Hydrogen system and method of operating hydrogen system

Patent metadata

Field	Value
Publication number	US-2021079546-A1
Application number	US-202017108008-A
Country	US
Kind code	A1
Filing date	Dec 1, 2020
Priority date	May 31, 2019
Publication date	Mar 18, 2021
Grant date	—

Abstract

A hydrogen system includes: a compressor in which protons extracted from an anode fluid supplied to an anode move to a cathode through an electrolyte membrane and compressed hydrogen is generated; and a first eliminator including: a water-permeable membrane; a cathode gas flow path through which a cathode gas discharged from the cathode of the compressor flows, the cathode gas flow path being provided on one main surface of the water-permeable membrane; and an accommodation portion provided on the other main surface of the water-permeable membrane and filled with a liquid at a pressure lower than that of the cathode gas. The first eliminator removes moisture contained in the cathode gas.

First claim

What is claimed is:

1 . A hydrogen system comprising:
a compressor in which protons extracted from an anode fluid supplied to an anode move to a cathode through an electrolyte membrane and compressed hydrogen is generated; and a first eliminator including:
a water-permeable membrane;
a cathode gas flow path through which a cathode gas discharged from the cathode of the compressor flows, the cathode gas flow path being provided on one main surface of the water-permeable membrane; and
an accommodation portion provided on the other main surface of the water-permeable membrane and filled with a liquid at a pressure lower than that of the cathode gas,
the first eliminator removing moisture contained in the cathode gas.

2 . The hydrogen system according to claim 1 , comprising:
a discharge path discharging the liquid in the accommodation portion to the first eliminator.

3 . The hydrogen system according to claim 1 , wherein
the accommodation portion is a flow path through which the liquid flows.

4 . The hydrogen system according to claim 1 , wherein
a temperature of the liquid is lower than the temperature of the cathode gas flowing into the first eliminator.

5 . The hydrogen system according to claim 1 , wherein
the liquid includes water.

6 . The hydrogen system according to claim 1 , comprising:
a recycle flow path for supplying the liquid discharged from the first eliminator to the first eliminator again.

7 . The hydrogen system according to claim 1 , wherein
the liquid includes water; the anode fluid is a hydrogen-containing gas; and the system comprises a supply path supplying the liquid discharged from the first eliminator to the hydrogen-containing gas to be supplied to the anode.

8 . The hydrogen system according to claim 1 , wherein
the water-permeable membrane is a membrane of a polymer having a sulfonate group.

9 . The hydrogen system according to claim 1 , wherein
the water-permeable membrane is not energized.

10 . The hydrogen system according to claim 3 , comprising:
a first porous structure provided in the flow path through which the liquid in the first eliminator flows.

11 . The hydrogen system according to claim 1 , comprising:
a second porous structure provided in the cathode gas flow path so as to be in contact with the water-permeable membrane.

12 . The hydrogen system according to claim 1 , wherein
the compressor is a stacked product that includes a cell including the cathode, the electrolyte membrane, and the anode; and the first eliminator and the stacked product are integrally stacked.

13 . The hydrogen system according to claim 1 , comprising
a second eliminator, wherein the cathode gas passed through the first eliminator flows over one main surface of a water-permeable membrane in the second eliminator and a gas of which the chemical potential of water vapor contained in the gas is lower than that of the cathode gas flows over to the other main surface in the second eliminator.

14 . The hydrogen system according to claim 1 , comprising
a third eliminator including an adsorbent that removes moisture in the cathode gas passed through the first eliminator.

15 . A method of operating a hydrogen system comprising:
moving protons extracted from an anode fluid to be supplied to an anode to a cathode through an electrolyte membrane and generating compressed hydrogen; and moving moisture from a cathode gas containing the compressed hydrogen to a low-pressure liquid filling an accommodation portion through a water-permeable membrane.

16 . The method of operating a hydrogen system according to claim 15 , comprising:
discharging the liquid in the accommodation portion.

17 . The method of operating a hydrogen system according to claim 15 , wherein
the accommodation portion is a flow path through which the liquid flows.

18 . The method of operating a hydrogen system according to claim 15 , wherein
a temperature of the liquid is lower than the temperature of the cathode gas.

19 . The method of operating a hydrogen system according to claim 15 , wherein
the liquid includes water.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Wakita Hidenobu
• Kamata Tomoya
• Sakai Osamu
• Ukai Kunihiro
• Kani Yukimune
• Yamamoto Keiichi
• Yorozuya Misa

Classifications

• B01D53/26

  Drying gases or vapours · CPC title

• B01D53/22

  by diffusion (manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00) · CPC title

• B01D53/326

  in electrochemical cells · CPC title

• B01D71/82

  characterised by the presence of specified groups, e.g. introduced by chemical after-treatment · CPC title

• C25B9/77

  having diaphragms · CPC title