Catalyst system for producing aromatic amines

Patent metadata

Field	Value
Publication number	US-2022161237-A1
Application number	US-202017602887-A
Country	US
Kind code	A1
Filing date	Apr 1, 2020
Priority date	Apr 12, 2019
Publication date	May 26, 2022
Grant date	—

Abstract

The invention relates to a catalyst system suitable for hydrogenating aromatic nitro compounds (I) to form the corresponding aromatic amines (II), the catalyst system containing, as essential constituents: a component A selected from the group consisting of silicon carbide, corundum (alpha-Al2O3) and slightly porous to non-porous zirconium oxide (ZrO2); and a component B, containing B1—a carrier substance selected from the group consisting of silicon dioxide, gamma-, delta- or theta-aluminum oxide Al2O3, titanium dioxide, zirconium dioxide and graphite, B2—a metal or a plurality of metals selected from the group consisting of copper, nickel, palladium, platinum and cobalt, and optionally B3—an additional metal selected from the group consisting of at least one metal selected from main group I, main group II, main group IV and sub-groups II, V, VI and VIII of the periodic table of the elements, the proportion of component A being in the range of 5 to 60 wt %, in relation to the total weight of the catalyst system, and the aromatic nitro compounds (I) being those of the general formula R—(NO2)n, (I), and the aromatic amines (II) being those of the general formula R—(NH2)n, (II), and the moieties R and indices n in formulas (I) and (II) having the following meaning: R is a substituted or unsubstituted aromatic C6-C10 moiety and n is an integer from 1 to 5.

First claim

1 .- 14 . (canceled)

15 . A catalyst system suitable for the hydrogenation of aromatic nitro compounds (I) to the corresponding aromatic amines (II), comprising as essential constituents a component A selected from the group consisting of silicon carbide, corundum (alpha-Al 2 O 3 ) and low-porosity to non-porous zirconium oxide (ZrO 2 ) and a component B comprising B1 a support material selected from the group consisting of silica, gamma-, delta- or theta-alumina Al 2 O 3 , titanium dioxide, zirconium dioxide, and graphite and B2 one or more metals selected from the group consisting of copper, nickel, palladium, platinum, and cobalt, and optionally B3 a further metal selected from the group consisting of at least one metal selected from main group I, main group II, main group IV, and subgroups II, V, VI, and VIII of the periodic table of the elements, wherein the proportion of component A is within a range from 5% to 60% by weight based on the total weight of the catalyst system and where the aromatic nitro compounds (I) are those of the general formula R—(NO 2 ) n (I), the aromatic amines (II) are those of the general formula R—(NH 2 ) n (II), and the radicals R and indices n in formulas (I) and (II) are defined as follows: R is a substituted or unsubstituted aromatic C 6 to C 10 radical and n is an integer from 1 to 5.

16 . The catalyst system according to claim 15 , wherein component A is a constituent of component B1.

17 . The catalyst system according to claim 15 , wherein component A comprises silicon carbide.

18 . The catalyst system according to claim 15 , wherein component A comprises exclusively silicon carbide.

19 . The catalyst system according to claim 15 , wherein component B2 comprises copper.

20 . The catalyst system according to claim 15 , wherein component B2 comprises exclusively copper.

21 . The catalyst system according to claim 15 , wherein component A comprises exclusively silicon carbide and component B2 comprises exclusively copper.

22 . The catalyst system according to claim 15 , wherein component A is a constituent of component B1, component A comprises exclusively silicon carbide, and component B2 comprises exclusively copper.

23 . A process for producing a catalyst system as defined in claim 15 , by
i) producing a support material B1 comprising a component selected from the group consisting of silica, gamma-, delta- or theta-alumina Al 2 O 3 , titanium dioxide, zirconium dioxide, and graphite and contacting this support material with one or more metals B2 selected from the group consisting of copper, nickel, palladium, platinum, and cobalt, and optionally with B3 selected from the group consisting of at least one metal selected from main group I, main group II, main group IV, and subgroups II, V, VI, and VIII of the periodic table of the elements and combining this with a component A selected from the group consisting of silicon carbide, corundum (alpha-Al 2 O 3 ) and low-porosity to non-porous zirconium oxide (ZrO 2 ) or ii) producing a support material B1 comprising iia) a component selected from the group consisting of silica, gamma-, delta- or theta-alumina Al 2 O 3 , titanium dioxide, zirconium dioxide, and graphite and component A selected from the group consisting of silicon carbide, corundum (alpha-Al 2 O 3 ) and low-porosity to non-porous zirconium oxide (ZrO 2 ) and contacting this support material with one or more metals B2 selected from the group consisting of copper, nickel, palladium, platinum, and cobalt, and optionally with B3 selected from the group consisting of at least one metal selected from main group I, main group II, main group IV and subgroups II, V, VI, and VIII of the periodic table of the elements.

24 . The catalyst system obtainable by the process according to claim 23 .

25 . A method comprising utilizing the catalyst system as defined in claim 15 for producing aromatic amines (II) through hydrogenation of aromatic nitro compounds (I).

26 . A process for producing aromatic amines (II) through catalytic hydrogenation of the corresponding aromatic nitro compound (II), wherein a catalyst system as defined in claim 15 is used.

27 . The process according to claim 26 , wherein the process is executed in the fluidized bed.

28 . The process according to claim 26 , wherein the aromatic amine compound (II) is aniline and the corresponding aromatic nitro compound (I) is nitrobenzene.

Assignees

• Basf Se

Inventors

• Wloka Veronika
• Garella Dominik
• Reiser Michael
• Heidemann Thomas
• De Winne Hendrik

Classifications

• C07C211/46

  Aniline · CPC title

• B01J37/0207

  Pretreatment of the support · CPC title

• C07C209/36

  by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings {in presence of hydrogen-containing gases and a catalyst} · CPC title

• B01J38/12

  Treating with free oxygen-containing gas · CPC title

• B01J23/72 Primary

  Copper · CPC title