Curable composition

Patent metadata

Field	Value
Publication number	US-2022017736-A1
Application number	US-201917311023-A
Country	US
Kind code	A1
Filing date	Dec 16, 2019
Priority date	Dec 19, 2018
Publication date	Jan 20, 2022
Grant date	—

Abstract

The present invention relates to a curable composition comprising: at least one polymer comprising cure sites [polymer (E)], at least one thermoplastic polymer [thermoplastic (P)] different from said polymer (E) and at least one 1,5 enediyne curing agent [agent (C)], and to a blend obtained by dynamic vulcanization of said composition.

First claim

1 - 17 . (canceled)

18 . A curable composition comprising:
(a) at least one polymer comprising cure sites [polymer (E)]; (b) at least one thermoplastic polymer [thermoplastic (P)] different from said polymer (E), (c) at least one curing agent [agent (C)] of formula (I):

wherein:
each R, equal to or different from each other, is independently selected from the group consisting of hydrogen; halogen; C 1 -C 20 alkyl, linear or branched, optionally substituted and/or optionally fluorinated; C 1 -C 20 oxyalkyl, linear or branched, optionally substituted and/or optionally fluorinated; (per)fluoropolyether chain; aromatic or heteroaromatic radical, monocyclic or polycyclic, optionally substituted and/or optionally fluorinated; —SiR 1 3 , —(R 1 2 SiO) b R 1 , —PR 1 2 wherein each R 1 , equal to or different from each other, is independently selected from the group consisting of hydrogen, C 1 -C 20 alkyl, linear or branched, optionally substituted and/or optionally fluorinated and wherein b is an integer of at least 1; and
A 1 and A 2 , equal to or different from each other, are each independently selected from the group consisting of hydrogen; halogen; C 1 -C 20 alkyl, linear or branched, optionally substituted and/or optionally fluorinated; C 1 -C 20 oxyalkyl, linear or branched, optionally substituted and/or optionally fluorinated; (per)fluoropolyether chain; —(R 1 2 SiO) b R 1 wherein R 1 and b are as defined; aromatic or heteroaromatic radical, monocyclic or polycyclic, optionally substituted and/or optionally fluorinated.

19 . The composition according to claim 18 , comprising at least one metal oxide or hydroxide.

20 . The composition according to claim 18 , wherein the curing agent is selected from the group of compounds of formula (II):

wherein each R, equal to or different from each other, is as defined above and wherein X is a divalent bridging group selected from a carbon-carbon bond; a C 1 -C 20 alkylene radical, optionally substituted and/or optionally fluorinated; a divalent (per)fluoropolyether radical; an organopolysiloxane radical —(R 1 2 SiO) b — wherein R 1 and b are as defined above; a —O— radical; a —S— radical; a —SO 2 — radical; a —C(O)— radical; a fused aromatic or heteroaromatic structure optionally substituted and/or optionally fluorinated; X being preferably a fluorinated C 1 -C 20 alkylene radical, preferably —C(CF 3 ) 2 — or —(CF 2 ) n — wherein n is an integer from 1 to 20, e.g. 2, 3, 4, 6, 8, 10, 12, 14, 16, 18, 20.

21 . The composition according to claim 18 , wherein said polymer (E) comprises iodine and/or bromine cure sites.

22 . The composition according to claim 18 , wherein said at least one polymer (E) is a (per)fluoroelastomer.

23 . The composition according to claim 22 , wherein said at least one polymer (E) comprises recurring units derived from tetrafluoroethylene (TFE) and recurring units derived from at least one perfluoroalkylvinylether.

24 . The composition according to claim 23 , wherein the amount of the recurring units derived from said perfluoroalkylvinylether is either from 25% (mol) to 40% (mol), with respect to total moles of TFE and the perfluoroalkylvinylether, or from 60% (mol) to 80% (mol), with respect to total moles of TFE and the perfluoroalkylvinylether.

25 . The composition according claim 18 , wherein said at least one polymer (E) is a thermoplastic (per)fluoropolymer comprising recurring units derived from tetrafluoroethylene (TFE) and recurring units derived from at least one (per)fluoroalkylvinylether.

26 . The composition according to claim 25 , wherein the amount of the recurring units derived from TFE preferably ranges from 80 to 99% (mol), with respect to the total moles of TFE and the (per)fluoroalkylvinylether, and/or wherein the amount of recurring units derived from said (per)fluoroalkylvinylether ranges from 1 to 20% (mol), with respect to the total moles of TFE and the (per)fluoroalkylvinylether.

27 . The composition according to claim 18 , said thermoplastic (P) being semi-crystalline and having a melting temperature higher than 200° C.

28 . The composition according to claim 18 , wherein said thermoplastic (P) is fluorinated and comprises recurring units derived from tetrafluoroethylene (TFE) and recurring units derived from at least one (per)fluoroalkylvinylether, wherein the amount of the recurring units derived from TFE ranges from 80 to 99% (mol), with respect to the total moles of TFE and the (per)fluoroalkylvinylether, and/or wherein the amount of recurring units derived from said (per)fluoroalkylvinylether ranges from 1 to 20% (mol), with respect to the total moles of TFE and the (per)fluoroalkylvinylether.

29 . The composition according to claim 18 , wherein the thermoplastic (P) is an aromatic polymer.

30 . The composition according to claim 29 , wherein said thermoplastic (P) is a poly(arylene sulphide) (PAS) comprising recurring units of formula —(ArS)—, Ar being an aromatic group.

31 . The composition according to claim 29 , wherein said thermoplastic (P) is a poly(ether ether ketone) (PEEK) comprising recurring units of formula (VII-A):

wherein each R 2 , equal or different from each other, is independently selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; and
each b, equal to or different from each other, is independently selected from 0, 1, 2, 3, and 4, being preferably 0.

32 . The composition according to claim 18 , wherein:
the amount of said at least one agent (C) is of at least 0.1% (wt), and of at most 10% (wt), with respect to the total weight of the composition; and/or the amount of said at least one polymer (E) is of at least 10% (wt), and of at most 90% (wt), with respect to the total weight of the composition; and/or the amount of said at least one thermoplastic (P) is of at least 10% (wt), and of at most 90% (wt), with respect to the total weight of the composition.

33 . A method for manufacturing the composition according to claim 18 , said method comprising at least one step of mixing said at least one polymer (E), said at least one agent (C) and said at least one thermoplastic (P).

34 . A method for manufacturing a blend comprising a continuous thermoplastic polymer phase and a dispersed vulcanized polymer phase, said method comprising dynamic vulcanizing the composition according to claim 18 .

35 . A blend comprising a continuous thermoplastic polymer phase and a dispersed vulcanized polymer phase, said blend being obtained by the method according to claim 34 .

36 . A method for manufacturing a shaped article, said method comprising moulding the blend of claim 35 .

Assignees

• Solvay Specialty Polymers It

Inventors

• Sanguineti Aldo
• Mirenda Marco
• Wlassics Ivan Diego

Classifications

• C08L27/10

  containing bromine or iodine atoms · CPC title

• C08L2205/22

  Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer · CPC title

• C08L2312/00

  Crosslinking · CPC title

• C08G65/2612

  containing aromatic or arylaliphatic hydroxyl groups · CPC title

• C08L2310/00

  Masterbatches · CPC title