Fluid-permeable electrodes, fluid-permeable electrochemical cells and integrated fluid-permeable analytical devices, and fluid-permeable devices for electrocatalytic conversion and electrosynthesis, and for fluid decontamination

Patent metadata

Field	Value
Publication number	US-2022006096-A1
Application number	US-202117365844-A
Country	US
Kind code	A1
Filing date	Jul 1, 2021
Priority date	Jul 1, 2020
Publication date	Jan 6, 2022
Grant date	—

Abstract

Provided is a fluid-permeable electrode having an open-cell structure and having: a layer of an electroactive material deposited on a surface of an open cell substrate that is formed of a material that differs from the electroactive material; or a fluid-permeable electrode having an open-cell structure and consisting of an electroactive material.

First claim

What is claimed is:

1 . A fluid-permeable electrode having an open-cell structure and comprising:
a layer of an electroactive material deposited on a surface of an open cell substrate that is formed of a material that differs from the electroactive material; or a fluid-permeable electrode having an open-cell structure and consisting of an electroactive material.

2 . The fluid-permeable electrode of claim 1 , wherein
the open cell substrate comprises: mesh or foam, screen or cloth; and the open cell substrate comprises one or more of: copper and its alloys; brass; nickel and its alloys; iron and its alloys; steel; stainless steel; and transition series metals including one or more of: alloys of transition metals; alloys of metals; pure gold; pure silver; and pure platinum.

3 . The fluid-permeable electrode of claim 1 , wherein
the electroactive material comprises gold, silver, platinum, silver chloride, a noble metal, noble metal alloy, transition metal, transition metal alloy, graphene, carbon nanotubes, or an electroconductive polymer.

4 . The fluid-permeable electrode of claim 1 , wherein
the electroactive material further comprises nanoparticles, or zeolites.

5 . The fluid-permeable electrode of claim 1 , wherein
the layer of electroactive material is applied by screen printing, electrodeposition, electroless deposition, chemical vapor deposition, dip coating, sputtering, or atomic layer deposition.

6 . A device comprising
one or more of the fluid-permeable electrodes of claim 1 , integrated into a fabric, paper, or plastic film substrate.

7 . The device of claim 6 , in the form of an analyte sensor to detect a biomolecule, metabolite, an enzyme, a protein, an antibody, a metal, metallic ions, bacteria, pesticides, or an organic pollutant or organic compounds.

8 . A fluid-permeable electrochemical cell (ECC), comprising
one or more of the fluid-permeable electrodes of claim 1 ; and a fluid, wherein the electrode and the fluid are disposed inside a compartment comprising an inlet port and an outlet port, and wherein the fluid is a gas or liquid.

9 . A fluid-permeable analytical device for the detection of an analyte, biomolecule, metabolite, an enzyme, a protein, an antibody, a metal, metallic ions, bacteria, pesticides, or an organic pollutant or organic compounds, the device comprising the fluid-permeable electrochemical flow cell of claim 8 .

10 . A fluid-permeable device for the decontamination of aqueous fluids, comprising the fluid-permeable electrochemical flow cell of claim 8 .

11 . A device comprising:
the ECC of claim 8 , operatively coupled to a syringe, with a sample in solution disposed therein and a reagent disposed in the solution, wherein the ECC is electrically coupled to a electrochemical analyzer, which is operatively connected to an electronic device, whereby the device is configured to capture information regarding the sample while the solution is urged out of the syringe and through the ECC.

12 . A method of detecting analyte in liquid samples, comprising:
filling the syringe of the device of claim 11 with a liquid sample of one or more of environmental water; drinking water; food extracts; liquid beverage; liquid food sample; whole blood; serum; urine; and plasma, wherein the reagent is either a liquid form or embedded a reagent support substrate; urging the liquid sample through the ECC, thereby determining via an electrochemical analyzer, a concentration of one or more analyte in the liquid sample, the one or more analyte including biomolecule, metabolite, an enzyme, a protein, an antibody, a metal, metallic ions, bacteria, pesticides, or an organic pollutant or organic compounds; and graphing data representing the output of the electrochemical analyzer on the external device to thereby illustrate the concentration.

13 . A device comprising:
the ECC of claim 8 , operatively coupled to a conduit for receiving a gas, and configured for being decoupled from the conduit after receiving the gas and then being operatively coupled to a syringe with a solution disposed therein and a reagent disposed in the solution, wherein the ECC is electrically coupled to an electrochemical analyzer, which is operatively connected to an electronic device, whereby the device is configured to capture information regarding the gas while the solution is urged out of the syringe and through the ECC.

14 . A method of detecting analyte in a gas, comprising:
directing a gas into the conduit of the device of claim 13 , wherein the reagent is either a liquid form or embedded a reagent support substrate; decoupling the conduit from the ECC and coupling the syringe to the ECC; and urging the solution through the ECC, thereby determining via electrochemical analyzer a concentration of one or more analyte in the gas, the one or more analyte including an organic pollutant or organic compounds, and graphing data representing the output of the electrochemical analyzer on the external device to thereby illustrate the concentration.

15 . A device comprising:
the ECC of claim 8 , operatively coupled to a fluid supply and in fluid communication with a disinfectant, wherein the ECC is electrically coupled to a power source, whereby the device is configured to decontaminate the fluid gas while the fluid is urged out of the syringe and through the ECC.

16 . A method of disinfecting a fluid, comprising:
urging the fluid through the ECC of the device of claim 15 , thereby decontaminating the fluid; and collecting from the ECC the fluid that is decontaminated.

17 . A method of performing a catalytic conversion, comprising: placing electrodes of claim 1 in a beaker or H-cell, or fluid permeable cell, and engaging the electrodes with a reagent mixture, and providing power to the electrodes.

18 . A device comprising:
a plurality of the cells of claim 8 , connected in series, including a first cell with a first inlet port; a fluid supply connected directly or indirectly via tubing to the first inlet port on the first cell, wherein the plurality of cells are electrically coupled to an electrochemical analyzer, which is operatively connected to an electronic device, wherein each of the cells includes a respectively unique set of the electrodes, so that the device is configured to detect a plurality of analytes.

19 . A device comprising the cell of claim 8 , connected via tubing to a pump and a fluid reservoir, and an electrochemical analyzer, wherein the device is configured as an electrochemical detection flow detection cell.

20 . A fluid flow control device including a fluid tube wrapped around a core so that the tube turns and twists about the core, wherein the fluid tube defines an input and an output flow rate.

Assignees

• Univ Massachusetts

Inventors

• Christodouleas Dionysios
• Kazi Abbas Parvez
• Routsi Anna Maria

Classifications

• C25B11/031

  Porous electrodes · CPC title

• Y02E60/50

  Fuel cells · CPC title

• C02F2001/46142

  Catalytic coating · CPC title

• C02F2001/46157

  Perforated or foraminous electrodes · CPC title

• C02F1/46109

  Electrodes · CPC title