Systems and processes for direct converting distillate fractions of crude oil to olefins

Patent metadata

Field	Value
Publication number	US-2022017829-A1
Application number	US-202016933087-A
Country	US
Kind code	A1
Filing date	Jul 20, 2020
Priority date	Jul 20, 2020
Publication date	Jan 20, 2022
Grant date	—

Abstract

A process for converting a hydrocarbon feed to olefins includes passing the hydrocarbon feed to a distillation system to separate the hydrocarbon feed to produce a light gas stream, a plurality of distillate fractions, and a residue. The process further includes passing at least one of the distillate fractions to a steam catalytic cracking system that includes at least one steam catalytic cracking reactor that is a fixed bed reactor containing a nano-zeolite cracking catalyst. The steam catalytic cracking system contacts the one or more of the plurality of distillate fractions with steam in the presence of the nano-zeolite cracking catalyst, which causes steam catalytic cracking of at least a portion of hydrocarbons in the at least one distillate fraction to produce a steam catalytic cracking effluent comprising the olefins.

First claim

1 . A process for converting a hydrocarbon feed to olefins, the process comprising:
separating the hydrocarbon feed through a distillation system to produce a light gas stream, a plurality of distillate fractions, and a residue; passing at least one of the plurality of distillate fractions from the distillation system directly to a steam catalytic cracking reactor; and steam catalytic cracking at least one of the distillate fractions in the presence of steam and a nano-zeolite cracking catalyst disposed in at least one steam catalytic cracking reactor to produce a steam catalytic cracking effluent comprising the olefins, where the steam catalytic cracking reactor is a fixed bed reactor.

2 . The process of claim 1 , where the hydrocarbon feed comprises a whole crude oil having an API gravity between 25 and 50 and the olefins comprise ethylene, propylene, butene, or combinations of these.

3 . The process of claim 1 , further comprising:
deasphalting the residue to remove asphaltene compounds from the residue to produce a deasphalted oil; passing the deasphalted oil to the fixed bed steam catalytic cracking reactor; and steam catalytic cracking the deasphalted oil.

4 . The process of claim 1 , further comprising introducing a gas condensate to the at least one steam catalytic cracking reactor.

5 . The process of claim 4 , further comprising combining the gas condensate with at least one of the distillate fractions upstream of the at least one steam catalytic cracking reactor, where the content of the gas condensate is from 5 weight percent to 50 weight percent of total hydrocarbons passed to the at least one steam catalytic cracking reactor.

6 . The process of claim 1 , where the plurality of distillate fractions comprise one or more of a light naphtha stream, a whole naphtha stream, a heavy naphtha stream, a kerosene stream, a gas oil stream, a light vacuum gas oil stream, a heavy vacuum gas oil stream, or combinations of these.

7 . The process of claim 6 , where the at least one steam catalytic cracking reactor comprises a first steam catalytic cracking reactor and a second steam catalytic cracking reactor in parallel with the first steam catalytic cracking reactor and the process further comprises:
passing one or more of the light naphtha stream, the whole naphtha stream, the heavy naphtha stream, the kerosene stream, the gas oil stream, or combinations of these to the first steam catalytic cracking reactor; steam catalytic cracking the one or more of the light naphtha stream, the whole naphtha stream, the heavy naphtha stream, the kerosene stream, the gas oil stream, or combinations of these in the first steam catalytic cracking reactor; passing at least one of the light vacuum gas oil, the heavy vacuum gas oil, or both to the second fixed bed steam catalytic cracking reactor; and steam catalytic cracking the at least one of the light vacuum gas oil, the heavy vacuum gas oil, or both in the second steam catalytic cracking reactor.

8 . The process of claim 6 , further comprising:
passing at least one naphtha stream to a steam cracking unit operated in parallel with the at least one catalytic steam cracking reactor, where the steam cracking unit does not include a catalyst and the naphtha stream comprises one or more of the light naphtha, the whole naphtha, the heavy naphtha, or combinations of these; and contacting the naphtha stream with steam in the steam cracking unit at a steam cracking temperature, where the contacting causes at least a portion of the hydrocarbons in the naphtha stream to undergo cracking reactions to produce a steam cracking effluent comprising the olefins.

9 . The process of claim 1 , where separating the hydrocarbon feed comprises passing the hydrocarbon feed to an atmospheric distillation unit that separates the hydrocarbon feed into the plurality of distillate fractions and the residue, where the residue is an atmospheric residue and the distillate fractions comprise one or more of a light naphtha stream, a whole naphtha stream, a heavy naphtha stream, a kerosene stream, a gas oil stream, or combinations of these.

10 . The process of claim 9 , further comprising passing the atmospheric residue to a vacuum distillation unit that separates the atmospheric residue into at least one vacuum gas oil stream and a vacuum residue.

11 . The process of claim 10 , further comprising:
passing the at least one vacuum gas oil stream to the at least one steam catalytic cracking reactor; and steam catalytic cracking the at least one vacuum gas oil stream.

12 . The process of claim 10 , further comprising:
deasphalting the vacuum residue to remove asphaltene compounds from the vacuum residue to produce a deasphalted oil; passing the deasphalted oil to the at least one steam catalytic cracking reactor; and steam catalytic cracking the deasphalted oil in the at least one steam catalytic cracking reactor.

13 . The process of claim 10 , further comprising:
passing at least one naphtha stream to a steam cracking unit operated in parallel with the at least one steam catalytic cracking reactor, where the steam cracking unit does not include a catalyst and the naphtha stream comprises one or more of the light naphtha, the whole naphtha, the heavy naphtha, or combinations of these; and contacting the naphtha stream with steam in the steam cracking unit at a steam cracking temperature, where the contacting causes at least a portion of the hydrocarbons in the naphtha stream to undergo cracking reactions to produce a steam cracking effluent comprising the olefins.

14 . The process of claim 10 , where the at least one steam catalytic cracking reactor comprises a first steam catalytic cracking reactor and a second steam catalytic cracking reactor in parallel with the first steam catalytic cracking reactor and the process further comprises:
passing one or more of the light naphtha stream, the whole naphtha stream, the heavy naphtha stream, the kerosene stream, the gas oil stream, or combinations of these to the first steam catalytic cracking reactor; steam catalytic cracking the one or more of the light naphtha stream, the whole naphtha stream, the heavy naphtha stream, the kerosene stream, the gas oil stream, or combinations of these in the first steam catalytic cracking reactor; passing at least one vacuum gas oil stream to the second steam catalytic cracking reactor; and steam catalytic cracking the at least one vacuum gas oil stream in the second steam catalytic cracking reactor.

15 . The process of claim 14 , further comprising introducing a gas condensate to the second steam catalytic cracking reactor.

16 . A system for converting a hydrocarbon feed to olefins, the system comprising:
a distillation system operable to separate the hydrocarbon feed to produce a light gas stream, a plurality of distillate fractions, and a residue; and a steam catalytic cracking system downstream of the distillation system, the steam catalytic cracking system comprising at least one steam catalytic cracking reactor that is a fixed bed reactor comprising a nano-zeolite cracking catalyst, where the at least one steam catalytic cracking reactor is operable to contact one or more of the distillate fractions with steam in the presence of the nano-zeolite cracking catalyst to produce a steam cracking effluent comprising the olefins.

17 . The system of claim 16 , further comprising:
a Solvent Deasphalting (SDA) unit downstream of the distillation system, the SDA unit operable to remove asphaltene compounds from the residue to produce a deasphalted oil, wher

Assignees

• Saudi Arabian Oil Co

Inventors

• Al-Shafei Emad Naji
• Al-Bahar Mohammed Z
• Al-Jishi Ali Nader
• Choi Ki-Hyouk
• Al-Jishi Mohammad F
• Al-Nasir Ali S

Classifications

• B01J35/77

  Compounds characterised by their crystallite size · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/10

  Infrared [IR] · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title