Hydrogen production from hydrocarbons with near zero greenhouse gas emissions

Patent metadata

Field	Value
Publication number	US-2022002153-A1
Application number	US-202117480444-A
Country	US
Kind code	A1
Filing date	Sep 21, 2021
Priority date	Apr 8, 2019
Publication date	Jan 6, 2022
Grant date	—

Abstract

Methods and systems for producing hydrogen substantially without greenhouse gas emissions, one method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

First claim

That claimed is:

1 . A system for producing hydrogen substantially without greenhouse gas emissions, the system comprising:
a hydrogen production unit with a hydrocarbon fuel inlet operable to produce a product gas comprising hydrogen and carbon dioxide from hydrocarbon fuel; a hydrogen separation unit operable to separate hydrogen from the product gas to create a hydrogen product stream and a byproduct stream comprising CO 2 ; and an injection well operable to inject the byproduct stream into a reservoir containing mafic rock to allow components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

2 . The system according to claim 1 , where the mafic rock comprises basaltic rock.

3 . The system according to claim 1 , further comprising a byproduct treatment unit to treat the byproduct stream to separate and purify CO 2 from other components and to increase CO 2 concentration of the byproduct stream for injection into the reservoir.

4 . The system according to claim 1 , further comprising a compressor to liquefy CO 2 in the byproduct stream for injection into the reservoir.

5 . The system according to claim 1 , further comprising a mixing unit to mix the byproduct stream with water, the byproduct stream comprising H 2 S.

6 . The system according to claim 1 , further comprising a reaction unit to react the separated hydrogen with nitrogen to form compressed liquid ammonia.

7 . The system according to claim 6 , further comprising a transportation unit to transport the compressed liquid ammonia and return the compressed liquid ammonia to hydrogen and nitrogen via electrolysis for use of hydrogen as a hydrogen fuel source.

8 . The system according to claim 1 , where the hydrogen production unit includes a steam reformer or partial oxidation reactor.

9 . The system according to claim 1 , where components of the produced byproduct stream react in situ with components of the mafic rock to precipitate products selected from the group consisting of: calcium carbonates, magnesium carbonates, iron carbonates, and combinations thereof.

10 . The system according to claim 1 , where the reservoir is between about 250 m and about 2,200 m below the surface and is between about 30° C. and about 325° C.

11 . The system according to claim 1 , where the reservoir is between about 350 m and about 1,500 m below the surface and is less than about 325° C.

Assignees

• Saudi Arabian Oil Co

Inventors

• Arkadakskiy Serguey Viktorov
• Al-Utaibi Humoud W
• Kunnummal Noushad
• Ahmed Zeyad Tareq
• Al-Jar Faisal Salman
• Stapp Christopher Ellis

Classifications

• C01B2203/86

  Carbon dioxide sequestration · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/06

  Integration with other chemical processes · CPC title

• C01B2203/025

  containing a partial oxidation step · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title