High-strength cold-rolled steel sheet having excellent surface quality and low material variation, and method for manufacturing same
US-2024384366-A1 · Nov 21, 2024 · US
US2022017985A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2022017985-A1 |
| Application number | US-201917311808-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 17, 2019 |
| Priority date | Dec 18, 2018 |
| Publication date | Jan 20, 2022 |
| Grant date | — |
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A cold rolled and heat-treated steel sheet having a composition including, by weight percent: C 0.3-0.4%, Mn 2.0-2.6%, Si: 0.8-1.6%, Al 0.01-0.6%, Mo 0.15-0.5%, Cr 0.3-1.0%, Nb≤0.06%, Ti≤0.06%, Ni≤0.8%, S≤0.010%, P≤0.020% and N≤0.008%, the remainder of the composition being iron and unavoidable impurities resulting from the smelting, and having a microstructure consisting of, in surface fraction: between 15% and 30% of retained austenite, said retained austenite having a carbon content of at least 0.7%, between 70% and 85% of tempered martensite, at most 5% of fresh martensite and at most 5% of bainite. It also deals with a manufacturing method thereof.
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1 - 17 . (canceled) 18 . A cold-rolled and heat-treated steel sheet, made of a steel having a composition comprising, by weight percent: C: 0.3-0.4% Mn: 2.0-2.6% Si: 0.8-1.6% Al: 0.01-0.6% Mo: 0.15-0.5% Cr: 0.3-1.0% Nb≤0.06% Ti≤0.06% Ni≤0.8% S≤0.010% P≤0.020% N≤0.008% Cu≤0.03% and optionally one or more of the following elements, in weight percentage: B: 0.0003-0.005% V≤0.2% a remainder of the composition being iron and unavoidable impurities resulting from processing, the steel sheet having a microstructure consisting of, in surface fraction: between 15% and 30% of retained austenite, said retained austenite having a carbon content of at least 0.7%; between 70% and 85% of tempered martensite; at most 5% of fresh martensite; and at most 5% of bainite. 19 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the chromium content is between 0.6% and 0.8%. 20 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the silicon content is below 1.5%. 21 . The cold-rolled and heat-treated steel sheet as recited in claim 20 wherein the silicon content is below 1.4%. 22 . The cold-rolled and heat-treated steel sheet as recited in claim 21 wherein the silicon content is below 1.3%. 23 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the cumulated amount of silicon and aluminum is equal to or above 1.6%. 24 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the aluminum content is between 0.2% and 0.5%. 25 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the molybdenum content is between 0.20% and 0.40%. 26 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the microstructure includes at most 2% of fresh martensite. 27 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the microstructure includes at most 2% of bainite. 28 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the microstructure includes no bainite and no fresh martensite. 29 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the cold-rolled and heat-treated steel sheet is coated with Zn or a Zn alloy or with Al or an Al alloy. 30 . The cold-rolled and heat-treated steel sheet as recited in claim 18 wherein the cold-rolled and heat-treated steel sheet has a yield strength YS of at least 1100 MPa, a tensile strength TS of at least 1470 MPa, a total elongation TE of at least 13%, a hole expansion ratio HER of at least 15% and an LME index of less than 0.70. 31 . A method for manufacturing a cold-rolled and heat-treated steel sheet, comprising the following successive steps: casting a steel to obtain a slab, said steel having a composition comprising, by weight percent: C: 0.3-0.4% Mn: 2.0-2.6% Si: 0.8-1.6% Al : 0.01-0.6% Mo: 0.15-0.5% Cr: 0.3-1.0% Nb≤0.06% Ti≤0.06% Ni≤0.8% S≤0.010% P≤0.020% N≤0.008% Cu≤0.03% and optionally one or more of the following elements, in weight percentage: B: 0.0003-0.005% V≤0.2% a remainder of the composition being iron and unavoidable impurities resulting from processing; reheating the slab at a temperature T reheat comprised between 1150° C. and 1300° C., hot rolling the reheated slab at a temperature higher than Ar3 to obtain a hot rolled steel sheet; coiling the hot rolled steel sheet at a coiling temperature T coil between 200° C. and 700° C.; optionally pickling said hot rolled steel sheet; optionally annealing the hot rolled steel sheet, to obtain a hot-rolled and annealed steel sheet; optionally pickling said hot-rolled and annealed steel sheet; cold rolling the hot-rolled and annealed steel sheet to obtain a cold rolled steel sheet; reheating the cold-rolled steel sheet to an annealing temperature between Ac3 and Ac3+100° C. and maintaining the cold-rolled steel sheet at the annealing temperature for a holding time between 30 s and 600 s, to obtain, upon annealing, a fully austenitic structure; quenching the cold-rolled steel sheet at a cooling rate comprised between 0.1° C./s and 200° C./s, to a quenching temperature Tq between (Ms-140° C.) and (Ms-75° C.) and optionally maintaining it at Tq for a holding time between 1 and 200 s; reheating the cold-rolled steel sheet to a partitioning temperature between 350° C. and 500° C., and maintaining the cold-rolled steel sheet at the partitioning temperature for a partitioning time between 30 s and 2000 s; and cooling the cold-rolled steel and heat-treated sheet to room temperature. 32 . The method as recited in claim 31 wherein the coiling temperature T coil is between 450° C. and 650° C. 33 . The method as recited in claim 31 wherein the hot rolled steel sheet after coiling comprises a grain boundary oxidation layer having a maximum thickness of 5 μm. 34 . The method as recited in claim 31 wherein the hot rolled steel sheet is annealed at a temperature between 500 and 800° C., during 1000 s to 108000 s.
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