Carbon dioxide conversion method using metal oxides

Patent metadata

Field	Value
Publication number	US-2020384447-A1
Application number	US-202016738544-A
Country	US
Kind code	A1
Filing date	Jan 9, 2020
Priority date	Jun 4, 2019
Publication date	Dec 10, 2020
Grant date	—

Abstract

The present invention relates to a catalyst for converting CO 2 to synthetic fuel such as CO using metal oxides and a conversion method using the same. The CO 2 conversion catalyst according to the present invention can treat a large amount of CO 2 per unit mole and is oxidized. In the reduction cycle, the catalyst has relatively high structural stability and excellent long-term stability as a catalyst, and it has excellent activity as a CO 2 decomposition catalyst that can be used in a continuous flow reactor, such as for CO 2 decomposition at a relatively low temperature.

First claim

1 . A catalyst for converting CO 2 having a composition represented by Formula 1:
SrFeCo 1-x O y (SFCO),  [Formula 1]
wherein: 0≤x<1, and 2.0≤y≤4.0.

2 . The catalyst of claim 1 , wherein in Formula 1, x is 0.2-0.8.

3 . A catalyst for converting CO 2 having a composition represented by Formula 2:
SrFeO 3−δ (SFO),  [Formula 2]
wherein δ≤1.

4 . The catalyst of claim 1 ,
wherein the catalyst has a particle size of 0.7 μm or less.

5 . A CO 2 conversion method using a metal oxide:
wherein the conversion method comprises the steps of selecting a catalyst for CO 2 conversion of any one of the catalysts described in claim 1 ; introducing the selected catalyst into a quartz reactor; injecting a reducing gas into the reactor and performing heat-treatment to activate the catalyst; and injecting a gas containing CO 2 into the quartz reactor and performing heat-treatment to induce a CO 2 conversion reaction, wherein the reducing gas is one among an inert gas, hydrogen, and CO; the heat-treatment temperature of the catalyst activation step is in the range of 100-1000° C.; and the heat-treatment temperature of the step of inducing the CO 2 conversion reaction is in the range of 300-800° C.

6 . The method of claim 5 ,
wherein the heat-treatment temperature of the step of inducing the CO 2 conversion reaction is in the range of 600-700° C.

7 . A CO 2 conversion method using a metal oxide:
wherein the conversion method comprises the steps of preparing two quartz tubes each having an inlet and an outlet; selecting the catalyst of claim 1 for the CO 2 conversion reaction and injecting into the two quartz tubes; activating the catalyst by connecting a reducing gas supply pipe to the inlet of the first quartz tube and a reducing gas recovery pipe to the outlet of the first quartz tube and performing heat-treatment; simultaneously with the catalyst activation step, inducing a CO 2 conversion reaction by connecting a gas supply pipe including CO 2 to the inlet of the second quartz tube and a gas recovery pipe including the CO 2 conversion reactant to the outlet of the second quartz tube and performing heat-treatment; replacing the gas supply pipe and the gas recovery pipe connected to the first quartz tube with the gas supply pipe and the gas recovery pipe connected to the second quartz tube, respectively, after a predetermined time elapses; and periodically repeating the step of replacing the gas supply pipes and the gas recovery pipes with each other, wherein the reducing gas is one among an inert gas, hydrogen, and CO, and the heat-treatment temperature of the step of activating the catalyst and inducing the CO 2 conversion reaction is in the range of 300-800° C.

8 . The method of claim 7 ,
wherein the heat-treatment temperature of the step of activating the catalyst and inducing the CO 2 conversion reaction is in the range of 600-700° C.

9 . The method of claim 7 ,
wherein the exchanging of the supply pipe and the recovery pipe optionally comprises exchanging the heat-treatment temperatures of the first quartz tube and the second quartz tube with each other, wherein periodically repeating the step of replacing the gas supply pipes and the gas recovery pipes with each other comprises replacing the heat-treatment temperatures, and wherein the heat-treatment temperature of the catalyst activation step is in the range of 100-1000° C.

10 . The catalyst of claim 3 ,
wherein the catalyst has a particle size of 0.7 μm or less.

11 . CO 2 conversion method using a metal oxide:
wherein the conversion method comprises the steps of selecting a catalyst for CO 2 conversion of the catalyst described in claim 3 ; introducing the selected catalyst into a quartz reactor; injecting a reducing gas into the reactor and performing heat-treatment to activate the catalyst; and injecting a gas containing CO 2 into the quartz reactor and performing heat-treatment to induce a CO 2 conversion reaction, wherein the reducing gas is one among an inert gas, hydrogen, and CO; the heat-treatment temperature of the catalyst activation step is in the range of 100-1000° C.; and the heat-treatment temperature of the step of inducing the CO 2 conversion reaction is in the range of 300-800° C.

12 . A CO 2 conversion method using a metal oxide:
wherein the conversion method comprises the steps of preparing two quartz tubes each having an inlet and an outlet; selecting a catalyst any one of the catalysts described in claim 3 for the CO 2 conversion reaction and injecting into the two quartz tubes; activating the catalyst by connecting a reducing gas supply pipe to the inlet of the first quartz tube and a reducing gas recovery pipe to the outlet of the first quartz tube and performing heat-treatment; simultaneously with the catalyst activation step, inducing a CO 2 conversion reaction by connecting a gas supply pipe including CO 2 to the inlet of the second quartz tube and a gas recovery pipe including the CO 2 conversion reactant to the outlet of the second quartz tube and performing heat-treatment; replacing the gas supply pipe and the gas recovery pipe connected to the first quartz tube with the gas supply pipe and the gas recovery pipe connected to the second quartz tube, respectively, after a predetermined time elapses; and periodically repeating the step of replacing the gas supply pipes and the gas recovery pipes with each other, wherein the reducing gas is one among an inert gas, hydrogen, and CO, and the heat-treatment temperature of the step of activating the catalyst and inducing the CO 2 conversion reaction is in the range of 300-800° C.

13 . The method of claim 8 ,
wherein the exchanging of the supply pipe and the recovery pipe optionally comprises exchanging the heat-treatment temperatures of the first quartz tube and the second quartz tube with each other, wherein periodically repeating the step of replacing the gas supply pipes and the gas recovery pipes with each other comprises replacing the heat-treatment temperatures, and wherein the heat-treatment temperature of the catalyst activation step is in the range of 100-1000° C.

Assignees

• Korea Inst Energy Res

Inventors

• Park Chan Young
• Nam Sung Chan
• Park Sung Youl

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title