Composition

Patent metadata

Field	Value
Publication number	US-2021001546-A1
Application number	US-201816499572-A
Country	US
Kind code	A1
Filing date	Apr 19, 2018
Priority date	Mar 15, 2018
Publication date	Jan 7, 2021
Grant date	—

Abstract

An example of a composition includes a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition. A flow additive is present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition. The flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal. The elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object. The composition is spreadable, having a Hausner Ratio less than 1.25.

First claim

What is claimed is:

1 . A composition, comprising:
a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition; a flow additive present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition, wherein the flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal, wherein the elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object; and wherein the composition is spreadable, having a Hausner Ratio less than 1.25.

2 . The composition as defined in claim 1 wherein the composition is spreadable in a layer having a layer thickness less than 200 micrometers.

3 . The composition as defined in claim 1 wherein the reducing environment is an atmosphere of hydrogen gas, carbon monoxide gas, or mixtures consisting of an inert gas with hydrogen gas or carbon monoxide gas.

4 . The composition as defined in claim 1 wherein the composition comprises particles of the host metal and particles of the flow additive.

5 . The composition as defined in claim 4 wherein the particles of the host metal have an average host metal particle size less than 20 micrometers.

6 . The composition as defined in claim 5 wherein at least 1 percent of the host metal particles have a host metal particle size smaller than 10 micrometers.

7 . The composition as defined in claim 4 wherein the primary particles of the flow additive have an average flow additive particle size ranging from about 1 to about 3 orders of magnitude smaller than an average host metal particle size.

8 . The composition as defined in claim 7 wherein the average flow additive primary particle size ranges from about 5 nanometers to about 200 nanometers.

9 . The composition as defined in claim 1 wherein:
the flow additive includes a transition metal oxide and wherein the transition metal oxide is selected from the group consisting of a vanadium oxide, a chromium oxide, an iron oxide, a cobalt oxide, a nickel oxide, and a copper oxide; or
the flow additive includes a mixed transition metal oxide.

10 . The composition as defined in claim 9 wherein the iron oxide is selected from the group consisting of FeO, Fe 2 O 3 , and Fe 3 O 4 .

11 . The composition as defined in claim 1 wherein the flow additive includes a thermally decomposing precursor selected from the group consisting of a transition metal hydroxide, and a transition metal oxo-hydroxide.

12 . The composition as defined in claim 11 wherein the elemental metal is obtainable from the thermally decomposing precursor by:
thermally decomposing the thermally decomposing precursor to form a thermal decomposition product; and
reducing the thermal decomposition product in the reducing environment.

13 . The composition as defined in claim 11 wherein the thermally decomposing precursor is selected from the group consisting of Fe(OH) 3 , FeO(OH), Cr(OH) 3 , Ni(OH) 2 , Ni(OH) 3 .

14 . A three-dimensional (3D) printing kit, comprising:
a build material composition, including:
a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the build material composition; and
a flow additive present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the build material composition, wherein the flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than a sintering temperature of the host metal, wherein the elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object, wherein the composition is spreadable, having a Hausner Ratio less than 1.25; and
a binder agent to be applied to at least a portion of a layer of the build material composition via an inkjet printhead to pattern a cross-section of an intermediate structure.

15 . A method for making a build material composition, comprising:
combining a host metal and a flow additive to form a build material mixture, the host metal being present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent based on a total weight of the build material mixture and the flow additive being present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent based on the total weight of the build material mixture, wherein the flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than a sintering temperature of the host metal, wherein the elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object; and mixing the build material mixture until a build material composition having a Hausner Ratio less than 1.25 is formed.

Assignees

• Hewlett Packard Development Co

Inventors

• Kasperchik Vladek
• Shaarawi Mohammed S
• Mckinnell James
• Monroe Michael G
• Hower Jason

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/102

  Metallic powder coated with organic material · CPC title

• B22F1/10 Primary

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title