High-hardness composite oxide dispersion-strengthened tungsten alloy and preparation method thereof

Patent metadata

Field	Value
Publication number	US-2022074027-A1
Application number	US-202117374442-A
Country	US
Kind code	A1
Filing date	Jul 13, 2021
Priority date	Sep 4, 2020
Publication date	Mar 10, 2022
Grant date	—

Abstract

A high-hardness composite oxide dispersion-strengthened tungsten alloy and a preparation method thereof are disclosed. The high-hardness composite oxide dispersion-strengthened tungsten alloy consists essentially of a tungsten phase, and nano-scale Y2O3 and ZrO2 particles dispersed in the tungsten phase, wherein there is a Y—Zr—O ternary phase structure at a coherent/semi-coherent interface.

First claim

What is claimed is:

1 . A high-hardness composite oxide dispersion-strengthened tungsten alloy, consisting essentially of a tungsten phase, and nano-scale Y 2 O 3 and ZrO 2 particles dispersed in the tungsten phase, wherein there is a Y—Zr—O ternary phase structure at a coherent/semi-coherent interface in the high-hardness composite oxide dispersion-strengthened tungsten alloy.

2 . The high-hardness composite oxide dispersion-strengthened tungsten alloy as claimed in claim 1 , consisting essentially of 0.25% of Y 2 O 3 , 0.1% of ZrO 2 , and a balance of tungsten.

3 . A method for preparing the high-hardness composite oxide dispersion-strengthened tungsten alloy as claimed in claim 1 , comprising
preparation of a composite powder
dissolving yttrium nitrate, zirconium nitrate, and surfactant triethanolamine, with a certain proportion, in an appropriate amount of deionized water respectively, and stirring to be dispersed uniformly respectively, to obtain an aqueous yttrium nitrate solution, an aqueous zirconium nitrate solution, and an aqueous triethanolamine solution respectively;
mixing the aqueous yttrium nitrate solution, the aqueous zirconium nitrate solution, and the aqueous triethanolamine solution, to obtain a mixed solution;
heating while stirring the mixed solution to 100° C., pouring a solution of ammonium metatungstate dissolved in deionized water thereto, and continuing heating while stirring until that the resulting mixture becomes transparent;
adding a solution of an appropriate amount of oxalic acid thereto, stirring the resulting solution at 140° C. until that the solution is completely volatilized, to obtain a precipitated block, i.e. a precursor;
drying the precursor, and grinding the dried precursor, to obtain a precursor powder; and
reducing the precursor powder in a hydrogen atmosphere, to obtain a W—Y 2 O 3 —ZrO 2 composite powder;
sintering of the W—Y 2 O 3 —ZrO 2 composite powder
loading the W—Y 2 O 3 —ZrO 2 composite powder into a graphite mold and compacting, putting the loaded graphite mold into a spark plasma sintering furnace, applying a pre-pressure to the W—Y 2 O 3 —ZrO 2 composite powder, vacuuming the spark plasma sintering furnace, and subjecting the W—Y 2 O 3 —ZrO 2 composite powder to a two-stage heat-preservation sintering; and cooling the sintered W—Y 2 O 3 —ZrO 2 composite powder in the spark plasma sintering furnace to ambient temperature, to obtain a block of the W—Y 2 O 3 —ZrO 2 alloy.

4 . The method as claimed in claim 3 , wherein reducing the precursor powder in a hydrogen atmosphere comprises subjecting the precursor powder to a two-stage pyrolysis, which comprises
first heating the precursor powder to 500-600° C., and maintaining at the temperature for 60-80 minutes, and further heating to 800-900° C., and maintaining at the temperature for 100-120 minutes.

5 . The method as claimed in claim 3 , wherein the two-stage heat-preservation sintering comprises
a first stage heat-preservation sintering, which is performed at 750-850° C. for 5-10 minutes; and a second stage heat-preservation sintering, which is performed at 1500-1600° C. for 1-3 minutes.

6 . The method as claimed in claim 3 , wherein before the first stage heat-preservation sintering, the pre-pressure is not more than 14 MPa, and when the first stage heat-preservation sintering starts, the pre-pressure starts increasing, and after the first stage heat-preservation sintering, the pre-pressure increases up to 50-100 MPa at a constant rate.

7 . The method as claimed in claim 5 , wherein before the first stage heat-preservation sintering, the pre-pressure is not more than 14 MPa, and when the first stage heat-preservation sintering starts, the pre-pressure starts increasing, and after the first stage heat-preservation sintering, the pre-pressure increases up to 50-100 MPa at a constant rate.

Assignees

• Univ Hefei Technology

Inventors

• Luo Laima
• Zhao Zhihao
• Wu Yucheng
• Yao Gang
• Zan xiang
• Zhu Xiaoyong

Classifications

• C22C32/0031

  Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof · CPC title

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title

• B22F7/08

  with one or more parts not made from powder {(B22F7/062 takes precedence)} · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C22C27/04 Primary

  Alloys based on tungsten or molybdenum · CPC title