Use of volatile compositions to limit or eliminate the perception of malodor

Patent metadata

Field	Value
Publication number	US-2020345601-A1
Application number	US-201816760031-A
Country	US
Kind code	A1
Filing date	Nov 21, 2018
Priority date	Nov 22, 2017
Publication date	Nov 5, 2020
Grant date	—

Abstract

The various aspects presented herein relate to the perfumery industry. More particularly, the various aspects presented herein relate to the use of volatile compositions to limit, decrease or eliminate the perception of malodor. Such compositions include at least one malodor antagonist optionally combined with perfuming ingredients. Such compositions, their use in combination with delivery systems and their applications in consumer products are also objects of the present disclosure.

First claim

1 . A method to inhibit, reduce, or suppress the perception of a malodor in a subject, comprising contacting the subject with at least one compound selected from the group consisting of: (1RS,6RS,11RS)-2,2,9,11-tetramethylspiro[5.5]undec-8-en-1-yl acetate, (+−)-2,2,7,11-tetramethylspiro[5.5]undec-8-en-1-yl-acetate, (+−)-2,3,7,7-tetramethylspiro[4.5]dec-2-en-6-yl acetate, (+−)-2,3,7,7-tetramethylspiro[4.5]dec-6-yl acetate, 1,5,10,10-tetramethylspiro[5.5]undec-3-en-11-yl acetate, 2,3,9,9-tetramethylspiro[4.5]decan-10-yl) acetate, (5,10,10-trimethylspiro[5.5]undec-2-en-11-yl) formate, (3,5,10,10-tetramethylspiro[5.5]undec-2-en-11-yl) acetate, (2,3,9,9-tetramethylspiro[4.5]dec-2-en-10-yl) acetate, (9,9-dimethylspiro[4.5]dec-2-en-10-yl) acetate, 10-methoxy-9,9-dimethylspiro[4.5]dec-2-ene, 4,10,10,11-tetramethylspiro[5.5]undec-2-en-11-ol, 5,10,10,11-tetramethylspiro[5.5]undec-3-en-11-ol, a mixture of 4,10,10,11-tetramethylspiro[5.5]undec-2-en-1-ol and 5,10,10,11-tetramethylspiro[5.5]undec-3-en-11-ol, 2,4,8-trimethylspiro[5.5]undec-3-en-11-ol, 2,9,11-trimethylspiro[5.5]undec-9-en-5-ol, a mixture of 2,4,8-trimethylspiro[5.5]undec-3-en-11-ol and 2,9,11-trimethylspiro[5.5]undec-9-en-5-ol, 3-methyl-5-propan-2-ylspiro[5.5]undec-2-en-11-ol, 11-methylspiro[5.5]undecan-5-ol, 3,10,10-trimethylspiro[5.5]undec-3-en-11-ol, 4,10,10-trimethylspiro[5.5]undec-3-en-11-ol, a mixture of 3,10,10-trimethylspiro[5.5]undec-3-en-11-ol and 4,10,10-trimethylspiro[5.5]undec-3-en-11-ol [2,2-dimethyl-1-(2,4,6-trimethylcyclohex-3-en-1-yl)propyl] acetate, [2,2-dimethyl-1-(2,4,6-trimethylcyclohexyl)propyl] acetate, (1RS)-2,2-dimethyl-1-[(1SR,2SR)-2-methylcyclohexyl]propyl acetate, 9,9-dimethylspiro[4.5]dec-2-en-10-ol, 2,3,9,9-tetramethylspiro[4.5]decan-10-ol, (2,2,3,3,9,9-hexamethylspiro[4.5]decan-10-yl) acetate, 9-methoxy-8,8-dimethylspiro[4.4]non-2-ene, (8,8-dimethylspiro[4.4]non-2-en-9-yl) acetate, 2,3,8,8-tetramethylspiro[4.4]non-2-en-9-one, 2,3,9,9-tetramethylspiro[4.5]dec-2-en-10-ol, 4-methoxy-3,3-dimethylspiro[4.4]nonane, (4,9,9-trimethylspiro[4.5]dec-2-en-10-yl) acetate, 2,4,9,9-tetramethylspiro[4.5]dec-2-en-10-ol, (2,3,9,9-tetramethylspiro[4.5]dec-2-en-10-yl) formate, (2,4,9,9-tetramethylspiro[4.5]dec-2-en-10-yl) acetate, (+−)-2,3-dimethylspiro[4.5]dec-2-en-6-yl acetate, (4 ˜ {S},5 ˜ {R},6 ˜ {S},11 ˜ {S})-4,11-dimethylspiro[5.5]undecan-5-ol, 9,9-dimethylspiro[4.5]dec-2-en-10-one, 2,3,9,9-tetramethylspiro[4.5]dec-2-en-10-one, 2,4,9,9-tetramethylspiro[4.5]dec-2-en-10-one, 1,1′,1′,5-tetramethyl-2′-methylidenespiro[6-oxabicyclo[3.1.0]hexane-3,3′-cyclohexane], 4,9,9-trimethylspiro[4.5]dec-2-en-10-one, 2,2-dimethyl-6,6-bis(2-methylprop-2-enyl)cyclohexan-1-one, 2,2-dimethyl-5,5-bis(2-methylprop-2-enyl)cyclopentan-1-one, 2-but-3-en-2-yl-6,6-dimethyl-2-prop-2-enylcyclohexan-1-one, 2,2-bis(2-methyl-2-propen-1-yl)cyclohexanone, a mixture of 2-but-3-en-2-yl-6,6-dimethyl-2-prop-2-enylcyclohexan-1-one and 2,2-bis(2-methyl-2-propen-1-yl)cyclohexanone, 2,2-dimethyl-1-(2-methylcyclohexyl)propan-1-ol, 2,2-dimethyl-1-(3-methylcyclohexyl)propan-1-ol, a mixture of 2,2-dimethyl-1-(2-methylcyclohexyl)propan-1-ol and 2,2-dimethyl-1-(3-methylcyclohexyl)propan-1-ol, 2,2-dimethyl-6,6-bis(2-methylprop-2-enyl)cyclohexan-1-ol, 1-methoxy-2,6-dimethyl-1-prop-2-enylcyclohexane, methyl 1-(3-methylbut-2-enyl)cyclohex-2-ene-1-carboxylate, methyl 1-(3-methylbut-2-enyl)cyclohex-3-ene-1-carboxylate, a mixture of methyl 1-(3-methylbut-2-enyl)cyclohex-2-ene-1-carboxylate and methyl 1-(3-methylbut-2-enyl)cyclohex-3-ene-1-carboxylate, 2,2-dimethyl-5,5-bis(2-methylprop-2-enyl)cyclopentan-1-ol, 1-(2,6-dimethylcyclohex-3-en-1-yl)-2,2-dimethylpropan-1-ol, 1-(2-methyl-4-tricyclo[5.2.1.01,5]decanyl)ethyl acetate, 1-(2,4-dimethyl-4-tricyclo[5.2.1.0{circumflex over ( )}1,5]decanyl)ethyl acetate, 1-((1R,3S,3aS,6S)-1,2,3-trimethyloctahydro-3a,6-methanoinden-1-yl)ethan-1-one, 1-(2,4-dimethyl-4-tricyclo[5.2.1.0{circumflex over ( )}{1,5}]decanyl)ethanone, 2,3,4-trimethyltricyclo[5.2.1.0{circumflex over ( )}{1,5}]decane-4-carbaldehyde, (2,3,4-trimethyl-4-tricyclo[5.2.1.0{circumflex over ( )}{1,5}]decanyl)methyl acetate, 1-((3aS,6S)-2,3-dimethyloctahydro-3a,6-methanoinden-1-yl)ethan-1-one oxime, 1,3-dimethyloctahydro-3a,6-methanoindene-1-carbaldehyde oxime, ˜ {N}-[1-[(1 ˜ {R},7 ˜ {R})-2,3,4-trimethyl-4-tricyclo[5.2.1.01,5]decanyl]ethylidene]hydroxylamine, (+−)-1-(2,4-dimethyltricyclo[5.2.1.01.5]dec-4-yl) ethanone, (+−)-1-(2,4-dimethyltricyclo[5.2.1.0 ˜ 1.5 ˜ ]dec-4-yl) ethyl acetate, 1-[(1RS,2RS,4SR,7RS)-2,3,4-trimethyltricyclo[5.2.1.01. ˜ ]dec-4-yl) ethanone, (E/Z)-1-[(1RS,7RS)-2,3-dimethyltricyclo[5.2.1.01.5]dec-4-yl) ethanone oxime, (E/Z)-1-[(1S,7S)-2,3,4-trimethyltricyclo[5.2.1.0 ˜ 1.5 ˜ ]dec-4-yl) ethanone oxime, (E/Z)-1-((3aS,6S)-1,2,3-trimethyloctahydro-3a,6-methanoinden-1-yl)ethanone oxime, (+−)-1-(3-methyloctahydro-3a,6-methanoinden-1-yl)ethyl acetate, [1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.04,6]dodecane, 1-2,6,6-trimethyl-3-cyclohexen-1-yl-2-buten-1-one, 2-tertbutyl phenol, 5-Methyl-2-(propan-2-yl)phenol, nona-2,6-dienal, 1,1-diethoxy-3,7-dimethylocta-2,6-diene, 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde, 1,4,8-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; 1,5,8-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene, 3-(4-tert-butylphenyl)propanal, (4R,4aS,6R)-4,4a-dimethyl-6-prop-1-en-2-yl-3,4,5,6,7,8-hexahydronaphthalen-2-one, geranyl acetate, 1-(3,3-dimethylcyclohexen-1-yl)pent-4-en-1-one; 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one, 1-(3,3-dimethylcyclohexen-1-yl)pent-4-en-1-one; 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one, 2-ethoxy-5-prop-1-enylphenol, 2,6,6,8-tetramethyl-9-oxatetracyclo[5.4.1.0{circumflex over ( )}{1,5}0{circumflex over ( )}{8,10}]dodecane, nonylenic aldehyde, isobutylquinoline, cyclopentadec-4-en-1-one, (−)-(R)-3,7-dimethyl-6-octenenitrile, 2-methyl-5-propan-2-ylphenol, isopropyl quinolone, 5-hexyl-2-methylpyridine, (2,5-dimethyl-1,3-dihydroinden-2-yl)methanol, 2-pentylcyclopentan-1-one, 4-(2,6,6-trimethylcyclohexen-1-yl)but-3-en-2-one; 4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one, 3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one, 2,4-dimethylcyclohex-3-enecarbaldehyde, phenylethylol, 3,7-dimethylocta-2,6-dienal, (2,2,2-trichloro-1-phenylethyl) acetate, 4-(2,6,6-trimethylcyclohexen-1-yl)but-3-en-2-one, phenyl ethyl acetate, 7-hydroxy-3,7-dimethyloctanal, methyl citral, 6,10-dimethylundeca-5,9-dien-2-one, 2-ethoxy-5-prop-1-enylphenol, (4-methyl-4-phenylpentan-2-yl) acetate, (+−)-3-methylcyclopentadecanone, 1-(4,8-dimethyl-12-methylidenecyclododeca-4,8-dien-1-yl)ethanone; 1-(2,6,10-trimethylcyclododeca-1,5,9-trien-1-yl)ethanone; 1-(2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethanone, cyclododecanone, (Z)-3,4,5,6,6-pentamethylhept-3-en-2-one, 1,4-dioxacyclohexadecane-5,16-dione, pentanol, oxacyclohexadecan-2-one, 1,1,2,3,3-pentamethyl-2,5,6,7-tetrahydroinden-4-one, (+−)-perhydro-5,5,8A-trimethyl-2-trans-naphthalenone, 2,3,3-trimethyl-2H-inden-1-one, 4-(4,8-dimethylnona-3,7-dienyl)pyridine, 4-[(1 ˜ {R},3 ˜ {R},6 ˜ {R})-2,2,3,6-tetramethylcyclohexyl]but-3-en-2-one; 4-[( 1 ˜ {S},3 ˜ {S},6 ˜ {R})-2,2,3,6-tetramethylcyclohexyl]but-3-en-2-one, (+)-(1R,7R)-10,10-dimethyl-tricyclo[7.1.1.0(2,7)]undec-2-en-4-one, (9<1>E</I>)-cycloheptadec-9-en-1-one, 8,8-dimethyl-2,3,4,6,7,8 ˜ {a}-hexahydro-1 ˜ {H}-naphthalene-2-carbaldehyde; 8,8-dimethyl-2,3,5,6,7,8 ˜ {a}-hexahydro-1 ˜ {H}-naphthalene-2-carbaldehyde; 8,8-dimethyl-2,3,4,5,6,7-hexahydro-1 ˜ {H}-naphthalene-2-carbaldehyde; 2,2-dimethyl-octahydro-1 ˜ {H}-2,4 ˜ {a}-methan, 2,4 ˜ {a},8,8-tetramethyl-1 ˜ {a},2,4,5,6,7-hexahydro-{H}-cyclopropa[j]naphthalen-3-one; 2,6,6,8-tetramethyltricyclo[5.3.1.01,5]undecan-9-one, (+−)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one, (+−)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol, (1RS,2SR,5RS,7RS,8SR)-5-methyltricyclo[6.2.1.

Assignees

• Firmenich & Cie

Inventors

• Kao Huey-Ling
• Ruider Stefan Alexander
• Smith Ben
• Marr Gary
• Rogers Matthew
• Sheikh Mushhood
• Wu Anna
• Pfister Patrick
• Birkbeck Anthony Alexander
• Coulomb Julien

Classifications

• A61K8/35

  Ketones, e.g. benzophenone · CPC title

• C11B9/0034

  the ring containing six carbon atoms · CPC title

• C11C5/002

  Ingredients · CPC title

• C11B9/0042

  compounds containing condensed hydrocarbon rings · CPC title

• A61L9/01

  Deodorant compositions {(compositions released by contact with a liquid A61L9/05)} · CPC title