Sinter powder (sp) comprising a first polyamide component (pa1) and a second polyamide component (pa2), where the melting point of the second polyamide component (pa2) is higher than the melting point of the first polyamide component (pa1)

Patent metadata

Field	Value
Publication number	US-2022010133-A1
Application number	US-201917280715-A
Country	US
Kind code	A1
Filing date	Sep 25, 2019
Priority date	Sep 26, 2018
Publication date	Jan 13, 2022
Grant date	—

Abstract

The present invention relates to a sinter powder (SP) comprising a first polyamide component (PA1) and a second polyamide component (PA2), where the melting point of the second polyamide component (PA2) is higher than the melting point of the first polyamide component (PA1). The present invention further relates to a method of producing a shaped body by sintering the sinter powder (SP) or by an FFF (fused filament fabrication) method, and to a shaped body obtainable by the methods of the invention. The present invention further relates to a method of producing the sinter powder (SP).

First claim

1 . A sinter powder (SP) comprising the following components:
(A) at least one first polyamide component (PA1) comprising, based on the total weight of the first polyamide component (PA1), at least 50% by weight of a first aliphatic polyamide (aPA1), where the first polyamide component (PA1) has a first melting point (T M 1) and where the first aliphatic polyamide (aPA1) has been formed from repeat units having a first ratio (V1) per repeat unit of CH 2 groups to NHCO groups in the range from 4 to 6, (B) at least one second polyamide component (PA2) comprising, based on the total weight of the second polyamide component (PA2), at least 50% by weight of a second aliphatic polyamide (aPA2), where the second polyamide component (PA2) has a second melting point (T M 2) and where the second aliphatic polyamide (aPA2) has been formed from repeat units having a second ratio (V2) per repeat unit of CH 2 groups to NHCO groups in the range from 4 to 6, where the second melting point (T M 2) is higher than the first melting point (T M 1) and where the quotient (Q) of the numerical value of the second ratio (V2) divided by the numerical value of the first ratio (V1) is in the range from 0.6 to 1.5.

2 . The sinter powder (SP) according to claim 1 , wherein the differential between second melting point (T M 2) and first melting point (T M 1) is in the range from 20 to 70 K.

3 . The sinter powder (SP) according to claim 1 , wherein the second melting point (T M 2) is in the range from 170 to 300° C. and the first melting point (T M 1) is in the range from 150 to 280° C.

4 . The sinter powder (SP) according to claim 1 , wherein the sinter powder (SP) comprises:
5% to 95% by weight of component (A), 5% to 95% by weight of component (B), 0% to 5% by weight of at least one free flow aid, 0% to 5% by weight of at least one additive and 0% to 40% by weight of at least one reinforcer, based in each case on the total weight of the sinter powder (SP).

5 . The sinter powder (SP) according to claim 1 , wherein the first ratio (V1) is in the range from 4.5 to 5.5, and
the second ratio (V2) is in the range from 4.5 to 5.5, and the quotient (Q) is in the range from 0.8 to 1.2.

6 . The sinter powder (SP) according to claim 1 , wherein the first aliphatic polyamide (aPA1) is at least one aliphatic polyamide selected from the group consisting of PA6/66, PA6 and PA66/6 and
the second aliphatic polyamide (aPA2) is at least one aliphatic polyamide selected from the group consisting of PA6, PA66/6 and PA66.

7 . The sinter powder (SP) according to claim 1 , wherein the first polyamide component (PA1) comprises 50% to 90% by weight of the first aliphatic polyamide (aPA1) selected from the group consisting of PA6/66, PA6 and PA66/6 and 10% to 50% by weight of a first (semi)aromatic polyamide (arPA1), based on the total weight of the first polyamide component (PA1), and the second polyamide component (PA2) comprises 50% to 90% by weight of the second aliphatic polyamide (aPA2) selected from the group consisting of PA6, PA66/6 and PA66 and 10% to 50% by weight of a second (semi)aromatic polyamide (arPA2), based on the total weight of the second polyamide component (PA2).

8 . The sinter powder (SP) according to claim 1 , wherein the sinter powder (SP) has a median particle size (D50) in the range from 10 to 250 μm.

9 . The sinter powder (SP) according to claim 1 , wherein the sinter powder (SP) has
a D10 in the range from 10 to 60 μm, a D50 in the range from 25 to 90 μm and a D90 in the range from 50 to 150 μm.

10 . The sinter powder (SP) according to claim 1 , wherein the sinter powder (SP) has a sintering window (W SP ), where the sintering window (W SP ) is the difference between the onset temperature of melting (T M2 onset ) and the onset temperature of crystallization (T C2 onset ) and where the sintering window (W SP ) is in the range from 10 to 40 K.

11 . The sinter powder (SP) according to claim 1 , wherein the sinter powder (SP) comprises
10% to 90% by weight of component (A), 10% to 90% by weight of component (B), 0.1% to 1% by weight of at least one free flow aid, 0.1% to 2.5% by weight of at least one additive, and 0% to 40% by weight of at least one reinforcer, based in each case on the total weight of the sinter powder (SP).

12 . A method of producing a shaped body, comprising the steps of:
is) providing a layer of the sinter powder (SP) according to claim 1 , iis) exposing the layer of the sinter powder (SP) provided in step is) in order to form the shaped body.

13 . A method of producing a shaped body, comprising the steps of:
if) melting the sinter powder (SP) according to claim 1 , iif) depositing the molten sinter powder (SP) in a construction space in order to form the shaped body.

14 . The use of the sinter powder (SP) according to claim 1 in a sintering method or in a fused filament fabrication method.

15 . A method of producing the sinter powder (SP) according to claim 1 , comprising the steps of
a) providing the first polyamide component (PA1) b) providing the second polyamide component (PA2) c) mixing the first polyamide component (PA1) and the second polyamide component (PA2).

16 . The sinter powder (SP) according to claim 1 , further comprising:
(C) at least one free-flow aid, (D) at least one additive, and (E) at least one reinforcer.

17 . The sinter powder (SP) according to claim 5 , wherein the first ratio (V1) is in the range from 4.8 to 5.2, the second ratio (V2) is in the range from 4.8 to 5.2, and the quotient (Q) is in the range from 0.9 to 1.1.

18 . The sinter powder (SP) according to claim 5 , wherein the first ratio (V1) is in the range from 4.9 to 5.1, the second ratio (V2) is in the range from 4.9 to 5.1, and the quotient (Q) is in the range from 0.96 to 1.04.

19 . The sinter powder (SP) according to claim 5 , wherein the first ratio (V1) is in the range from 4.95 to 5.05, the second ratio (V2) is in the range from 4.95 to 5.05, and the quotient (Q) is in the range from 0.98 to 1.02.

Assignees

• Basf Se

Inventors

• Gabriel Claus
• Meier Thomas
• Gottke Clemens
• Zepp Angelika

Classifications

• C08L77/02 Primary

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B29C64/118

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title