Positive Electrode Material for Lithium Secondary Battery, and Positive Electrode and Lithium Secondary Battery Including Same

Patent metadata

Field	Value
Publication number	US-2022059832-A1
Application number	US-201917298818-A
Country	US
Kind code	A1
Filing date	Dec 4, 2019
Priority date	Dec 10, 2018
Publication date	Feb 24, 2022
Grant date	—

Abstract

A positive electrode material and a positive electrode and a lithium secondary battery including the same are provided. The positive electrode material having a bimodal particle size distribution which includes large-diameter particles and small-diameter particles having different average particle diameters (D50), wherein the large-diameter particles are lithium composite transition metal oxide having a nickel content of 80 atm % or more in all transition metals thereof, and the small-diameter particles are a lithium composite transition metal oxide including nickel, cobalt, and aluminum, having a nickel content of 80 atm % to 85 atm % in all transition metals, and having an atomic ratio of the cobalt to the aluminum (Co/Al) of 1.5 to 5.

First claim

1 . A positive electrode material having a bimodal particle size distribution, comprising large-diameter particles and small-diameter particles having different average particle diameters (D 50 ),
wherein the large-diameter particles are a lithium composite transition metal oxide having a nickel content of 80 atm % or greater in all transition metals, and the small-diameter particles are a lithium composite transition metal oxide including nickel, cobalt, and aluminum, having a nickel content of 80 atm % to 85 atm % in all transition metals, and having an atomic ratio of the cobalt to the aluminum (Co/Al) of 1.5 to 5.

2 . The positive electrode material of claim 1 , wherein the small-diameter particles are a lithium composite transition metal oxide represented by [Formula 1] below:
Li x [Ni y Co z Al w M 1 v ]O 2   [Formula 1]
wherein, M 1 is one or more selected from the group consisting of Mn, W, Cu, Fe, Ba, V, Cr, Ti, Zr, Zn, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo, and 0.9≤x≤1.5, 0.8≤y≤0.85, 0<z≤0.1, 0<w≤0.1, 1.5≤z/w<5, and 0≤v<0.2.

3 . The positive electrode material of claim 1 , wherein the small-diameter particles are a lithium composite transition metal oxide represented by [Formula 2] below:
Li x [Ni y Co z Al w Mn v ]O 2   [Formula 2]
wherein, 0.9≤x≤1.5, 0.8≤y≤0.85, 0<z≤0.1, 0<w≤0.1, 1.5≤z/w≤5, and 0≤v<0.2.

4 . The positive electrode material of claim 1 , wherein the large-diameter particles are a lithium composite transition metal oxide represented by Formula 3 below:
Li a [Ni b Co c M 2 d M 3 e ]O 2   [Formula 3]
wherein, M 2 is one or more selected from the group consisting of Mn and Al, M 3 is one or more selected from the group consisting of W, Cu, Fe, Ba, V, Cr, Ti, Zr, Zn, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo, and 0.9≤a≤1.5, 0.8≤b<1, 0<c≤0.15, 0<d<0.2, and 0≤e<0.2.

5 . The positive electrode material of claim 4 , wherein in the Formula 3, M 2 is Al d1 Mn d2 , 0.9≤a≤1.5, 0.8≤b<1, 0<c≤0.1, 0<d 1 ≤0.1, and 0<d 2 <0.2, and 1.5≤c/d 1 <5.

6 . The positive electrode material of claim 1 , wherein the average particle diameter (D 50 ) of the small-diameter particles is 2-8 m.

7 . The positive electrode material of claim 1 , wherein the average particle diameter (D 50 ) of the large-diameter particles is 10-20 m.

8 . The positive electrode material of claim 1 , wherein the small-diameter particles and the large-diameter particles are included in a weight ratio of 1:9 to 5:5.

9 . A positive electrode comprising:
a positive electrode current collector; and a positive electrode active material layer formed on the positive electrode current collector, wherein the positive electrode active material layer comprises the positive electrode material of claim 1 .

10 . A lithium secondary battery comprising:
the positive electrode of claim 9 ; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte.

Assignees

• Lg Chemical Ltd

Inventors

• Han Jung Min
• Lee Dong Hun
• Park Sung Bin
• Cho Hyung Man
• Hwang Jin Tae
• Jung Wang Mo

Classifications

• H01M4/364 Primary

  as mixtures · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title