Devices and methods for high voltage and solar applications

Patent metadata

Field	Value
Publication number	US-2021366664-A1
Application number	US-202117332008-A
Country	US
Kind code	A1
Filing date	May 27, 2021
Priority date	Mar 23, 2016
Publication date	Nov 25, 2021
Grant date	—

Abstract

Provided herein are devices comprising one or more cells, and methods for fabrication thereof. The devices may be electrochemical devices. The devices may include three-dimensional supercapacitors. The devices may be microdevices such as, for example, microsupercapacitors. In some embodiments, the devices are three-dimensional hybrid microsupercapacitors. The devices may be configured for high voltage applications. In some embodiments, the devices are high voltage microsupercapacitors. In certain embodiments, the devices are high voltage asymmetric microsupercapacitors. In some embodiments, the devices are integrated microsupercapacitors for high voltage applications.

First claim

1 . An electrochemical system comprising, a planar array of interconnected electrochemical cells comprising:
three or more first electrodes, each first electrode comprising three or more first microelectrodes; three or more second electrodes, each second electrode comprising three or more second microelectrodes, wherein each first microelectrode is interdigitated with one second microelectrode to form one electrochemical cell, wherein at least one of the first electrodes and the second electrodes comprises a three-dimensional interconnected corrugated carbon-based network (ICCN) comprising a plurality of expanded and interconnected carbon layers, and a pseudocapacitive material.

2 . The electrochemical system of claim 1 wherein the at least one of the first electrodes and the second electrodes further comprises a plurality of pores.

3 . The electrochemical system of claim 2 wherein the pseudocapacitive material is located in the plurality of pores.

4 . The electrochemical system of claim 1 , wherein the pseudocapacitive material comprises pseudocapacitive nanostructures comprising MnO 2 , RuO 2 , Co 3 O 4 , NiO, Fe 2 O 3 , CuO, MoO 3 , V 2 O 5 , Ni(OH) 2 , or any combination thereof.

5 . The electrochemical system of claim 1 , further comprising an electrolyte disposed between at least two electrodes of the three or more first electrodes and three or more second electrodes.

6 . The electrochemical system of claim 1 , wherein at least one electrochemical cell is capable of outputting a voltage of at least about 5 volts.

7 . The electrochemical system of claim 1 , wherein the electrochemical system is capable of outputting a voltage of at least 100 volts.

8 . The electrochemical system of claim 1 , wherein at least one electrochemical cell has an energy density of at least about 22 watt-hours per liter (Wh/L).

9 . The electrochemical system of claim 1 , wherein the planar array of interconnected electrochemical cells has a capacitance per footprint of at least about 380 millifarads per square centimeter (mF/cm 2 ).

10 . The electrochemical system of claim 1 , wherein the planar array of interconnected electrochemical cells has a volumetric capacitance of at least about 1,100 farads per cubic centimeter (F/cm 3 ).

11 . The electrochemical system of claim 1 , wherein the planar array of interconnected electrochemical cells is arranged in an interdigitated structure.

12 . The electrochemical system of claim 1 further comprising a current collector coupled to at least one of the first electrode and the second electrode.

13 . A method for fabricating an electrochemical system, comprising:
forming a carbonaceous film; forming a carbonaceous framework from the carbonaceous film comprising a three-dimensional interconnected corrugated carbon-based network (ICCN) comprising a plurality of expanded and interconnected carbon layers; patterning the carbonaceous framework to form an array of two or more cells in one step, wherein the array of two or more cells comprises three or more first electrodes, each first electrode comprising three or more first microelectrodes, and three or more second electrodes, each second electrode comprising three or more second microelectrodes, wherein each first microelectrode is interdigitated with one second microelectrode to form one electrochemical cell; and electrodepositing a pseudocapacitive material onto the three or more first electrodes, the three or more second electrodes, or both. forming a charge storing active material comprising the three-dimensional ICCN having a plurality of pores from the carbonaceous film; patterning the three-dimensional ICCN to form the array of two or more cells, wherein each cell comprises at least two electrodes; and electrodepositing pseudocapacitive nanostructures within at least a portion of the plurality of pores.

14 . The method of claim 13 , wherein the array of two or more cells is a planar array.

15 . The method of claim 14 , wherein the planar array comprises interconnected electrochemical cells directly fabricated in one step.

16 . The method of claim 13 , wherein the patterning of the carbonaceous framework comprises light scribing.

17 . The method of claim 13 , wherein the patterning of the carbonaceous framework forms two or more interdigitated electrodes.

18 . The method of claim 13 , wherein the pseudocapacitive material comprises MnO 2 , RuO 2 , Co 3 O 4 , NiO, Fe 2 O 3 , CuO, MoO 3 , V 2 O 5 , Ni(OH) 2 , or any combination thereof.

19 . The method of claim 13 , further comprising depositing an electrolyte on at least one first electrode and at least one second electrode.

20 . The method of claim 13 , wherein both the first electrodes and the second electrodes comprise the pseudocapacitive material.

21 . The method of claim 13 , further comprising connecting two or more of the three or more first electrodes, two or more of the three or more second electrodes, or both.

22 . The method of claim 13 , wherein the forming of the carbonaceous framework from the carbonaceous film comprises light scribing.

23 . The method of claim 13 , wherein the plurality of expanded and interconnected carbon layers is corrugated and one atom thick.

Assignees

• Univ California
• Nanotech Energy Inc

Inventors

• El-Kady Maher F
• Kaner Richard B
• Kavanaugh Jack

Classifications

• Y02T10/70

  Energy storage systems for electromobility, e.g. batteries · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01M12/00

  Hybrid cells; Manufacture thereof (hybrid capacitors H01G11/00) · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title