Positive electrode active material for lithium secondary battery, method of preparing the same and lithium secondary battery including the same
US-2017309910-A1 · Oct 26, 2017 · US
US2021020935A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2021020935-A1 |
| Application number | US-202017036611-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 29, 2020 |
| Priority date | Jun 26, 2017 |
| Publication date | Jan 21, 2021 |
| Grant date | — |
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A positive electrode active material has a small difference in a crystal structure between the charged state and the discharged state. For example, the crystal structure and volume of the positive electrode active material, which has a layered rock-salt crystal structure in the discharged state and a pseudo-spinel crystal structure in the charged state at a high voltage of approximately 4.6 V, are less likely to be changed by charging and discharging as compared with those of a known positive electrode active material. In order to form the positive electrode active material having the pseudo-spinel crystal structure in the charged state, it is preferable that a halogen source such as a fluorine and a magnesium source be mixed with particles of a composite oxide containing lithium, a transition metal, and oxygen, which is synthesized in advance, and then the mixture be heated at an appropriate temperature for an appropriate time.
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1 . A lithium-ion secondary battery comprising: a positive electrode active material, wherein the positive electrode active material comprises a path through which lithium is inserted and extracted in a region from a surface to a depth of 10 nm, and wherein the positive electrode active material is configured to inhibit dissolution of transition metal from the positive electrode active material. 2 . A lithium-ion secondary battery comprising: a positive electrode active material comprising lithium, cobalt, and oxygen, wherein the positive electrode active material comprises a path through which lithium is inserted and extracted in a region from a surface to a depth of 10 nm, and wherein the positive electrode active material is configured to inhibit dissolution of the cobalt from the positive electrode active material. 3 . A lithium-ion secondary battery comprising: a positive electrode active material comprising lithium cobalt oxide, wherein the positive electrode active material comprises a path through which lithium is inserted and extracted in a region from a surface to a depth of 10 nm, and wherein the positive electrode active material is configured to inhibit dissolution of the cobalt from the positive electrode active material.
Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements · CPC title
of inorganic oxides or hydroxides · CPC title
of elements or alloys · CPC title
Selection of substances as active materials, active masses, active liquids · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
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