Resin composition for fiber-reinforced plastic, cured product of same, and fiber-reinforced plastic comprising said cured product

Patent metadata

Field	Value
Publication number	US-2021130538-A1
Application number	US-201816477471-A
Country	US
Kind code	A1
Filing date	Feb 26, 2018
Priority date	Feb 27, 2017
Publication date	May 6, 2021
Grant date	—

Abstract

The present invention provides a resin composition for a fiber-reinforced plastic, the resin composition including a cyanate ester (A), an epoxy resin (B), and an aromatic amine-based curing agent that is liquid at 25° C. (C), wherein the average number of cyanate groups in the cyanate ester (A) is 2.1 or greater, and/or the average number of epoxy groups in the epoxy resin (B) is 2.1 or greater. A fiber-reinforced plastic that is produced using this composition and a reinforcing fiber has favorable heat resistance and excellent tensile and bending properties, and therefore can be applied to a wide variety of fields including transport vehicles such as ships, automobiles, and aircrafts, sporting goods, building materials such as sinks and window frames, as well as industrial machinery and materials such as high-pressure gas tanks and blades for wind power generation.

First claim

1 . A resin composition for a fiber-reinforced plastic, the resin composition comprising:
a cyanate ester (A), an epoxy resin (B), and an aromatic amine-based curing agent that is liquid at 25° C. (C), wherein an average number of cyanate groups in the cyanate ester (A) expressed as a formula (1) below is 2.1 or greater, and/or an average number of epoxy groups in the epoxy resin (B) expressed as a formula (2) below is 2.1 or greater:

[

Math
.

⁢
1

]

Average
⁢

⁢
number
⁢

⁢
of
⁢

⁢
cyanate
⁢

⁢
groups

⁢

=

∑

i
=
1

n

⁢

(

A
i

×

X
i

)

100

(
1
)

(in the formula (1), “n” represents the number of types of cyanate ester components contained in the cyanate ester (A), A i represents the number of cyanate groups in an i-th cyanate ester component contained in the cyanate ester (A), and X i represents the content ratio by mass of the i-th cyanate ester component in the cyanate ester (A)), and

[

Math
.

⁢
2

]

Average
⁢

⁢
number
⁢

⁢
of
⁢

⁢
epoxy
⁢

⁢
groups

⁢

=

∑

k
=
1

n

⁢

(

B
k

×

Y
k

)

100

(
2
)

(in the formula (2), “n” represents the number of types of epoxy resin components contained in the epoxy resin (B), B k represents the number of epoxy groups in a k-th epoxy resin component contained in the epoxy resin (B), and Y k represents the content ratio by mass of the k-th epoxy resin component in the epoxy resin (B)).

2 . The resin composition for a fiber-reinforced plastic as set forth in claim 1 , wherein the cyanate ester (A) contains at least one compound and/or prepolymer selected from the group consisting of a compound represented by a general formula (3-1) below, a prepolymer of the compound represented by the general formula (3-1) below, and a compound represented by a general formula (3-2) below:
[Chem. 1] NCO—R b —R a —R c OCN   (3-1)
(in the general formula (3-1), R a represents a single bond, —S—, or a divalent hydrocarbon group, and R b and R c each independently represent a phenylene group that is unsubstituted or substituted with 1 to 4 alkyl groups, and when R b and R c are substituted with 2 to 4 alkyl groups, the alkyl groups may be the same or different), and

(in the general formula (3-2), “n” represents an integer of 1 to 10, and R d represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms).

3 . The resin composition for a fiber-reinforced plastic as set forth in claim 2 , wherein the compound represented by the general formula (3-1) above is a compound represented by a general formula (3-3) below:

(in the general formula (3-3), R e represents a single bond, a methylene group, —CH(CH 3 )—, —C(CH 3 ) 2 —, or any one of functional groups represented by general formulae (4-1) to (4-8) below, and
R f , R g , R h , and R i each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms),

Assignees

• Adeka Corp

Inventors

• INADOME Masato
• Fujita Naohiro
• Morino Kazuhide

Classifications

• C08J5/04 Primary

  Reinforcing macromolecular compounds with loose or coherent fibrous material · CPC title

• C08G59/4028

  Isocyanates; Thioisocyanates · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08G59/245

  aromatic · CPC title

• C08G59/28

  containing acyclic nitrogen atoms · CPC title