Electrolytic cell and electrolytic device

Patent metadata

Field	Value
Publication number	US-2021025063-A1
Application number	US-201917040853-A
Country	US
Kind code	A1
Filing date	Mar 28, 2019
Priority date	Mar 29, 2018
Publication date	Jan 28, 2021
Grant date	—

Abstract

An electrolytic cell capable of simply electrolyzing carbon dioxide into carbon monoxide and oxygen with low activation energy, and an electrolytic device. The carbon dioxide electrolytic cell includes a cathode, an anode, and a solid electrolyte having oxide ion conductivity. The cathode is the following (A) or (B); (A) a metal and a first mayenite-type compound are included therein or (B) a metal and a second mayenite-type compound are included therein, said second mayenite type compound including a mayenite type compound having electron conductivity.

First claim

1 . A electrolytic cell comprising:
a cathode, an anode, and a solid electrolyte having oxide ion conductivity; wherein the cathode is following (A) or (B): (A) the cathode comprises a metal and a first mayenite-type compound, or (B) the cathode comprises a metal and a second mayenite-type compound, wherein the second mayenite-type compound comprises a mayenite-type compound having electronic conductivity; each of the first mayenite-type compound and the second mayenite-type compound is a mayenite-type compound having a representative composition represented by 12CaO.7Al 2 O 3 ; the first mayenite-type compound and the second mayenite-type compound are the same or different; and the mayenite-type compound comprises Al and at least one element selected from the group consisting of Ca and Sr, and a molar ratio of a sum of CaO and SrO to Al 2 O 3 in terms of oxides is 12.6:6.4 to 11.7:7.3.

2 . The electrolytic cell according to claim 1 ,
wherein the mayenite-type compound comprises: (i) at least one element selected from the group consisting of B, Si and Ge, and total amount thereof is 0 to 17 mol % in terms of oxides with respect to the mayenite-type compound; (ii) at least one element selected from the group consisting of Li, Na, and K, and total amount thereof is 0 to 5 mol % in terms of oxides with respect to the mayenite-type compound; (iii) at least one element selected from the group consisting of Mg and Ba, and total amount thereof is 0 to 10 mol % in terms of oxides with respect to the mayenite-type compound; and (iv) at least one element selected from the group consisting of: at least one rare earth element selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb, at least one transition metal element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Pd, Ir, and Pt, and at least one typical metal element selected from the group consisting of Zn, Cd, In, and Sn, nd total amount thereof is 0 to 8 mol % in terms of oxides with respect to the mayenite-type compound.

3 . The electrolytic cell according to claim 1 or 2 ,
wherein the solid electrolyte is a third mayenite-type compound;
the third mayenite-type compound is the mayenite-type compound having the representative composition represented by 12 CaO.7Al 2 O 3 ; and
the third mayenite-type compound is the same as or different from the first mayenite-type compound or the second mayenite-type compound.

4 . The electrolytic cell according to claim 1 ,
wherein the anode is the first mayenite-type compound or the second mayenite-type compound.

5 . The electrolytic cell according to claim 1 ,
wherein the electrolytic cell is for decomposing carbon dioxide.

6 . An electrolytic device comprising the electrolytic cell according to claim 1 .

7 . A method for decomposing carbon dioxide using the electrolytic device according to claim 1 .

8 . A method of decomposing carbon dioxide, comprising:
decomposing carbon dioxide into carbon monoxide and oxygen by using the electrolytic cell according to claim 1 .

9 . A method of decomposing carbon dioxide, comprising:
decomposing carbon dioxide into carbon monoxide and oxygen with the electrolytic device according to claim 6 .

Assignees

• Japan Science & Tech Agency

Inventors

• Hosono Hideo
• Yokoyama Toshiharu
• Toda Yoshitake
• Ishiyama Shintaro
• Taguchi Masami
• Takahashi Hiroki

Classifications

• C01F7/16

  Preparation of alkaline-earth metal aluminates or magnesium aluminates; Aluminium oxide or hydroxide therefrom (C01F7/028 takes precedence) · CPC title

• C01B32/40

  Carbon monoxide · CPC title

• C25B11/077

  the compound being a non-noble metal oxide · CPC title

• C25B13/07

  based on ceramics · CPC title

• C25B1/23 Primary

  Carbon monoxide or syngas · CPC title