Method for producing acrylic block copolymer pellets
US-2021115197-A1 · Apr 22, 2021 · US
US2022106503A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2022106503-A1 |
| Application number | US-201917273569-A |
| Country | US |
| Kind code | A1 |
| Filing date | Aug 30, 2019 |
| Priority date | Sep 5, 2018 |
| Publication date | Apr 7, 2022 |
| Grant date | — |
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A laminate production method is provided which can sufficiently prevent the occurrence of blocking without causing deterioration in the outstanding characteristics of acrylic block copolymers such as adhesive performance, and can also ensure excellent processability during extrusion. The laminate production method includes a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) including at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock including the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate including the adhesive layer and a substrate layer.
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1 . A laminate production method comprising a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) comprising at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock comprising the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate comprising the adhesive layer and a substrate layer. 2 . The laminate production method according to claim 1 , wherein the adhesive layer and the substrate layer are both formed by extrusion in the step (3). 3 . A laminate production method comprising a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) comprising at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), a step (2′) of bringing additional acrylic resin particles (B) into contact with the pellets (D) and thereby obtaining pellets (D′), and a step (3′) of preparing an adhesive composition using an adhesive feedstock comprising the pellets (D′) from the step (2′), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate comprising the adhesive layer and a substrate layer. 4 . The laminate production method according to claim 3 , wherein the adhesive layer and the substrate layer are both formed by extrusion in the step (3′). 5 . The laminate production method according to claim 3 , wherein the adhesive composition is prepared in the step (3′) by melt kneading of an adhesive feedstock comprising the pellets (D) and the pellets (D′). 6 . A laminate production method comprising a step of preparing an adhesive composition using an adhesive feedstock comprising pellets (D), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate comprising the adhesive layer and a substrate layer, wherein the pellets (D) are pellets obtained through a step of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) comprising at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, and the pellets (D) are such that the acrylic resin particles (B) are attached to the acrylic block copolymer (A). 7 . The laminate production method according to claim 1 , wherein the aqueous dispersion (C) comprises at least one selected from the group consisting of an aqueous dispersion (C-1) containing wet-ground acrylic resin particles (B), and an aqueous dispersion (C-2) containing dry-ground acrylic resin particles (B). 8 . The laminate production method according to claim 7 , wherein the aqueous dispersion (C) comprises an aqueous dispersion (C-1) containing wet-ground acrylic resin particles (B). 9 . The laminate production method according to claim 3 , wherein the aqueous dispersion (C) comprises at least one selected from the group consisting of an aqueous dispersion (C-1) containing wet-ground acrylic resin particles (B), and an aqueous dispersion (C-2) containing dry-ground acrylic resin particles (B). 10 . The laminate production method according to claim 6 , wherein the aqueous dispersion (C) comprises at least one selected from the group consisting of an aqueous dispersion (C-1) containing wet-ground acrylic resin particles (B), and an aqueous dispersion (C-2) containing dry-ground acrylic resin particles (B).
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