Curable Composition

Patent metadata

Field	Value
Publication number	US-2022162360-A1
Application number	US-202017436245-A
Country	US
Kind code	A1
Filing date	Oct 16, 2020
Priority date	Oct 16, 2019
Publication date	May 26, 2022
Grant date	—

Abstract

The present application relates to a curable composition and a use thereof. The present application can provide a curable composition that has excellent reliability including excellent light resistance, where such excellent reliability can be stably maintained for a long period of time even under severe conditions, and a use thereof. The curable composition comprises a polymer component and a curing agent, wherein the polymer component includes an alkyl (meth)acrylate unit having a straight or branched alkyl group and a unit of a compound of Formula 1 below, and has a weight average molecular weight of 2,200,000 or more:wherein, R1 is an alkylene group having 3 or more carbon atoms, and R2 is hydrogen or an alkyl group having 1 to 4 carbon atoms.

First claim

1 . A curable composition comprising a polymer component and a curing agent,
wherein the polymer component comprises an alkyl (meth)acrylate unit having a straight or branched alkyl group and a unit of a compound of Formula 1 below and has a weight average molecular weight of 2,200,000 or more,

wherein in Formula 1, R 1 is an alkylene group having 3 or more carbon atoms, and R 2 is hydrogen or an alkyl group having 1 to 4 carbon atoms.

2 . The curable composition according to claim 1 , wherein the polymer component comprises 5 to 60 parts by weight of the unit of the compound of Formula 1 relative to 100 parts by weight of the alkyl (meth)acrylate unit having a straight or branched alkyl group.

3 . The curable composition according to claim 1 , wherein the polymer component further comprises a unit of a compound of Formula 2 below:

wherein in Formula 2, R 3 is a methylene group or an ethylene group, and R 2 is hydrogen or an alkyl group having 1 to 4 carbon atoms.

4 . The curable composition according to claim 3 , wherein the unit of the compound of Formula 2 is included in an amount of 0.5 to 50 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate unit having a straight or branched alkyl group, and the weight ratio of the unit of the compound of Formula 1 to the unit of the compound of Formula 2 is in a range of 0.01 to 20.

5 . The curable composition according to claim 1 , wherein the polymer component further comprises a unit of a compound of Formula 3 below:

wherein, R is hydrogen or an alkyl group, and Q is a monovalent substituent having a non-aromatic ring structure with 3 to 20 carbon atoms.

6 . The curable composition according to claim 5 , wherein the unit of the compound of Formula 3 is included in an amount of 40 to 150 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate unit having a straight or branched alkyl group.

7 . The curable composition according to claim 1 , wherein the curing agent comprises two or more selected from the group consisting of a polyfunctional acrylate having a molar mass of 500 g/mol or less, a polyfunctional isocyanate compound and a polyfunctional urethane acrylate.

8 . The curable composition according to claim 1 , wherein the curing agent is included in a range of 0.01 to 10 parts by weight relative to 100 parts by weight of the polymer component.

9 . The curable composition according to claim 1 , wherein the curing agent comprises a polyfunctional acrylate having a molar mass of 500 g/mol or less and a polyfunctional urethane acrylate.

10 . The curable composition according to claim 9 , wherein the polyfunctional urethane acrylate is included in a ratio within a range of 0.5 parts by weight to 10 parts by weight relative to 100 parts by weight of the polymer component, and the weight ratio (C of the polyfunctional urethane acrylate (C) to the polyfunctional acrylate having a molar mass of 500 g/mol or less is in a range of 20 to 60.

11 . The curable composition according to claim 1 , further comprising one or more selected from the group consisting of a silane coupling agent, a radical initiator, an antioxidant, an antistatic agent, an ultraviolet absorber and a tackifier.

12 . A pressure-sensitive adhesive which is a cured product of a curable composition, and has a gel fraction of 80% or more, herein the curable composition comprises a polymer component and a curing agent, wherein the polymer component comprises an alkyl (meth)acrylate unit having a straight or branched alkyl group and a unit of a compound of Formula 1 below and having a weight average molecular weight of 2,200,000 or more,

wherein, R 1 is an alkylene group having 3 or more carbon atoms, and R 2 is hydrogen or an alkyl group having 1 to 4 carbon atoms.

13 . The pressure-sensitive adhesive according to claim 12 , wherein the pressure-sensitive adhesive has a room temperature storage modulus in a range of 0.05 MPa to 0.2 MPa.

14 . A display device comprising the pressure-sensitive adhesive of claim 12 .

15 . The curable composition according to claim 1 , wherein the alkyl (meth)acrylate unit is included in the polymer component in a ratio of about 20 to 70 wt %.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Byeong Ho
• Kim Won Ho
• Song Ho Kyung
• Seo Kwang Su
• Shin Hwan Ho

Classifications

• C09J4/06

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00 · CPC title

• C09J133/06

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• C09J133/066 Primary

  containing -OH groups · CPC title

• C08F220/20 Primary

  of polyhydric alcohols or phenols {, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate} · CPC title

• C09J2301/312

  parameters being the characterizing feature · CPC title