Hard coat film
US-2019292342-A1 · Sep 26, 2019 · US
US2021023827A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2021023827-A1 |
| Application number | US-202017038890-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 30, 2020 |
| Priority date | Apr 26, 2018 |
| Publication date | Jan 28, 2021 |
| Grant date | — |
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A hardcoat film has a substrate, a hardcoat layer, and a mixed layer in this order. The hardcoat layer contains a cured product of polyorganosilsesquioxane (a1) having an epoxy group. The mixed layer contains a cured product of a compound (b1) having an epoxy group and a cured product of a compound (b2) having two or more (meth)acryloyl groups in one molecule.
Opening claim text (preview).
What is claimed is: 1 . A hardcoat film comprising: a substrate; a hardcoat layer; and a mixed layer in this order, wherein the hardcoat layer contains a cured product of polyorganosilsesquioxane (a1) having an epoxy group, and the mixed layer contains a cured product of a compound (b1) having an epoxy group and a cured product of a compound (b2) having two or more (meth)acryloyl groups in one molecule. 2 . The hardcoat film according to claim 1 , wherein a thickness of the mixed layer is 0.05 μm to 10 μm. 3 . The hardcoat film according to claim 1 , further comprising: an anti-scratch layer on one surface of the mixed layer that is opposite to the other surface of the mixed layer coming into contact with the hardcoat layer, wherein the anti-scratch layer contains a cured product of a compound (c1) having two or more (meth)acryloyl groups in one molecule. 4 . The hardcoat film according to claim 3 , wherein a total thickness of the mixed layer and the anti-scratch layer is 0.1 μm to 10 μm. 5 . The hardcoat film according to claim 1 , wherein the polyorganosilsesquioxane (a1) having an epoxy group is polyorganosilsesquioxane having an alicyclic epoxy group. 6 . The hardcoat film according to claim 1 , wherein the compound (b1) having an epoxy group is polyorganosilsesquioxane having an epoxy group. 7 . The hardcoat film according to claim 6 , wherein the compound (b1) having an epoxy group is polyorganosilsesquioxane having an alicyclic epoxy group. 8 . The hardcoat film according to claim 1 , wherein in the mixed layer, a content rate of the cured product of the compound (b2) having two or more (meth)acryloyl groups in one molecule is equal to or higher than 10% by mass with respect to a total amount of the cured product of the compound (b1) having an epoxy group and the cured product of the compound (b2) having two or more (meth)acryloyl groups in one molecule. 9 . The hardcoat film according to claim 1 , wherein the hardcoat layer does not contain a cured product of a compound having a (meth)acryloyl group, or a content rate of the cured product of a compound having a (meth)acryloyl group is less than 10% by mass with respect to a total amount of the cured product of the polyorganosilsesquioxane (a1) having an epoxy group and the cured product of the compound having a (meth)acryloyl group. 10 . The hardcoat film according to claim 1 , wherein the substrate contains an imide-based polymer. 11 . An article comprising: the hardcoat film according to claim 1 . 12 . An image display device comprising the hardcoat film according to claim 1 as a surface protection film.
Protective coatings, e.g. hard coatings · CPC title
All layers being polymeric · CPC title
2 layers · CPC title
comprising acrylic (co)polymers · CPC title
comprising epoxy resins · CPC title
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