Self-releasing in-mold coating (imc) for coating substrates

Patent metadata

Field	Value
Publication number	US-2022010168-A1
Application number	US-201917295840-A
Country	US
Kind code	A1
Filing date	Nov 8, 2019
Priority date	Nov 23, 2018
Publication date	Jan 13, 2022
Grant date	—

Abstract

Described herein is a composition which is suitable for coating components in an in-mold coating process, a process for coating components, and a method of using the composition for improving the flow behavior of compositions used for producing components. The composition includes at least one solvent L, at least one alkoxylated fatty acid and/or fatty alcohol, and at least one alkoxylated polysiloxane.

First claim

1 . A composition comprising
(a) at least one solvent L, (b) at least one compound of the general formula (I)
R 1 —(C═O) r —O—(AO) s —R 2   (I)

in which R 1 is a saturated or unsaturated, aliphatic hydrocarbon radical having 6 to 30 carbon atoms, R 2 is H, a PO(OH) 2 radical, or the optionally partially phosphated radical of a monosaccharide or disaccharide, or the optionally partially phosphated radical of an alditol, AO stands for one or more alkylene oxide radicals selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide, r is 0 or 1, and s is 0 to 30; (c) optionally at least one polyether-modified alkylpolysiloxane, (d) at least one polysiloxane of the general formula (II)
R 3 —Si(R 4 ) 2 —[O—Si(R 4 )(R 5 )] a —[O—Si(R 4 ) 2 ] b —O—Si(R 4 ) 2 —R 3   (II),

in which R 3 and R 4 , in each case independently of one another, are a methyl group or a (HO—CH 2 ) 2 —C(CH 2 —CH 3 )—CH 2 —O—(CH 2 ) 3 —* radical, R 5 is a methyl group, a is 0 or 1 to 10, and b is 3 to 30; and (e) optionally at least one binder B.

2 . The composition as claimed in claim 1 , wherein in the general formula (I), R 1 is a saturated or unsaturated aliphatic hydrocarbon radical having 10 to 24 carbon atoms, R 2 is H, a PO(OH) 2 radical, or the optionally partially phosphated radical of a monosaccharide or the optionally partially phosphated radical of an alditol, AO stands for one or more alkylene oxide radicals selected from the group consisting of ethylene oxide and propylene oxide, and the ethylene oxide fraction in the entirety of the radicals AO is at least 70 mol %, r is 0 or 1, and s is 0 or s is 6 to 20.

3 . The composition as claimed in claim 1 , wherein the at least one compound of the general formula (I) is present in a total amount of 0.1 to 10 wt %, based on the total weight of the composition.

4 . The composition as claimed in claim 1 , wherein the polyether-modified alkylpolysiloxane comprises at least one structural unit (R 7 ) 2 (OR 6 )SiO 1/2 and at least one structural unit (R 7 ) 2 SiO 2/2, where R 6 is an ethylene oxide, propylene oxide, and butylene oxide group, and R 7 is a C 1 -C 10 alkyl group.

5 . The composition as claimed in claim 1 , wherein the at least one polyether-modified alkylpolysiloxane is present in a total amount of 0 wt % or of 0.1 to 6 wt %, based on the total weight of the composition.

6 . The composition as claimed in claim 1 , wherein, in the general formula (II), the radical R 3 is a (HO—CH 2 ) 2 —C(CH 2 —CH 3 )—CH 2 —O—(CH 2 ) 3 —* radical, the radical R 4 is a methyl group, the radical R 5 is a methyl group, a is 0, and b is 7 to 14.

7 . The composition as claimed in claim 1 , which comprises the at least one polysiloxane of the general formula (II) in a total amount of 0.1 to 5 wt %, based on the total weight of the composition.

8 . The composition as claimed in claim 1 , wherein the at least one binder B is present in a total amount (solids content) of 20 to 50 wt %, based on the total weight of the composition.

9 . The composition as claimed in claim 1 , wherein the binder B is selected from the group consisting of (i) poly(meth)acrylates, (ii) polyurethanes, (iii) polyesters, (iv) polyethers, (v) copolymers of the stated polymers, and (vi) mixtures thereof.

10 . The composition as claimed in claim 1 , which additionally comprises at least one crosslinking agent V.

11 . The composition as claimed in claim 10 , wherein the at least one crosslinking agent V is present in a total amount of 10 wt % to 40 wt %, based on the total weight of the composition.

12 . The composition as claimed in claim 1 , which additionally comprises at least one crosslinking catalyst VK.

13 . The composition as claimed in claim 12 , wherein the at least one crosslinking catalyst VK is present in a total amount of 0.01 wt % to 3.5 wt %, based on the total weight of the composition.

14 . A process for producing a coated molding, by
(A) applying a composition as claimed in claim 1 to a surface of a molding tool to form a coating material film, (B) flashing the coating material film, (C) applying a composition forming the component to the flashed coating material film, (D) crosslinking the composition and the coating material film, and (E) subsequently removing the coated component.

15 . A method of using the composition as claimed in claim 1 , the method comprising using the composition for improving the flow behavior of compositions used for producing components.

16 . The composition as claimed in claim 1 , wherein the at least one compound of the general formula (I) is present in a total amount of 0.5 to 5 wt %, based on the total weight of the composition.

17 . The composition as claimed in claim 1 , wherein the polyether-modified alkylpolysiloxane comprises at least one structural unit (R 7 ) 2 (OR 6 )SiO 1/2 and at least one structural unit (R 7 ) 2 SiO 2/2 , wherein R 6 is a mixture of ethylene oxide and propylene oxide and butylene oxide groups, and R 7 is a methyl group.

18 . The composition as claimed in claim 1 , wherein the at least one polyether-modified alkylpolysiloxane is present in a total amount of 0.5 to 4 wt %, based on the total weight of the composition.

19 . The composition as claimed in claim 1 , wherein the at least one polysiloxane of the general formula (II) is present in a total amount of 0.5 to 4 wt %, based on the total weight of the composition.

20 . The composition as claimed in claim 1 , wherein the binder B is selected from the group consisting of (i) hydroxy-functional and/or carboxylate-functional and/or amine-functional poly(meth)acrylates, (ii) hydroxy-functional and/or carboxylate-functional and/or amine-functional polyurethanes, (iii) polyester polyols, (iv) polyether polyols, (v) copolymers in the stated polymers, and (vi) mixtures thereof.

Assignees

• Basf Coatings Gmbh

Inventors

• Reuter Karin
• Fedeler Lea
• Winzen Simon

Classifications

• C08G2110/0008

  flexible · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title

• B29C2037/0035

  the coating being applied as liquid, gel, paste or the like · CPC title

• C08G77/16

  to hydroxy groups · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title