Electrode coated with a film obtained from an aqueous solution comprising a water-soluble binder, production method thereof and uses of same

Patent metadata

Field	Value
Publication number	US-2021098771-A1
Application number	US-202017117256-A
Country	US
Kind code	A1
Filing date	Dec 10, 2020
Priority date	Nov 13, 2002
Publication date	Apr 1, 2021
Grant date	—

Abstract

A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

First claim

1 . (canceled)

2 . A process for preparing an electrochemical separator comprising spreading an aqueous solution on a support, the aqueous solution comprising:
at least one water soluble binder; and at least one water soluble thickening agent, wherein the aqueous solution is essentially free of active materials and carbon, and wherein the support comprises at least one metal.

3 . The process according to claim 2 , wherein constituents of the aqueous solution have been prepared without using organic solvents.

4 . The process according to claim 2 , wherein the resultant electrochemical separator has a porosity between 10 and 90%.

5 . The process according to claim 2 , wherein the resultant electrochemical separator has a porosity between 30 and 50%.

6 . The process according to claim 2 , wherein the aqueous solution is free of active materials and carbon.

7 . The process according to claim 2 , wherein at least 90% of the water soluble binder and/or the water soluble thickening agent are soluble at room temperature.

8 . The process according to claim 2 , wherein the water soluble thickener is selected from the group consisting of natural celluloses, modified celluloses, natural polysaccharides and modified polysaccharides.

9 . The process according to claim 8 , wherein the water soluble thickener has a molecular weight between 27,000 and 250,000.

10 . The process according to claim 2 , wherein the water soluble thickener is selected from the group consisting of carboxymethylcelluloses, hydroxymethylcelluloses and methylethylhydroxycelluloses.

11 . The process according to claim 2 , wherein the water soluble thickener is a carboxymethylcellulose.

12 . The process according to claim 2 , wherein the water soluble thickener is selected from the group consisting of EP, 7A, WSC. BS-H and 3H carboxymethylcelluloses, sold by Daiichi Kogyo Seiyaku Co. of Japan.

13 . The process according to claim 12 , wherein the water soluble thickener is EP and/or 3H.

14 . The process according to claim 2 , wherein the water soluble binder is a natural or synthetic rubber.

15 . The process according to claim 2 , wherein the water soluble binder is a water soluble rubber is selected from the group consisting of SBRs, NBRs, HNBRs, CHRs and ACMs.

16 . The process according to claim 2 , wherein the water soluble binder is an SBR.

17 . The process according to claim 2 , wherein the water soluble binder is an SBR in the form of a paste at room temperature.

18 . The process according to claim 2 , wherein the water soluble binder is a non-fluorinated binder or a low-fluorinated binder.

19 . The process according to claim 2 , wherein the water soluble binder is a non-fluorinated SBR in the form of a paste at room temperature.

20 . The process according to claim 2 , wherein at least 95% of the water that is present in the aqueous solution is evaporated after spreading.

21 . The process according to claim 20 , further comprising heat treatment in line of the EXT, DBH and/or DB process or by infrared.

22 . The process according to claim 21 , wherein the heat treatment is conducted at a temperature between 80 and 130° Celsius for a period of time between 1 and 12 hours.

23 . The process according to claim 2 , wherein the spreading is carried out in ambient air and by using a Doctor Blade extrusion method.

24 . The process according to claim 2 , wherein the spreading is carried out in ambient air and by using an electrostatic method.

25 . An electrochemical separator prepared according to claim 2 .

26 . The electrochemical separator according to claim 25 , wherein the separator is cross-linked by UV thermal heating, E-Beam, or IR (thermal).

27 . An electrochemical system comprising the separator of claim 25 .

Assignees

• Hydro Quebec

Inventors

• Zaghib Karim
• Armand Michel
• Guerfi Abdelbast
• Perrier Michel
• Dupuis Elisabeth
• Charest Patrick

Classifications

• H01M50/42

  Acrylic resins · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M50/491

  Porosity · CPC title

• H01M50/406

  Moulding; Embossing; Cutting · CPC title