Oxygen catalyst and electrode using said oxygen catalyst

Patent metadata

Field	Value
Publication number	US-2022085387-A1
Application number	US-202017424670-A
Country	US
Kind code	A1
Filing date	Jan 22, 2020
Priority date	Jan 23, 2019
Publication date	Mar 17, 2022
Grant date	—

Abstract

Provided are: an oxygen catalyst that uses an alkaline aqueous solution as an electrolyte and has high catalytic activity; and an electrode. The oxygen catalyst according to the present invention is an oxygen catalyst in which an alkaline aqueous solution is used as an electrolyte, the oxygen catalyst being characterized by having a pyrochlore oxide structure including bismuth on an A-site and ruthenium on a B-site, and containing manganese as well as bismuth and ruthenium. The electrode according to the present invention is characterized by using the oxygen catalyst according to the present invention.

First claim

1 - 10 . (canceled)

11 . An oxygen catalyst that uses an alkaline aqueous solution as an electrolyte, the oxygen catalyst comprising a structure of a pyrochlore oxide with bismuth located at A-sites and ruthenium at B-sites, and containing manganese as well as the bismuth and the ruthenium.

12 . The oxygen catalyst of claim 11 , wherein the pyrochlore oxide further contains sodium.

13 . The oxygen catalyst of claim 12 , wherein the sodium is less than 15 atom % in an atomic ratio of four elements that are the bismuth, the ruthenium, the manganese, and the sodium.

14 . The oxygen catalyst of claim 13 , wherein the sodium is 11 atom % to 14 atom % in the atomic ratio of the four elements that are the bismuth, the ruthenium, the manganese, and the sodium.

15 . The oxygen catalyst of claim 11 , wherein the manganese is located at the B sites.

16 . The oxygen catalyst of claim 12 , wherein the manganese is located at the B sites.

17 . The oxygen catalyst of claim 13 , wherein the manganese is located at the B sites.

18 . The oxygen catalyst of claim 11 , wherein the manganese is 15 atom % or less in an atomic ratio of three elements that are the bismuth, the ruthenium, and the manganese.

19 . The oxygen catalyst of claim 13 , wherein the manganese is 15 atom % or less in an atomic ratio of three elements that are the bismuth, the ruthenium, and the manganese.

20 . The oxygen catalyst of claim 15 , wherein the manganese is 15 atom % or less in an atomic ratio of three elements that are the bismuth, the ruthenium, and the manganese.

21 . The oxygen catalyst of claim 11 , wherein the manganese is cations having a valence of +4.

22 . The oxygen catalyst of claim 13 , wherein the manganese is cations having a valence of +4.

23 . The oxygen catalyst of claim 15 , wherein the manganese is cations having a valence of +4.

24 . The oxygen catalyst of claim 18 , wherein the manganese is cations having a valence of +4.

25 . The oxygen catalyst of claim 11 , wherein the pyrochlore oxide is of an oxygen-deficient type.

26 . The oxygen catalyst of claim 15 , wherein the pyrochlore oxide is of an oxygen-deficient type.

27 . The oxygen catalyst of claim 18 , wherein the pyrochlore oxide is of an oxygen-deficient type.

28 . The oxygen catalyst of claim 22 , wherein the pyrochlore oxide is of an oxygen-deficient type.

29 . An electrode characterized by using the oxygen catalyst of claim 11 .

30 . The electrode of claim 29 , wherein the electrode is one of: an air electrode of an air primary battery, an air electrode of an air secondary battery, an oxygen cathode for brine electrolysis, a cathode of an alkaline fuel cell, or an anode for alkaline water electrolysis.

Assignees

• The Doshisha

Inventors

• Morimitsu Masatsugu

Classifications

• H01M2004/8689

  Positive electrodes · CPC title

• H01M4/9016 Primary

  Oxides, hydroxides or oxygenated metallic salts · CPC title

• C25B11/052

  Electrodes comprising one or more electrocatalytic coatings on a substrate · CPC title

• C25B11/0771

  of the spinel type · CPC title

• C25B11/0773

  of the perovskite type · CPC title