Catalytic metal fiber felt and articles made therefrom
US-2019329234-A1 · Oct 31, 2019 · US
US2021268484A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2021268484-A1 |
| Application number | US-201917253926-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jun 20, 2019 |
| Priority date | Jun 29, 2018 |
| Publication date | Sep 2, 2021 |
| Grant date | — |
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A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The at least one additional metal is present in an amount from 5.0 at % to 20.0 at %.
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1 . A hybrid catalyst comprising: a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese; and a microporous catalyst component that is a molecular sieve having 8-MR pore openings, wherein the at least one additional metal is present in an amount from 5.0 at % to 20.0 at %. 2 . The hybrid catalyst of claim 1 , wherein the at least one additional metal is iron. 3 . The hybrid catalyst of claim 1 , wherein the at least one additional metal is manganese. 4 . The hybrid catalyst of claim 1 , wherein the microporous catalyst component is SAPO-34. 5 . The hybrid catalyst of claim 1 , wherein a ratio of chromium to zinc is from 0.35 to 0.45. 6 . The hybrid catalyst of claim 1 , wherein a ratio of chromium to zinc is about 0.40. 7 . The hybrid catalyst of claim 1 , wherein the metal oxide catalyst component is calcined at a temperature less than 600° C. 8 . The hybrid catalyst of claim 7 , wherein the metal oxide catalyst component is calcined at a temperature less than 500° C. 9 . The hybrid catalyst of claim 7 , wherein the metal oxide catalyst component is calcined at temperatures from 300° C. to less than 600° C. 10 . The hybrid catalyst of claim 1 , wherein the at least one additional metal is present in an amount from 5.0 at % to 17.5 at %. 11 . The hybrid catalyst of claim 1 , wherein the at least one additional metal is present in an amount from 7.5 at % to 17.5 at %. 12 . A process for preparing C 2 and C 3 olefins comprising: introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and converting the feed stream into a product stream comprising C 2 and C 3 olefins in the reaction zone in the presence of the hybrid catalyst of claim 1 . 13 . The hybrid catalyst of claim 2 , wherein a ratio of chromium to zinc is from 0.35 to 0.45. 14 . The hybrid catalyst of claim 3 , wherein a ratio of chromium to zinc is from 0.35 to 0.45. 15 . The hybrid catalyst of claim 2 , wherein a ratio of chromium to zinc is from 0.35 to 0.45. 16 . The hybrid catalyst of claim 3 , wherein a ratio of chromium to zinc is from 0.35 to 0.45. 17 . The hybrid catalyst of claim 2 , wherein the metal oxide catalyst component is calcined at a temperature less than 600° C. 18 . The hybrid catalyst of claim 3 , wherein the metal oxide catalyst component is calcined at a temperature less than 600° C. 19 . The hybrid catalyst of claim 2 , wherein the at least one additional metal is present in an amount from 5.0 at % to 17.5 at %. 20 . The hybrid catalyst of claim 3 , wherein the at least one additional metal is present in an amount from 5.0 at % to 17.5 at %.
characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 (C07C2521/16 takes precedence) · CPC title
Iron · CPC title
Manganese · CPC title
Chromium · CPC title
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