Secondary electrochemical cells with separator and electrolyte combination

Patent metadata

Field	Value
Publication number	US-2021367262-A1
Application number	US-202117444371-A
Country	US
Kind code	A1
Filing date	Aug 3, 2021
Priority date	Nov 24, 2009
Publication date	Nov 25, 2021
Grant date	—

Abstract

A secondary electrochemical cell comprises an anode, a cathode including electrochemically active cathode material, a separator between the anode and the cathode, and an electrolyte. The electrolyte comprises at least one salt dissolved in at least one organic solvent. The separator in combination with the electrolyte has an area-specific resistance of less than about 2 ohm-cm2.

First claim

What is claimed is:

1 . A secondary electrochemical cell comprising an anode; a cathode comprising electrochemically active cathode material, said electrochemically active cathode material comprises one or more electrochemically active cathode materials chosen from the group of lithium-transition-metal phosphate, sodium-transition-metal phosphate, and lithium-metal oxide; a separator comprising one or more separator materials chosen from the group of polypropylene, polyethylene, polyvinylidene, and poly(vinylidene fluoride) disposed between said anode and said cathode; and an electrolyte said electrolyte comprising at least one salt dissolved in at least one organic solvent, wherein said separator in combination with said electrolyte has an area-specific resistance of less than about 2 ohm-cm 2 and wherein said lithium-metal oxide comprises one or more lithium-metal oxides chosen from the group of LiCoO 2 , LiNi x Mn 2 O 4 , Li(Ni x Co y Al z )O 2 , Li(Ni x Mn y Co z )O 2 , and aLi 2 MnO 3 -(1-a)Li(Ni x Mn y Co z )O 2 , wherein 0<a<1, 0≤x≤1, 0≤y≤1, and 0≤z≤1.

2 . The electrochemical cell of claim 1 wherein the lithium-transition-metal phosphate comprises LiMPO 4 wherein M comprises one or more metals chosen from the group of vanadium, chromium, manganese, iron, cobalt, tin, niobium, molybdenum, zirconium, zinc, and nickel.

3 . The electrochemical cell of claim 1 wherein the sodium-transition-metal phosphate comprises NaMPO 4 wherein M comprises one or more metals chosen from the group of vanadium, chromium, manganese, iron, cobalt, tin, niobium, molybdenum, zirconium, zinc, and nickel.

4 . The electrochemical cell of claim 1 wherein the separator porosity is between about 30% and about 70%.

5 . The electrochemical cell of claim 1 wherein the at least one salt comprises one or more salts chosen from the group of lithium perchlorate (LiClO 4 ), lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluorooxalatophosphate (LiPF 4 (C 2 O 4 )), lithium tetrafluoroborate (LiBF 4 ), lithium trifluorosulfonate (LiSO 3 CF 3 ), lithium trifluorosulfonimide (LiN(SO 2 CF 3 ) 2 ), lithium bis(pentafluoroethanesulfonyl)imide (LiN(SO 2 CF 2 CF 3 ) 2 ) (LiBETi), lithium bis(oxalato)borate (LiBOB), lithium hexafluoroarsenate (LiAsF 6 ), lithium fluorosulfonimide (LiFSI), sodium perchlorate (NaClO 4 ), sodium trifluorosulfonimide (NaTFSI), and sodium trifluorosulfonate (NaTFS).

6 . The electrochemical cell of claim 1 wherein the at least one salt is at a concentration within the electrolyte from about 0.5 M to about 1.8 M.

7 . The electrochemical cell of claim 1 wherein the electrolyte comprises one or more electrolyte additives chosen from the group of propane sultone (PS), vinylene carbonate (VC), succinonitrile (SN), cyclohexylbenzene (CHB), tetra ethyl orthosilicate (TEOS), lithium bis(oxalato)borate (LiBOB), tetramethoxy titanium (TMTi), dimethyl acetamide (DMAc), lithium perchlorate (LiClO 4 ), and propargyl methane sulfonate (PMS).

8 . The electrochemical cell of claim 1 wherein the electrolyte comprises at least one electrolyte additive at a concentration from about 0.05 to about 5 weight percent of the electrolyte solution.

9 . The electrochemical cell of claim 1 wherein the organic solvent comprises one or more organic solvents chosen from the group of ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), dimethyl carbonate (DMC), ethyl methyl dicarbonate (EMC), diethyl carbonate (DEC), dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, dibutyl carbonate, butylmethyl carbonate, butylethyl carbonate, and butylpropyl carbonate.

10 . The electrochemical cell of claim 1 wherein the organic solvent is at a concentration from about 0.5 weight percent to about 95 weight percent of the electrolyte solution.

11 . The electrochemical cell of claim 1 wherein the anode comprises an electrochemically active anode material chosen from one or more in the group of graphite, spheroidal natural graphite, mesocarbon microbead, coke, mesophase carbon fibers, fullerene, graphene, carbon nanotube, single-walled carbon nanotube (SWCNT), multi-wall carbon nanotube (MWCNT), vapor-phase grown carbon fiber (VGCF), silicon, silicon alloy, tin, tin alloy, and lithium titanate.

12 . The electrochemical cell of claim 1 wherein the anode comprises a conductive additive chosen from one or more in the group of graphite, carbon black, acetylene black, vapor-phase grown carbon fiber (VGCF), carbon nanotube, fullerenic carbon nanotube, vitreous carbon, carbon fiber, and graphene.

13 . The electrochemical cell of claim 1 wherein the separator has a thickness from about 8 to about 30 micrometers.

14 . The electrochemical cell of claim 1 wherein the area-specific resistance is from about 1.0 to about 1.9.

15 . The electrochemical cell of claim 1 wherein the cathode comprises a conductor material chosen from one or more in the group of carbon black, graphite, fullerenes, graphenes, carbon nanotube, single-walled carbon nanotube (SWCNT), multi-wall carbon nanotube (MWCNT), and vapor-phase grown carbon fibers (VGCF).

16 . The electrochemical cell of claim 1 wherein said electrochemical cell has a total anode-to-cathode (A/C) ratio of less than about 1.5.

17 . The electrochemical cell of claim 16 wherein the total anode-to-cathode (A/C) ratio is from about 1.0 to about 1.35.

Assignees

• Duracell Us Operations Inc

Inventors

• Issaev Nikolai Nikolaevich
• Kaplan Alexander
• Kao Junan
• Nanjundaswamy Kirakodu Seetharama
• Pozin Michael
• Zhang Fan

Classifications

• H01M50/417

  Polyolefins · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M50/491

  Porosity · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title