represented by the general formula M I M IV 2 (M V O 4 ) 3 , wherein, in the general formula M I M VI 2 (M V O 4 ) 3 , M I is at least one selected from the group consisting of Li, Na, K, 1/2Mg, 1/2Ca, 1/2Sr, and 1/4Zr, M IV is at least one selected from the group consisting of Zr, Ge, Ti, Hf, Cr+Na, Nb—Na, and Y+Na, and M V is at least one selected from the group consisting of P, As, and Si+Na.
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