Producing polyolefin products

Patent metadata

Field	Value
Publication number	US-2022002455-A1
Application number	US-202117475851-A
Country	US
Kind code	A1
Filing date	Sep 15, 2021
Priority date	Feb 11, 2014
Publication date	Jan 6, 2022
Grant date	—

Abstract

Catalyst systems and methods for making and using the same. A method of methylating a catalyst composition while substantially normalizing the entiomeric distribution is provided. The method includes slurrying the organometallic compound in dimethoxyethane (DME), and adding a solution of RMgBr in DME, wherein R is a methyl group or a benzyl group, and wherein the RMgBr is greater than about 2.3 equivalents relative to the organometallic compound. After the addition of the RMgBr, the slurry is mixed for at least about four hours. An alkylated organometallic is isolated, wherein the methylated species has a meso/rac ratio that is between about 0.9 and about 1.2.

First claim

What is claimed is:

1 . A method of forming a catalyst composition, comprising:
dissolving 1-ethylindenyllithium in dimethoxyethane to form a precursor solution; cooling the precursor solution to about −20° C.; adding solid ZrCl 4 over about five minutes to start a reaction; continuing the reaction overnight; removing volatiles to form a raw product; extracting the raw product with CH 2 Cl 2 ; and removing the CH 2 Cl 2 under vacuum to form a mixture comprising about 19 parts meso-(1-EtInd) 2 ZrCl 2 and about 1 part rac-(1-EtInd) 2 ZrCl 2 .

2 . The method of claim 1 , comprising:
slurrying the mixture in Et 2 O; adding at least about 2.3 equivalents of RMgBr dissolved in ether to the slurry, wherein R is a benzyl group, a methyl group, or a mixture thereof; drying the slurry; extracting with warm hexanes; and filtering to form a catalyst component comprising about 19 parts meso-(1-EtInd) 2 ZrR 2 and about 1 part rac-(1-EtInd) 2 ZrR 2 .

3 . The method of claim 2 , comprising:
fluidizing a catalyst support with an inert gas; heating the support to remove any adsorbed water to form a dried support; and storing the dried support under an inert gas.

4 . The method of claim 3 , comprising:
forming a slurry of the dried support in a mixture of toluene and methylaluminoxane; and drying the mixture to form methyl amluminoxane supported on silica (SMAO).

5 . The method of claim 4 , comprising:
adding pentane to the SMAO to form a slurry; dissolving the catalyst component in toluene to form a toluene solution; adding the toluene solution to the slurry to form a catalyst; filtering the catalyst from the slurry; and drying the catalyst.

Assignees

• Univation Tech Llc

Inventors

• Rix Francis C
• Todd Alexander D
• Harlan C Jeff

Classifications

• C08F4/65925 Primary

  two cyclopentadienyl rings being mutually non-bridged · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/18

  with non-conjugated dienes, e.g. EPT rubbers · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title