Composite membranes and methods of making and use thereof
US-2018345227-A1 · Dec 6, 2018 · US
US2021086136A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2021086136-A1 |
| Application number | US-201816620470-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jun 11, 2018 |
| Priority date | Jun 9, 2017 |
| Publication date | Mar 25, 2021 |
| Grant date | — |
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A filter medium is provided. According to one embodiment of the present invention, the filter medium is implemented by including: a porous second support and a nanofiber web which are sequentially stacked on each of an upper portion and a lower portion of a first support; and a channel through which a filtrate filtered in the nanofiber web flows in a direction of the first support, wherein the first support, the second support, and the nanofiber web satisfy predetermined conditions on a basis weight and a thickness of each layer. In a water treatment operation of the filter medium, the shape, structural deformation, and damage of the filter medium can be minimized, excellent filtration efficiency can be implemented, and a channel can be smoothly secured, thereby securing high flux. In addition, even at high pressure applied during backwashing, the filter medium has an extended use period due to excellent durability of the filter medium. Accordingly, the filter medium can be variously applied in various water treatment fields.
Opening claim text (preview).
1 . A filter medium comprising: a second support with porosity and a nanofiber web which are sequentially stacked on each of an upper portion and a lower portion of a first support with porosity; and a channel through which a filtrate filtered in the nanofiber web flows in a direction of the first support, wherein the first support, the second support, and the nanofiber web satisfy at least one condition selected from condition (1) and condition (2) below: ( b 1 +c 1 )/ a 1 ≤0.9 and c 1 /b 1 ≤2.1, and (1) ( b 2 +c 2 )/ a 2 ≤0.32 and c 2 /b 2 ≤2.1, (2) wherein a 1 , b 1 and c 1 respectively refer to basis weights (g/m 2 ) of the first support, the second support, and the nanofiber web, and a 2 , b 2 , and c 2 respectively refer to thicknesses (mm) of the first support, the second support, and the nanofiber web. 2 . The filter medium of claim 1 , wherein the first support, the second support, and the nanofiber web satisfy at least one condition selected from condition (1) and condition (2) below: 0.06≤( b 1 +c 1 )/ a 1 ≤0.67 and 0.02 ≤c 1 /b 1 ≤0.46, and (1) 0.027≤( b 2 +c 2 )/ a 2 ≤0.29 and 0.0022 ≤c 2 /b 2 ≤1.1. (2) 3 . The filter medium of claim 1 , wherein the first support has a basis weight ranging from 250 g/m 2 to 800 g/m 2 , the second support has a basis weight ranging from 10 g/m 2 to 200 g/m 2 , and the nanofiber web has a basis weight ranging from 0.05 g/m 2 to 20 g/m 2 . 4 . The filter medium of claim 1 , wherein the first support has a thickness ranging from 2 mm to 8 mm, the second support has a thickness ranging from 100 μm to 400 μm, and the nanofiber web has a thickness ranging from 0.5 μm to 200 μm. 5 . The filter medium of claim 1 , wherein the first support and the second support include a nonwoven fabric, and the first support, the second support, and the nanofiber web satisfy condition (3) below: ( b 3 +c 3 )/ a 3 ≤6.4 and c 3 /b 3 '0.21, (3) wherein a3, b3, and c3 respectively refer to fiber average diameters (μm) of the first support, the second support, and the nanofiber web. 6 . The filter medium of claim 5 , wherein the first support has a fiber average diameter ranging from 5 μm to 50 μm, the second support has a fiber average diameter ranging from 5 μm to 30 μm, and the nanofiber web has a fiber average diameter ranging from 0.05 μm to 1 μm. 7 . The filter medium of claim 1 , wherein the second support includes a second composite fiber which includes a support component and a low melting point component and is disposed such that at least a portion of the low melting point component is exposed at an outer surface thereof, and the low melting point component of the second composite fiber is fused to the nanofiber web. 8 . The filter medium of claim 7 , wherein the first support includes a first composite fiber which includes a support component and a low melting point component and is disposed such that at least a portion of the low melting point component is exposed at an outer surface thereof, and the low melting point component of the first composite fiber and the low melting point component of the second composite fiber are fused to each other to bond the first support and the second support. 9 . The filter medium of claim 1 , wherein the nanofiber web includes a fluorine-based compound as a fiber-forming component, and the fluorine-based compound includes at least one compound selected from the group consisting of polytetrafluoroethylene (PTFE)-based, tetrafluoroethylene-perfluoroalkyl vinyl ether (PFA) copolymer-based, tetrafluoroethylene-hexafluoropropylene (FEP) copolymer-based, tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether (EPE) copolymer-based, tetrafluoroethylene-ethylene (ETFE) copolymer-based, polychlorotrifluoroethylene (PCTFE)-based, chlorotrifluoroethylene-ethylene (ECTFE) copolymer-based, and polyvinylidene fluoride (PVDF)-based compounds. 10 . The filter medium of claim 1 , wherein the nanofiber web has an average pore size ranging from 0.1 μm 3 μm and a porosity ranging from 60% to 90%. 11 . The filter medium of claim 1 , wherein the filter medium is an ultrafiltration membrane. 12 . A manufacturing method of a filter medium, comprising: (1) laminating a nanofiber web and a second support; and (2) disposing the laminated nanofiber web and second support on each of both surfaces of a first support such that the second support is in contact with the first support and performing laminating thereon, wherein the first support, the second support, and the nanofiber web satisfy at least one condition selected from condition (1) and condition (2) below: ( b 1 +c 1 )/ a 1 ≤0.9 and c 1 /b 1 ≤2.1, and (1) ( b 2 +c 2 )/ a 2 ≤0.32 and c 2 /b 2 ≤2.1, (2) wherein a 1 , b 1 , and c 1 respectively refer to basis weights (g/m 2 ) of the first support, the second support, and the nanofiber web, and a 2 , b 2 , and c 2 respectively refer to thicknesses (mm) of the first support, the second support, and the nanofiber web. 13 . The manufacturing method of claim 12 , wherein operation (1) includes 1-1) electrospinning a nanofiber on the second support to form the nanofiber web, and 1-2) laminating the nanofiber web and the second support by applying heat and pressure in both directions of the second support on which the nanofiber web is formed. 14 . A flat filter unit comprising: the filter medium according to claim 1 ; and a support frame which includes a channel configured to allow a filtrate filtered in the filter medium to be discharged to the outside and supports an edge of the filter medium.
Flat membrane modules · CPC title
Molecular weight or degree of polymerisation · CPC title
Pore size · CPC title
Flat membranes · CPC title
Woven, non-woven or net mesh · CPC title
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