System and method for production of synthetic fuel through co2 capture and water splitting

Patent metadata

Field	Value
Publication number	US-2022118406-A1
Application number	US-202017428965-A
Country	US
Kind code	A1
Filing date	Feb 5, 2020
Priority date	Feb 5, 2019
Publication date	Apr 21, 2022
Grant date	—

Abstract

A system for producing gas streams for use in synthetic fuel production through CO2 capture and water splitting is disclosed. The system includes a CO2 capture device configured to receive a CO2-containing stream and including an aqueous alkaline solution. The alkaline solution includes hydroxide and/or carbonate ions. The CO2 capture device generates a carbon-rich solution when the alkaline solution absorbs CO2. The carbon-rich solution includes carbonate and/or bicarbonate ions. The system also includes an electrolyzer fluidically coupled to the CO2 capture device, and defining a volume including an anode region having an anode, and a cathode region having a cathode. The volume includes an electrolyte solution having a pH gradient generated by an electric current, causing the electrolyte solution to be acidic in the anode region and alkaline in the cathode region. The carbon-rich solution is received into the electrolyzer. The electrolyzer generates hydrogen, oxygen, and CO2 streams.

First claim

1 . A system for producing gas streams for use in synthetic fuel production through CO 2 capture and water splitting, comprising:
a CO 2 capture device configured to receive a CO 2 -containing stream and comprising an aqueous alkaline solution, the aqueous alkaline solution comprising hydroxide ions and/or carbonate ions, the CO 2 capture device generating a carbon-rich solution when the aqueous alkaline solution absorbs CO 2 received from the CO 2 -containing stream, the carbon-rich solution including carbonate ions and/or bicarbonate ions; an electrolyzer fluidically coupled to the CO 2 capture device, the electrolyzer defining a volume including an anode region having an anode, a cathode region having a cathode, the volume comprising an electrolyte solution having a pH gradient generated by the application of an electric current between the anode and the cathode, causing the electrolyte solution in the anode region to be acidic and the electrolyte solution in the cathode region to be alkaline, wherein the carbon-rich solution is received into the volume of the electrolyzer; and wherein the electrolyzer generates a hydrogen product stream, an oxygen product stream, and a CO 2 product stream.

2 . (canceled)

3 . The system of claim 1 , wherein the electrolyte solution comprises Na+ and/or K+ as a dominant cation.

4 - 8 . (canceled)

9 . The system of claim 1 , wherein the electrolyzer delivers the aqueous alkaline solution back to the CO 2 capture device after making the aqueous alkaline solution carbon-lean by generating the CO 2 product stream.

10 - 15 . (canceled)

16 . The system of claim 1 , wherein the cathode region of the electrolyzer is separated from a neutral region of the electrolyzer by a first divider, wherein the neutral region is between the cathode region and anode region.

17 . The system of claim 16 , wherein the anode region of the electrolyzer is separated from the neutral region of the electrolyzer by a second divider.

18 . The system of claim 17 , wherein the first divider and/or the second divider comprise a material that substantially prevents fluid circulation across the first divider and/or the second divider without substantially preventing electric ionic currents from crossing through the material.

19 - 20 . (canceled)

21 . The system of claim 16 , wherein the first divider comprises a cationic membrane that substantially prevents fluid flow and anion flow across the first divider.

22 - 28 . (canceled)

29 . The system of claim 1 , wherein the electrolyzer is disposed in a pressurized housing, and wherein the hydrogen product stream, the CO 2 product stream and the oxygen product stream are produced by the electrolyzer at a pressure greater than about 1 bar absolute.

30 - 32 . (canceled)

33 . The system of claim 1 , further comprising a conduit, the conduit placing the output of the electrolyzer in the cathode region in fluid communication with the CO 2 capture apparatus.

34 . The system of claim 33 , wherein the conduit is a first conduit, further comprising a second conduit, the second conduit placing the CO 2 capture apparatus in fluid communication with the volume of the electrolyzer.

35 - 44 . (canceled)

45 . An electrolyzer, comprising:
a volume having a cathode region, an anode region, and a neutral region between the cathode region and the anode region; an electrolyte solution inside the volume having a pH gradient when an electric current is applied to the electrolyzer such that the electrolyte solution has a pH of less than about 6 in the anode region, a pH of greater than about 5 in the cathode region, and a pH of between about 6 and about 13 in the neutral region; an output in the cathode region configured to remove an alkaline-rich solution from the electrolyzer; and an input configured to supply a carbon-rich solution to the electrolyzer.

46 . The electrolyzer of claim 45 , wherein the alkaline-rich solution comprises hydroxide ions and/or carbonate ions.

47 . The electrolyzer of claim 45 , wherein the carbon-rich solution comprises carbonate ions and/or bicarbonate ions.

48 - 51 . (canceled)

52 . The electrolyzer of claim 45 , further comprising a cathodic head space over at least part of the cathode region, wherein the electrolyzer produces CO 2 gas in the neutral region, and a CO 2 gas stream exits the electrolyzer via the cathodic head space.

53 - 56 . (canceled)

57 . The electrolyzer of claim 45 , wherein the electrolyte of the anode region comprises dissolved sulfate ions, suflite ions, and/or phosphate ions.

58 . The electrolyzer of claim 45 , wherein the input is fluidically coupled to a distributor disposed between the anode region and the neutral region, the distributor having a plurality of holes facing toward the neutral region and away from the cathode region.

59 - 72 . (canceled)

73 . A method for producing gas streams for use in synthetic fuel production through CO 2 capture and water-splitting, comprising:
exposing an aqueous alkaline solution comprising hydroxide ions to a CO 2 -containing gas region; capturing CO 2 from the CO 2 -containing gas region with the aqueous alkaline solution, forming a second solution comprising at least one of carbonate ions and bicarbonate ions; introducing the second solution to an electrolyte composition within an electrolytic water-splitting cell, the electrolyte composition being acidic in an anode region of the cell and alkaline in a cathode region of the cell; energizing the electrolytic water-splitting cell to produce hydrogen, oxygen, and CO 2 product streams, and to generate the aqueous alkaline solution in the cathode region; and transporting the aqueous alkaline solution to the CO 2 -containing gas region through a conduit that fluidically connects the cathode region and the CO 2 -containing gas region.

74 - 77 . (canceled)

78 . The method of claim 73 , further comprising:
expelling the CO 2 product stream and the hydrogen product stream via a cathodic head space.

79 . The method of claim 78 , wherein the cathodic head space is maintained at a pressure between about 1 bar and about 3 bar absolute.

80 . The method of claim 73 , further comprising:
expelling the oxygen product stream via an anodic head space.

81 - 83 . (canceled)

Assignees

• Univ Arizona State

Inventors

• Lackner Klaus

Classifications

• B01D2251/306

  of potassium · CPC title

• B01D2251/606

  Carbonates · CPC title

• C25B9/19

  with diaphragms · CPC title

• B01D2251/404

  of calcium · CPC title

• C25B15/087

  Recycling of electrolyte to electrochemical cell · CPC title