Polymer additives and their use in electrode materials and electrochemical cells

Patent metadata

Field	Value
Publication number	US-2022013786-A1
Application number	US-201917279406-A
Country	US
Kind code	A1
Filing date	Sep 27, 2019
Priority date	Sep 28, 2018
Publication date	Jan 13, 2022
Grant date	—

Abstract

Described are polymers comprising norbornene-based monomeric units derived from the polymerization of norbornene-based monomers for use as electrode material additives, binder compositions comprising said polymers as additives, electrode materials comprising said polymers as additives, electrode materials comprising said binder compositions, their methods of production and their use in electrochemical cells, for instance, in lithium or lithium ion batteries.

First claim

1 . A polymer for use as an electrode material additive, the polymer comprising norbornene-based monomeric units derived from the polymerization of a norbornene-based monomer of Formula I:

wherein,
W and W are independently in each occurrence selected from a hydrogen atom, —COOH, —SO 3 H, —OH, and —F.

2 . The polymer of claim 1 , wherein said polymer is of Formulae II or II(a):

wherein,
R 1 and R 2 are as defined in claim 1 , preferably R 2 is —COOH or a hydrogen atom; and
n is an integer selected such that the number average molecular weight is from about 10 000 g/mol to about 100 000 g/mol, or from about 12 000 g/mol to about 85 000 g/mol, or from about 15 000 g/mol to about 75 000 g/mol, or from about 20 000 g/mol to about 65 000 g/mol, or from about 25 000 g/mol to about 55 000 g/mol, or from about 25 000 g/mol to about 50 000 g/mol, limits included.

3 - 6 . (canceled)

7 . The polymer of claim 1 , wherein the polymer is a homopolymer.

8 . A binder composition comprising the polymer as defined in claim 1 together with a binder.

9 . The binder composition of claim 8 , wherein the polymer is a binder additive.

10 . The binder composition of claim 8 , wherein the weight ratio of binder to polymer is within the range of from about 6:1 to about 2:1.

11 . The binder composition of claim 8 , wherein the binder is selected from the group consisting of a polymeric binder of polyether type, a fluorinated polymer, and a synthetic or natural rubber, preferably wherein the binder is a fluorinated polymer, preferably polytetrafluoroethylene (PTFE) or polyvinylidene fluoride (PVdF), or the binder is a synthetic or natural rubber, preferably an ethylene propylene diene monomer rubber (EPDM).

12 - 16 . (canceled)

17 . The binder composition of claim 8 , for use in an electrode material.

18 . An electrode material comprising the polymer as defined in claim 1 and an electrochemically active material.

19 . The electrode material of claim 18 , wherein the electrochemically active material is selected from the group consisting of metal oxide particles, lithiated metal oxide particles, metal phosphate particles and lithiated metal phosphate particles, wherein the metal is preferably a transition metal selected from the group consisting of iron (Fe), titanium (Ti), manganese (Mn), vanadium (V), nickel (Ni), cobalt (Co) and a combination of at least two thereof, and more preferably the electrochemically active material is a manganese-containing oxide or phosphate.

20 - 21 . (canceled)

22 . The electrode material of claim 18 , wherein the electrochemically active material further comprises at least one doping element (e.g. magnesium).

23 . The electrode material of claim 18 , further comprising an electronically conductive material preferably selected from the group consisting of carbon black, acetylene black, graphite, graphene, carbon fibers, carbon nanofibers, carbon nanotubes, and combinations thereof, and more preferably the electronically conductive material is a combination of acetylene black and carbon fibers (e.g. vapor grown carbon fibers (VGCF)).

24 - 25 . (canceled)

26 . The electrode material of claim 18 , further comprising a binder comprising the polymer as an additive, wherein the ratio of binder to polymer is preferably within the range of from about 6:1 to about 2:1.

27 . (canceled)

28 . The electrode material of claim 26 , wherein the binder is selected from the group consisting of a polymeric binder of polyether type, a synthetic or natural rubber, and a fluorinated polymer, preferably wherein the binder is a fluorinated polymer, preferably polytetrafluoroethylene (PTFE) or polyvinylidene fluoride (PVdF), or the binder is a synthetic or natural rubber, preferably an ethylene propylene diene monomer rubber (EPDM).

29 - 33 . (canceled)

34 . An electrode comprising the electrode material as defined in claim 18 on a current collector.

35 . An electrochemical cell comprising a negative electrode, a positive electrode and an electrolyte, wherein at least one of the negative electrode or the positive electrode comprises an electrode material as defined in claim 18 .

36 . An electrochemical cell comprising a negative electrode, a positive electrode and an electrolyte, wherein at least one of the positive electrode and negative electrode is as defined in claim 34 .

37 . The electrochemical cell of claim 35 , wherein the electrolyte is a liquid electrolyte comprising a salt in a solvent, or a gel electrolyte comprising a salt in a solvent and optionally a solvating polymer, or a solid polymer electrolyte comprising a salt in a solvating polymer, and wherein the salt is preferably a lithium salt.

38 - 40 . (canceled)

41 . A battery comprising at least one electrochemical cell as defined in claim 35 , wherein said battery is preferably a lithium-ion battery.

42 . (canceled)

43 . The electrochemical cell of claim 36 , wherein the electrolyte is a liquid electrolyte comprising a salt in a solvent, or a gel electrolyte comprising a salt in a solvent and optionally a solvating polymer, or a solid polymer electrolyte comprising a salt in a solvating polymer, and wherein the salt is preferably a lithium salt.

44 . A battery comprising at least one electrochemical cell as defined in claim 36 , wherein said battery is preferably a lithium-ion battery.

Assignees

• Hydro Quebec
• Murata Manufacturing Co

Inventors

• Daigle Jean-Christophe
• Asakawa Yuichiro
• Zaghib Karim

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C08F132/08

  having condensed rings · CPC title

• H01M4/623 Primary

  fluorinated polymers · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2004/027

  Negative electrodes · CPC title