Sintered compact target and method of producing sintered compact

Patent metadata

Field	Value
Publication number	US-2021237153-A1
Application number	US-202117239740-A
Country	US
Kind code	A1
Filing date	Apr 26, 2021
Priority date	Mar 17, 2008
Publication date	Aug 5, 2021
Grant date	—

Abstract

A sintered compact target containing an element(s) (A) and an element(s) (B) as defined below is provided. The sintered compact target is free from pores having an average diameter of 1 μm or more, and the number of micropores having an average diameter of less than 1 μm existing in 40000 μm2 of the target surface is 100 micropores or less. The element(s) (A) is one or more chalcogenide elements selected from S, Se, and Te, and the element(s) (B) is one or more Vb group elements selected from Bi, Sb, As, P, and N. The provided technology is able to eliminate the source of grain dropping or generation of nodules in the target during sputtering, and additionally inhibit the generation of particles.

First claim

We claim:

1 . A method of producing a sintered compact containing an element (A) and an element (B), comprising the steps of:
mixing raw material powder composed of respective elements or raw material powder of an alloy of two or more elements; vacuum hot pressing the mixed powder under conditions that satisfy the following formula: P (pressure)≤(Pf/(Tf−T 0 ))×(T−T 0 )+P 0 wherein Pf: final pressure, Tf: final temperature, P 0 : atmospheric pressure, T: heating temperature, T 0 : room temperature, and temperatures are in Celsius; and further performing hot isostatic pressing (HIP) treatment under the conditions of P hip >5×Pf; wherein the sintered compact is free from pores having an average diameter of 1 μm or more, and the number of micropores having an average diameter of less than 1 μm existing in an area of 40,000 μm 2 of the target surface is 100 micropores or less; and wherein (A): one or more chalcogenide elements selected from S, Se, and Te and (B): one or more elements selected from Bi, Sb, As, P, and N.

2 . The method of producing a sintered compact according to claim 1 , wherein a composition of the sintered compact is selected from the group consisting of Ge—Sb—Te, Ag—In—Sb—Te, and Ge—In—Sb—Te.

3 . The method of producing a sintered compact according to claim 1 , wherein raw material powder is composed of an alloy, a compound or a mixture of constituent elementary substances, or constituent elements, and wherein the average grain size of the raw material powder is 0.1 μm to 50 μm, the maximum grain size is 90 μm or less, and the purity is 4N or higher.

4 . The method of producing a sintered compact according to claim 1 , wherein, in a course of heating temperature T rising from 100° C. to 500° C. during the vacuum hot pressing, the pressure P is maintained at a constant level for 10 to 120 minutes at least in a part of a range of the heating temperature of 100° C. to 500° C.

5 . A method of producing a sintered compact containing an element (A), an element (B) and one or more elements selected from (C) or (D), comprising the steps of:
mixing raw material powder composed of the respective elements or raw material powder of an alloy of two or more elements; vacuum hot pressing the mixed powder under conditions that satisfy the following formula: P (pressure)≤(Pf/(Tf−T 0 ))×(T−T 0 )+P 0 wherein Pf: final pressure, Tf: final temperature, P 0 : atmospheric pressure, T: heating temperature, T 0 : room temperature, and temperatures are in Celsius; and further performing hot isostatic pressing (HIP) treatment under the conditions of P hip >5×Pf; wherein the sintered compact is free from pores having an average diameter of 1 μm or more, and the number of micropores having an average diameter of 0.1 to 1 μm existing in an area of 40,000 μm 2 of the target surface is 100 micropores or less; and wherein (A): one or more chalcogenide elements selected from S, Se, and Te; (B): one or more elements selected from Bi, Sb, As, P, and N; (C): one or more elements selected from Pb, Sn, Ge, Si, and C; and (D): one or more elements selected from Ag, Au, Pd, Pt, B, Al, Ga, In, Ti, and Zr.

6 . The method of producing a sintered compact according to claim 5 , wherein the element (A) is Te, the element (B) is Sb, the element (C) is Ge, and the element (D) is one or more elements selected from Ag, Ga, and In.

7 . The method of producing a sintered compact according to claim 5 , wherein a composition of the sintered compact is selected from the group consisting of Ge—Sb—Te, Ag—In—Sb—Te, and Ge—In—Sb—Te.

8 . The method of producing a sintered compact according to claim 5 , wherein raw material powder is composed of an alloy, a compound or a mixture of constituent elementary substances, or constituent elements, and wherein the average grain size of the raw material powder is 0.1 μm to 50 μm, the maximum grain size is 90 μm or less, and the purity is 4N or higher.

9 . The method of producing a sintered compact according to claim 5 , wherein, in a course of heating temperature T rising from 100° C. to 500° C. during the vacuum hot pressing, the pressure P is maintained at a constant level for 10 to 120 minutes at least in a part of a range of the heating temperature of 100° C. to 500° C.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Fukuyo Hideaki
• Yahagi Masataka
• Yamakoshi Yasuhiro
• Takahashi Hideyuki

Classifications

• G11B2007/24316

  group 16 elements (i.e. chalcogenides, Se, Te) · CPC title

• B22F3/14

  simultaneously · CPC title

• B22F3/15

  Hot isostatic pressing · CPC title

• G11B2007/24308

  transition metal elements of group 11 (Cu, Ag, Au) · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title