Method for printing three-dimensional parts with cyrstallization kinetics control

Patent metadata

Field	Value
Publication number	US-2022016828-A1
Application number	US-202117474827-A
Country	US
Kind code	A1
Filing date	Sep 14, 2021
Priority date	Nov 21, 2012
Publication date	Jan 20, 2022
Grant date	—

Abstract

A method for printing a three-dimensional part with an additive manufacturing system, which includes providing a part material that compositionally has one or more semi-crystalline polymers and one or more secondary materials that are configured to retard crystallization of the one or more semi-crystalline polymers, where the one or more secondary materials are substantially miscible with the one or more semi-crystalline polymers. The method also includes melting the part material in the additive manufacturing system, forming at least a portion of a layer of the three-dimensional part from the melted part material in a build environment, and maintaining the build environment at an annealing temperature that is between a glass transition temperature of the part material and a cold crystallization temperature of the part material.

First claim

1 . A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a part material compositionally including one or more semi-crystalline polymers and one or more secondary materials that are configured to retard crystallization of the one or more semi-crystalline polymers, wherein the one or more secondary materials are substantially miscible with the one or more semi-crystalline polymers; melting the part material in the additive manufacturing system; forming at least a portion of a layer of the three-dimensional part from the melted part material in a build environment; and maintaining the build environment at an annealing temperature that is between a glass transition temperature of the part material and a cold crystallization temperature of the part material.

2 . The method of claim 1 , wherein the one or more secondary materials comprise one or more amorphous polymers.

3 . The method of claim 2 , wherein the one or more amorphous polymers constitute from about 50% by weight to about 85% by weight of a combined weight of the one or more semi-crystalline polymers and the one or more amorphous polymers.

4 . The method of claim 1 , wherein the one or more semi-crystalline polymers comprise one or more semi-crystalline polyamides, and wherein the one or more secondary materials comprise one or more amorphous polyamides.

5 . The method of claim 1 , wherein the one or more semi-crystalline polymers comprise one or more one or more polyaryletherketones, and wherein the one or more secondary materials comprise one or more polyetherimides.

6 . The method of claim 1 , and further comprising performing a post-printing crystallization step on the printed three-dimensional part.

7 . The method of claim 1 , wherein the one or more semi-crystalline polymers are polymerized from one or more base monomers, and wherein the one or more secondary materials comprise one or more second semi-crystalline polymers polymerized from one or more monomers that are isomers of the one or more base monomers.

8 . The method of claim 7 , wherein the one or more semi-crystalline polymers and the one or more second semi-crystalline polymers each comprise one or more polylactic acid polymers, one or more polyetherketoneketone polymers, or one or more polyesters.

9 . A method for printing a three-dimensional part from with an additive manufacturing system, the method comprising:
providing a part material that compositionally comprises one or more semi-crystalline polymers and one or more amorphous polymers that are substantially miscible with the one or more semi-crystalline polymers; maintaining a build environment of the additive manufacturing system, at least in a deposition region of the build environment, at an annealing temperature that is between a glass transition temperature of the part material and a cold crystallization temperature of the part material; feeding the part material to a print head retained by of the additive manufacturing system; melting the part material in the print head; extruding the melted part material from the print head; and depositing the extruded part material onto a build surface in the deposition region to form at least a portion of a layer of the three-dimensional part from the extruded part material.

10 . The method of claim 9 , wherein the one or more semi-crystalline polymers comprise one or more semi-crystalline polyamides, and wherein the one or more amorphous polymers comprise one or more amorphous polyamides.

11 . The method of claim 10 , wherein the one or more amorphous polymers constitute from about 50% by weight to about 85% by weight of a combined weight of the one or more semi-crystalline polymers and the one or more amorphous polymers.

12 . The method of claim 8 , and further comprising selecting the annealing temperature to achieve a predetermined crystallinity level for the part material of the printed three-dimensional part.

13 . The method of claim 8 , wherein the one or more amorphous polymers are configured to retard crystallization of the one or more semi-crystalline polymers.

14 . The method of claim 8 , and further comprising performing a post-printing crystallization step on the printed three-dimensional part.

15 . A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a part material that compositionally comprises one or more semi-crystalline polymers and one or more amorphous polymers that are substantially miscible with the one or more semi-crystalline polymers; melting the part material in the additive manufacturing system; forming layers of the three-dimensional part from the melted part material using an additive manufacturing technique, wherein the layers are formed in a region that is maintained at an annealing temperature that is within 10° C. of a glass transition temperature of the part material; and reheating the printed three-dimensional part to one or more temperatures that are within about 10° C. of a cold crystallization temperature of the part material.

16 . The method of claim 15 , wherein the re-crystallization temperature is within about 5° C. of the cold crystallization temperature of the part material.

17 . The method of claim 15 , wherein reheating the printed three-dimensional part to the one or more temperatures is performed for at least about 30 minutes.

18 . The method of claim 15 , wherein the reheating step is performed in a separate oven from the additive manufacturing system.

19 . The method of claim 18 , and further comprising separating the three-dimensional part from a build sheet used to received the formed layers of the three-dimensional part.

20 . The method of claim 15 , wherein the one or more semi-crystalline polymers comprise one or more semi-crystalline polyamides, and wherein the one or more amorphous polymers comprise one or more amorphous polyamides.

Assignees

• Stratasys Inc

Inventors

• Rodgers Luke M B
• Jaker Vittorio L

Classifications

• B29C64/194

  during lay-up · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• G03G15/224 Primary

  Machines for forming tactile or three dimensional images by electrographic means, e.g. braille, 3d printing · CPC title

• B33Y40/20

  Post-treatment, e.g. curing, coating or polishing · CPC title

• B29C64/118 Primary

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title