Aqueous surface coating solution composition and polyester film structure

Patent metadata

Field	Value
Publication number	US-2021253895-A1
Application number	US-202017030586-A
Country	US
Kind code	A1
Filing date	Sep 24, 2020
Priority date	Feb 18, 2020
Publication date	Aug 19, 2021
Grant date	—

Abstract

An aqueous surface coating solution composition and a polyester film structure are provided. The aqueous surface coating solution composition includes 5-20 wt % of a resin composition and 0.15-5 wt % of an inorganic particle dispersion liquid. The resin composition includes 0.01-10 wt % of a polyester resin, 2-19 wt % of an acrylate-grafted polyurethane resin, and 0.5-10 wt % of a cross-linking agent. The inorganic particle dispersion liquid includes a plurality of first inorganic filling particles and a plurality of second inorganic filling particles, and the first inorganic filling particles have a larger average particle diameter than the second inorganic filling particles.

First claim

What is claimed is:

1 . An aqueous surface coating solution composition, which is usable for forming a surface coating on a polyester film, wherein the aqueous surface coating solution composition comprises 5-20 wt % of a resin composition and 0.15-5 wt % of an inorganic particle dispersion liquid;
wherein the resin composition includes 0.01-10 wt % of a polyester resin, 2-19 wt % of an acrylate-grafted polyurethane resin, and 0.5-10 wt % of a cross-linking agent; wherein the inorganic particle dispersion liquid includes a plurality of first inorganic filling particles and a plurality of second inorganic filling particles, and the first inorganic filling particles have a larger average particle diameter than the second inorganic filling particles; and wherein the first inorganic filling particles and the second inorganic filling particles are uniformly dispersed in the surface coating, so that the surface coating has a surface roughness Ra between 0.004 μm and 0.025 μm.

2 . The aqueous surface coating solution composition according to claim 1 , wherein the average particle diameter of the first inorganic filling particles is between 100 nm and 180 nm, and the content of the first inorganic filling particles, based on a total weight of the surface coating, is 0.05 wt % to 1 wt %; wherein the average particle diameter of the second inorganic filling particles is between 30 nm and 80 nm, and the content of the second inorganic filling particles, based on the a total weight of the surface coating, is 0.2 wt % to 3 wt %.

3 . The aqueous surface coating solution composition according to claim 2 , wherein surfaces of the first inorganic filling particles and surfaces of the second inorganic filling particles are modified with an epoxy-functional silane coupling agent.

4 . The aqueous surface coating solution composition according to claim 1 , the first inorganic filling particles and the second inorganic filling particles are each silicon oxide, titanium oxide, zirconium oxide, aluminum oxide, aluminum hydroxide, calcium carbonate, magnesium carbonate or barium sulfate particles.

5 . The aqueous surface coating solution composition according to claim 1 ,
wherein the cross-linking agent is selected from at least one of a melamine resin, a melamine modified resin, a carbodiimide-based cross-linking agent, and an oxazoline-based cross-linking agent.

6 . A polyester film structure, comprising:
a polyester film; and a surface coating formed on a surface of the polyester film, wherein the surface coating is formed by the aqueous surface coating solution composition according to claim 1 and has a surface roughness Ra between 0.004 μm and 0.025 μm.

7 . The polyester film structure according to claim 6 , wherein the average particle diameter of the first inorganic filling particles is between 100 nm and 180 nm, and the content of the first inorganic filling particles, based on the total weight of the surface coating, is 0.05 wt % to 1 wt %; wherein the average particle diameter of the second inorganic filling particles is between 30 nm and 80 nm, and the content of the second inorganic filling particles, based on the total weight of the surface coating, is 0.2 wt % to 3 wt %.

8 . The polyester film structure according to claim 7 , wherein surfaces of the first inorganic filling particles and surfaces of the second inorganic filling particles are modified with an epoxy-functional silane coupling agent, which is selected from at least one of 2-(3 4-epoxycyclohexyl)ethyltrimethoxysilane, (3-glycidoxypropyl)trimethoxysilane, (3-glycidoxypropyl)methyldiethoxysilane, and 3-glycidoxypropyl triethoxysilane.

9 . The polyester film structure according to claim 8 , wherein a visible light transmittance of the surface coating measured according to JIS K7705 test standard is at least 90%, and a haze value is less than 0.8%.

10 . The polyester film structure according to claim 6 , wherein a thickness of the polyester film is between 12 μm and 300 μm, and a thickness of the surface coating is between 30 nm and 150 nm.

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Yang Wen-Cheng
• Tsao Chun-Che
• Cheng Wen-Jui
• Yeh Chih-Fu

Classifications

• C09D175/04

  Polyurethanes · CPC title

• C09D7/68 Primary

  Particle size between 100-1000 nm · CPC title

• B32B2307/538

  Roughness · CPC title

• C09D167/025

  containing polyether sequences · CPC title

• C09D167/02 Primary

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09D167/06 takes precedence) · CPC title