Water electrolysis system and control method thereof

Patent metadata

Field	Value
Publication number	US-2021180197-A1
Application number	US-202016916982-A
Country	US
Kind code	A1
Filing date	Jun 30, 2020
Priority date	Dec 12, 2019
Publication date	Jun 17, 2021
Grant date	—

Abstract

A water electrolysis system includes a pair of electrolytic cells for accommodating electrolytic water supplied from an electrolytic water tank and connected to a hydrogen tank and an oxygen tank, a pair of active electrodes including a cathode and an anode being accommodated in the electrolytic cells and connected to electric power by an active electrode lead to electrolyze electrolytic water to produce hydrogen and oxygen, auxiliary electrodes accommodated in the electrolytic cells and connected by an auxiliary electrode lead to provide electrons to the separated electrolytic cells or receive electrons therefrom, sensors for measuring pressure of hydrogen or oxygen generated in the electrolytic cells and measure electrolytic water capacity of the electrolytic cells, and a controller for selectively discharging a hydrogen or oxygen gas upon receiving a measurement value of a sensor, selectively supplying electrolytic water to the electrolytic cells from the electrolytic water tank, and selectively controlling a current direction of the electric power.

First claim

1 . A water electrolysis system comprising:
a pair of separate electrolytic cells configured to accommodate electrolytic water supplied from an electrolytic water tank and connected to a hydrogen tank and an oxygen tank; a pair of active electrodes including a cathode and an anode, the cathode and the anode being accommodated in the pair of electrolytic cells and connected to electric power by an active electrode lead to electrolyze electrolytic water to produce hydrogen and oxygen, respectively; auxiliary electrodes respectively accommodated in the pair of electrolytic cells and connected to each other by an auxiliary electrode lead to provide electrons to the separated electrolytic cells or receive electrons therefrom; a plurality of sensors configured to measure pressure of hydrogen or oxygen generated in the electrolytic cells and to measure an electrolytic water capacity of the electrolytic cells; and a controller configured to control to selectively discharge a hydrogen gas or oxygen gas upon receiving a measurement value of a sensor, to control to selectively supply electrolytic water to the electrolytic cells from the electrolytic water tank, and to selectively control a current direction of the electric power.

2 . The water electrolysis system of claim 1 , wherein the sensor includes a pressure sensor configured to measure a pressure of hydrogen or oxygen generated in each electrolytic cell and an electrolytic water sensor configured to measure an electrolytic water capacity and the pressure sensor and the electrolytic water sensor are positioned on the electrolytic cells, respectively.

3 . The water electrolysis system of claim 2 , further comprising:
at least one pipe connected to each electrolytic cell to form a flow path allowing a hydrogen or oxygen gas generated in the active electrodes to be discharged to a hydrogen tank or an oxygen tank and having a gas valve positioned at an inlet for discharging a gas from the electrolytic cell to selectively open and close the flow path.

4 . The water electrolysis system of claim 3 , wherein the pipe includes a hydrogen pipe connected to the hydrogen tank and having a hydrogen valve and an oxygen pipe connected to the oxygen tank and having an oxygen valve, and the hydrogen valve and the oxygen valve are controlled to be selectively opened and closed by the controller.

5 . The water electrolysis system of claim 3 , wherein the pipe is configured as a single pipe connected to the electrolytic cells and having a branching point connected to the hydrogen tank or the oxygen tank, and a three-way valve is positioned at the branching point.

6 . The water electrolysis system of claim 5 , wherein the controller is configured to control to open the oxygen valve of the electrolytic water accommodating the anode and open the hydrogen valve of the electrolytic water accommodating the cathode to store a gas in the oxygen tank and the hydrogen tank, when a pressure of a gas measured by the pressure sensor reaches a predetermined gas discharge pressure.

7 . The water electrolysis system of claim 6 , wherein the predetermined gas discharge pressure is 20 bar or higher.

8 . The water electrolysis system of claim 6 , wherein the controller controls to supply electrolytic water to the electrolytic cell to entirely discharge a remaining gas, when the gas generated in the electrolytic water is discharged and a pressure of the gas measured by the pressure sensor is equal to or lower than a predetermined electrolytic water replenishment pressure.

9 . The water electrolysis system of claim 8 , wherein the predetermined electrolytic water replenishment pressure is 1 bar or lower.

10 . The water electrolysis system of claim 9 , wherein the controller controls to open an electrolytic water valve when a capacity of the electrolytic water measured by the electrolytic water sensor is less than or equal to a predetermined capacity, and controls to close the electrolytic water valve when the predetermined capacity is reached.

11 . The water electrolysis system of claim 10 , wherein, when the electrolytic water reaches a predetermined capacity, the controller controls to close both the gas valve and the electrolytic water valve and to apply a current by changing a direction of a current applied from the electric power, and as the direction of the current is reversed, the cathode is changed into the anode and the anode is changed into the cathode and an operation of the system is circulated.

12 . The water electrolysis system of claim 1 , wherein the pair of electrolytic cells are continuously provided in plurality and operated by the same controller.

13 . The water electrolysis system of claim 1 , wherein the electrolytic water may be a NaOH or KOH aqueous solution.

14 . A method of controlling a water electrolysis system, the method comprising:
a current applying operation of applying a current to active electrodes in one direction; a gas generating operation of generating hydrogen in the active electrode providing an electron and generating oxygen in the active electrode receiving an electron; a gas storing operation of storing a gas generated in an electrolytic cell; an electrolytic water replenishing operation of replenishing electrolytic water in the electrolytic cell; and a current re-applying operation of re-performing the gas generating operation by applying a current to the active electrode in the other direction.

15 . The method of claim 14 , wherein the gas storing operation includes:
a gas discharging operation of controlling, by a controller, to discharge the gas to a hydrogen tank and an oxygen tank when a pressure of the produced hydrogen or oxygen reaches a predetermined gas discharge pressure; and a discharge stopping operation of blocking the connection between the hydrogen tank, the oxygen tank, and the electrolytic cell to stop discharging of the gas when a pressure of the electrolytic cell is lowered to a predetermined electrolytic water replenishment pressure.

16 . The method of claim 14 , wherein the gas discharge pressure is 20 bar and the electrolytic water replenishment pressure is 1 bar.

17 . The method of claim 15 , wherein the electrolytic water replenishing operation includes:
an electrolytic water introducing operation of introducing electrolytic water by controlling, by the controller, to connect the electrolytic cell and the electrolytic water tank; and a current re-application preparing operation of blocking, by the controller, the connection between the electrolytic cell and the electrolytic water and stopping current application when a capacity of the electrolytic water reaches a predetermined capacity.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp

Inventors

• Choi Seung Hyeon

Classifications

• C25B15/033

  Conductivity · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• C25B15/02 Primary

  Process control or regulation · CPC title

• C25B15/023

  Measuring, analysing or testing during electrolytic production · CPC title