Single atom catalyst having a two dimensional support material

Patent metadata

Field	Value
Publication number	US-2022111358-A1
Application number	US-202017423491-A
Country	US
Kind code	A1
Filing date	Feb 18, 2020
Priority date	Feb 19, 2019
Publication date	Apr 14, 2022
Grant date	—

Abstract

A method for forming a single atom catalyst on a two-dimensional support material involves providing the two-dimensional support material. The two-dimensional support material is combined with at least two heteroatoms and a metal to form a solution. Liquid is removed from the solution to form a material that includes the two-dimensional support material, the at least two heteroatoms, and the metal. The material including the two-dimensional support material, the at least two heteroatoms, and the metal is heated to form the single atom catalyst that includes single atoms of the metal. The at least two heteroatoms bind the single atoms of the metal to, and stabilize the single atoms of the metal on, the two-dimensional support material.

First claim

1 . A method for forming a single atom catalyst on a two-dimensional support material, the method comprising:
providing the two-dimensional support material; combining the two-dimensional support material with at least two heteroatoms and a metal to form a solution; removing liquid from the solution to form a material comprising the two-dimensional support material, the at least two heteroatoms, and the metal; and heating the material comprising the two-dimensional support material, the at least two heteroatoms, and the metal to form the single atom catalyst comprising single atoms of the metal, wherein the at least two heteroatoms bind the single atoms of the metal to, and stabilize the single atoms of metal on, the two-dimensional support material.

2 . The method of claim 1 , wherein the liquid is removed from the solution by freeze-drying, which forms a foam comprising the two-dimensional support material, the at least two heteroatoms, and the metal.

3 . The method of claim 1 , wherein the heating comprises annealing.

4 . The method of claim 1 , wherein the two-dimensional support material is an MXene and the provision of the two-dimensional support material comprises forming the MXene from a MAX phase material, wherein M is a transition metal, A is a main group element, and X is carbon or nitrogen.

5 . The method of claim 4 , wherein the MAX phase material is titanium aluminum carbide, Ti 3 AlC 2 , and the MXene is titanium carbide T x , Ti 3 C 2 T x wherein T x is a functional group element.

6 . The method of claim 5 , wherein the metal is ruthenium.

7 . The method of claim 6 , wherein a first one of the at least two heteroatoms is sulfur and a second one of the at least two heteroatoms is nitrogen.

8 . The method of claim 5 , wherein the metal is platinum.

9 . A single atom catalyst, comprising:
a two-dimensional support material; at least one single atom metal; and first and second heteroatoms binding the at least one single atom metal to, and stabilizing the at least one single atom metal on, the two-dimensional support material.

10 . The single atom catalyst of claim 9 , wherein the two-dimensional support material is graphene.

11 . The single atom catalyst of claim 9 , wherein the two-dimensional support material is an MXene.

12 . The single atom catalyst of claim 11 , wherein the MXene is titanium carbide T x , Ti 3 C 2 T x .

13 . The single atom catalyst of claim 9 , wherein the at least one single atom metal is ruthenium or platinum.

14 . The single atom catalyst of claim 13 , wherein the first heteroatom is sulfur and the second heteroatom is nitrogen.

15 . The single atom catalyst of claim 9 , wherein the first heteroatom bound to the first single atom metal is one of a plurality of first heteroatoms bound to one of a plurality of first single atom metals and the second heteroatom bound to the second single atom metal is one of a plurality of second heteroatoms bound to one of a plurality of second single atom metals, and wherein the plurality of first heteroatoms bound to one of the plurality of first single atom metals and the plurality of second heteroatoms bound to one of the plurality of second single atom metals are distributed across the two-dimensional support material.

16 . A water splitting device, comprising:
a metal anode; and a semiconductor photocathode, spaced apart from the metal anode and having a first side facing the metal anode, wherein the first side of the photocathode comprises a single atom catalyst comprising
a two-dimensional support material;
at least one single atom metal; and
first and second heteroatoms binding the at least one single atom metal to, and stabilizes the at least one single atom metal on, the two-dimensional support material.

17 . The water splitting device of claim 16 , wherein the semiconductor photocathode is a n+np+-Si photocathode and the first side of the semiconductor photocathode comprises an n+ silicon layer on which the single atom catalyst is arranged.

18 . The water spitting device of claim 16 , wherein the semiconductor photocathode includes a metallic contact that is electrically connected to the metal anode.

19 . The water splitting device of claim 16 , wherein the two-dimensional support material is a titanium carbide T x , Ti 3 C 2 T x MXene.

20 . The water splitting device of claim 19 , wherein the at least one single atom metal is ruthenium, the first heteroatom is sulfur, and the second heteroatom is nitrogen.

Assignees

• Univ King Abdullah Sci & Tech

Inventors

• He Jr-Hau
• Ramalingam Vinoth
• Varadhan Purushothaman
• Fu hui-chun

Classifications

• B01J27/24

  Nitrogen compounds · CPC title

• B01J27/22

  Carbides · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C25B11/067

  Inorganic compound e.g. ITO, silica or titania · CPC title

• C25B11/091

  consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds · CPC title