Ultraviolet absorbing agent, ultraviolet absorbing composition, ultraviolet absorbing film, laminate, and novel compound

Patent metadata

Field	Value
Publication number	US-2022064458-A1
Application number	US-202117522943-A
Country	US
Kind code	A1
Filing date	Nov 10, 2021
Priority date	Jun 28, 2019
Publication date	Mar 3, 2022
Grant date	—

Abstract

Provided are an ultraviolet absorbing agent represented by General Formula (1) and an application thereof. In General Formula (1), R11 represents a monovalent substituent. n is 1 or 2. W1 and W2 each independently represent a hydrogen atom, a cyano group, a carbamoyl group, a sulfamoyl group, a nitro group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkyl group, an aryl group, or a heterocyclic group, where at least one of W1 or W2 represents a substituent having a Hammett's substituent constant σp value of 0.2 or more. W1 and W2 may be bonded to each other to form a ring.

First claim

What is claimed is:

1 . An ultraviolet absorbing agent represented by General Formula (1),

wherein, in General Formula (1), R 11 represents a monovalent substituent, n is 1 or 2, where in a case where n is 2, two existing R 11 's may be the same or different from each other,
W 1 and W 2 each independently represent a hydrogen atom, a cyano group, a carbamoyl group, a sulfamoyl group, a nitro group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkyl group, an aryl group, or a heterocyclic group, where at least one of W 1 or W 2 represents a substituent having a Hammett's substituent constant σp value of 0.2 or more, and W 1 and W 2 may be bonded to each other to form a ring, and
at least one group of R 11 , W 1 , or W 2 has an acid group selected from the group consisting of a sulfonic acid group, a carboxylic acid group, and a phosphoric acid group.

2 . The ultraviolet absorbing agent according to claim 1 ,
wherein the ultraviolet absorbing agent is represented by General Formula (2),

wherein, in General Formula (2), R 1 and R 2 each independently represent a monovalent substituent,
W 1 and W 2 each independently represent a hydrogen atom, a cyano group, a carbamoyl group, a sulfamoyl group, a nitro group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkyl group, an aryl group, or a heterocyclic group, where at least one of W 1 or W 2 represents a substituent having a Hammett's substituent constant σp value of 0.2 or more, and W 1 and W 2 may be bonded to each other to form a ring, and
at least one group of R 1 , R 2 , W′, or W 2 has an acid group selected from the group consisting of a sulfonic acid group, a carboxylic acid group, and a phosphoric acid group.

3 . The ultraviolet absorbing agent according to claim 1 ,
wherein the ultraviolet absorbing agent is represented by General Formula (3),

wherein, in General Formula (3), R 1 and R 2 each independently represent a monovalent substituent,
R 3 represents an alkyl group, an aryl group, or a heterocyclic group, and
at least one group of R 1 , R 2 , or R 3 has an acid group selected from the group consisting of a sulfonic acid group, a carboxylic acid group, and a phosphoric acid group.

4 . The ultraviolet absorbing agent according to claim 1 ,
wherein the acid group is a sulfonic acid group.

5 . The ultraviolet absorbing agent according to claim 1 ,
wherein a solubility in water at 25° C. is 1% by mass or more.

6 . An ultraviolet absorbing composition comprising:
the ultraviolet absorbing agent according to claim 1 ; and an aqueous medium.

7 . The ultraviolet absorbing composition according to claim 6 , further comprising:
a water-soluble polymer.

8 . An ultraviolet absorbing film,
wherein the ultraviolet absorbing film is a cured substance of the ultraviolet absorbing composition according to claim 6 .

9 . A laminate comprising:
a base material; and the ultraviolet absorbing film according to claim 8 , formed on the base material.

10 . A compound represented by General Formula (4),

wherein, in General Formula (4), L 1 and L 2 each independently represent an alkylene group,
X's each independently represent a hydrogen atom or a countercation of —SO 3 − , and
W 1 and W 2 each independently represent a hydrogen atom, a cyano group, a carbamoyl group, a sulfamoyl group, a nitro group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkyl group, an aryl group, or a heterocyclic group, where at least one of W 1 or W 2 represents a substituent having a Hammett's substituent constant σp value of 0.2 or more, and W 1 and W 2 may be bonded to each other to form a ring.

Assignees

• Fujifilm Corp

Inventors

• Katou Takashi

Classifications

• C07D409/04

  directly linked by a ring-member-to-ring-member bond · CPC title

• C09D129/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C09D5/32 Primary

  Radiation-absorbing paints {(protection against X-, gamma- or corpuscular radiation G21F)} · CPC title

• C07D339/06 Primary

  having the hetero atoms in positions 1 and 3, e.g. cyclic dithiocarbonates · CPC title

• C09D7/20

  Diluents or solvents · CPC title